Citation: NI Ting, ZOU Fan, JIANG Yu-Rong, YANG Sheng-Yi. To Improve the Efficiency of Bulk Heterojunction Organic Solar Cells by Incorporating CdSe/ZnS Quantum Dots[J]. Acta Physico-Chimica Sinica, ;2014, 30(3): 453-459. doi: 10.3866/PKU.WHXB201312274 shu

To Improve the Efficiency of Bulk Heterojunction Organic Solar Cells by Incorporating CdSe/ZnS Quantum Dots

1.
Beijing Key Laboratory of Nanophotonics and Ultrafine Optoelectronic Systems, School of Optoelectronics and School of Physics, Beijing Institute of Technology, Beijing 100081, P. R. China

Received Date: 23 October 2013
Available Online: 27 December 2013
Fund Project: 国家自然科学基金(60777025)，北京市科技新星合作项目(XXHZ201204)，北京理工大学杰出中青年教师支持计划项目(BIT-JC-201005)以及光电成像与系统教育部重点实验室开放项目(2012OEIOF02)资助 (60777025)，北京市科技新星合作项目(XXHZ201204)，北京理工大学杰出中青年教师支持计划项目(BIT-JC-201005)以及光电成像与系统教育部重点实验室开放项目(2012OEIOF02)

The efficiency of bulk heterojunction solar cells was enhanced by incorporating CdSe/ZnS core-shell colloidal quantum dots (CQDs) into copolymers of poly(3-hexylthiophene (P3HT) and [6,6]-phenyl-C₆₁-butyric acid methyl ester (PCBM) as the active layer, as result of the increased absorption in the visible region. The doping of CdSe/ZnS CQDs in the active layer and the influence of CQD surface ligands on device performance were investigated. A maximum power conversion efficiency (PCE) of 3.99% was obtained from the optimized solar cell ITO/PEDOT:PSS/P3HT:PCBM:(CdSe/ZnS)/Al (ITO: indium-tin oxide; PEDOT: poly(3,4-ethylendioxythiophene; PSS: poly(styrenesulfonate)) under AM1.5 illumination. This was 45.1% improvement on the PCE of the control device ITO/PEDOT:PSS/P3HT:PCBM/Al.
- Bulk heterojunction solar cell,
- CdSe/ZnS core-shell colloidal quantum dot,
- Polymer,
- Ligand exchange,
- Power conversion efficiency
1. [1]
  
  (1) Landi, B. J.; Castro, S. L.; Ruf, H. J.; Evans, C. M.; Bailey, S. G.; Raffaelle, R. P. Sol. Energy Mater. Sol. Cells 2005, 87, 733. doi: 10.1016/j.solmat.2004.07.047
2. [2]
  (2) Chang, L. L.; Lademann, H.W. A.; Bonekamp, J. B.; Meerholz, K.; Moulé, A. J. Adv. Funct. Mater. 2011, 21, 1779. doi: 10.1002/adfm.201002372
3. [3]
  (3) Ip, A. H.; Thon, S. M.; Hoogland, S.; Voznyy, O.; Zhitomirsky, D.; Debnath, R.; Levina, L.; Rollny, L. R.; Carey, G. H.; Fischer, A.; Kemp, K.W.; Kramer, I. J.; Ning, Z. J.; Labelle, A. J.; Chou, K.W.; Amassian, A.; Sargent, E. H. Nanotechnology 2012, 7, 577.
4. [4]
  (4) Greenham, N. C.; Peng, X.; Alivisatos, A. P. Phys. Rev. B 1996, 54, 17628. doi: 10.1103/PhysRevB.54.17628
5. [5]
  (5) Han, L. L.; Qin, D. H.; Jiang, X.; Liu, Y. S.;Wang, L.; Chen, J. W.; Cao, Y. Nanotechnology 2006, 17, 4736. doi: 10.1088/0957-4484/17/18/035
6. [6]
  (6) Olson, J. D.; Gray, G. P.; Carter, S. A. Sol . Energy Mater. Sol. Cells 2009, 93, 519. doi: 10.1016/j.solmat.2008.11.022
7. [7]
  (7) Zhou, Y. F.; Riehle, F. S.; Yuan, Y.; Schleiermacher, H. F.; Niggemann, M.; Urban, G. A.; Kruger, M. Appl. Phys. Lett. 2010, 96, 013304. doi: 10.1063/1.3280370
8. [8]
  (8) Noone, K. M.; Strein, E.; Anderson, N. C.;Wu, P. T.; Jenekhe, S. A.; Ginger, D. S. Nano Lett. 2010, 10, 2635. doi: 10.1021/nl1013663
9. [9]
  (9) Cui, D.; Xu, J.; Zhu, T.; Paradee, G.; Ashok, S.; Gerhold, M. Appl. Phys. Lett. 2006, 88, 183111. doi: 10.1063/1.2201047
10. [10]
  (10) Khan, M. T.; Bhargav, R.; Kaur, A.; Dhawan, S. K.; Chand, S. Thin Solid Films 2010, 519, 1007. doi: 10.1016/j.tsf.2010.08.032
11. [11]
  (11) Yue,W.; Hart, S.; Peng, R.; Shen,W.; Geng, H.;Wu, F.; Tao, S.; Wang, M. J. Mater. Chem. 2010, 20, 7570. doi: 10.1039/c0jm00611d
12. [12]
  (12) Fu,W. F.; Shi, Y.; Qiu,W. M.;Wang, L.; Nan, Y. X.; Shi, M. M.; Li, H. Y.; Chen, H. Z. Phys. Chem. Chem. Phys. 2012, 14, 12094. doi: 10.1039/c2cp42487h
13. [13]
  (13) Dixit, S. K.; Madan, S.; Madhwal, D.; Kumar, J.; Singh, I.; Bhatia, C. S.; Bhatnagar, P. K.; Mathur, P. C. Org. Electron. 2012, 13, 710. doi: 10.1016/j.orgel.2012.01.014
14. [14]
  (14) Jeong, S.; Shim, H. C.; Kim, S.; Han, C. S. ACS Nano 2009, 4, 324.
15. [15]
  (15) Meng, Q. L.; Li, F. X.; Xi, X.; Qian,W. Y.; Que, L. Z.; Ji, J. J.; Ding, Y. Q.; Li, G. H. J. Synth. Cryst. 2010, 39, 670. [孟庆蕾, 李方馨, 席曦, 钱维莹, 阙立志, 季静佳, 丁玉强, 李果华. 人工晶体学报, 2010, 39, 670.]
16. [16]
  (16) Zhuo, Z. L.; Zhang, F. J.; Xu, X.W.;Wang, J.; Lu, L. F.; Xu, Z. Acta Phys. -Chim. Sin. 2011, 27, 875. [卓祖亮, 张福俊, 许晓伟, 王健, 卢丽芳, 徐征. 物理化学学报, 2011, 27, 875.] doi: 10.3866/PKU.WHXB20110414
17. [17]
  (17) Olek, M.; Bulsgen, T.; Hilgendorff, M.; Giersig, M. J. Phys. Chem. B 2006, 110, 12901. doi: 10.1021/jp061453e
18. [18]
  (18) Dabbousi, B. O.; Rodriguez-Viejo, J.; Mikulec, F. V.; Heine, J. R.; Mattoussi, H.; Ober, R.; Jensen, K. F.; Bawendi, M. G. J. Phys. Chem. B 1997, 101, 9463. doi: 10.1021/jp971091y
19. [19]
  (19) Efros, A. L.; Rosen, M. Annu. Rev. Mater. Sci. 2000, 30, 475. doi: 10.1146/annurev.matsci.30.1.475
20. [20]
  (20) Kucur, E.; Qu, L.; Riegler, G. A.; Urban, G. A.; Nann, T. J. Chem. Phys. 2003, 119, 2333. doi: 10.1063/1.1582834
21. [21]
  (21) Moule, A. J.; Meerholz, K. Adv. Funct. Mater. 2009, 19, 3028. doi: 10.1002/adfm.v19:19
22. [22]
  (22) Wang, L.; Zhao, D.; Su, Z.; Li, B.; Zhang, Z.; Shen, D. J. Electrochem. Soc. 2011, 158, H804.
23. [23]
  (23) Landsberg, P. T.; Nussbaumer, H.;Willeke, G. J. Appl. Phys. 1993, 74, 1451. doi: 10.1063/1.354886
24. [24]
  (24) Kolodinski, S.;Werner, J. H.;Wittchen, T.; Queisser, H. J. Appl. Phys. Lett. 1993, 63, 2405. doi: 10.1063/1.110489
25. [25]
  (25) Li, G.; Shrotriya, V.; Huang, J. S.; Yao, Y.; Moriarty, T.; Emery, K.; Yang, Y. Nat. Mater. 2005, 4, 864. doi: 10.1038/nmat1500
1. [1]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
2. [2]
  Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304
3. [3]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
4. [4]
  Dongdong Yao , JunweiGu , Yi Yan , Junliang Zhang , Yaping Zheng . Teaching Phase Separation Mechanism in Polymer Blends Using Process Representation Teaching Method: A Teaching Design for Challenging Theoretical Concepts in “Polymer Structure and Properties” Course. University Chemistry, 2025, 40(4): 131-137. doi: 10.12461/PKU.DXHX202408125
5. [5]
  .
  南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积
  . CCS Chemistry, 2025, 7(0): -.
6. [6]
  Kun Rong , Cuilian Wen , Jiansen Wen , Xiong Li , Qiugang Liao , Siqing Yan , Chao Xu , Xiaoliang Zhang , Baisheng Sa , Zhimei Sun . 层状MoS₂/Ti₃C₂T_x异质结光热转换材料用于太阳能驱动水蒸发. Acta Physico-Chimica Sinica, 2025, 41(6): 100053-. doi: 10.1016/j.actphy.2025.100053
7. [7]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
8. [8]
  Xuefei Leng , Yanshai Wang , Hai Wang , Shengyang Tao . The In-Depth integration of “Industry-University-Research” in the Exploration and Practice of “Comprehensive Training in Polymer Engineering”. University Chemistry, 2025, 40(4): 66-71. doi: 10.12461/PKU.DXHX202405105
9. [9]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
10. [10]
  Xingchao Zhao , Xiaoming Li , Ming Liu , Zijin Zhao , Kaixuan Yang , Pengtian Liu , Haolan Zhang , Jintai Li , Xiaoling Ma , Qi Yao , Yanming Sun , Fujun Zhang . 倍增型全聚合物光电探测器及其在光电容积描记传感器上的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2311021-. doi: 10.3866/PKU.WHXB202311021
11. [11]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
12. [12]
  Zijuan LI , Xuan LÜ , Jiaojiao CHEN , Haiyang ZHAO , Shuo SUN , Zhiwu ZHANG , Jianlong ZHANG , Yanling MA , Jie LI , Zixian FENG , Jiahui LIU . Synthesis of visual fluorescence emission CdSe nanocrystals based on ligand regulation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 308-320. doi: 10.11862/CJIC.20240138
13. [13]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
14. [14]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
15. [15]
  Xingyuan Lu , Yutao Yao , Junjing Gu , Peifeng Su . Energy Decomposition Analysis and Its Application in the Many-Body Effect of Water Clusters. University Chemistry, 2025, 40(3): 100-107. doi: 10.12461/PKU.DXHX202405074
16. [16]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
17. [17]
  Jianjun Liu , Xue Yang , Chi Zhang , Xueyu Zhao , Zhiwei Zhang , Yongmei Chen , Qinghong Xu , Shao Jin . Preparation and Fluorescence Characterization of CdTe Semiconductor Quantum Dots. University Chemistry, 2024, 39(7): 307-315. doi: 10.3866/PKU.DXHX202311031
18. [18]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
19. [19]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . 锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制. Acta Physico-Chimica Sinica, 2025, 41(1): 2404042-. doi: 10.3866/PKU.WHXB202404042
20. [20]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . 钠离子电池中铁基异质结构负极材料的最新研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-. doi: 10.3866/PKU.WHXB202311015

Get Citation

PDF

XML

Metrics

PDF Downloads(620)
Abstract views(794)
HTML views(8)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

To Improve the Efficiency of Bulk Heterojunction Organic Solar Cells by Incorporating CdSe/ZnS Quantum Dots

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

Metrics

通讯作者: 陈斌, bchen63@163.com