Citation: WANG Jian, WANG Shao-Qing. Correlation between Galvanic Corrosion and Electronic Work Function of Al Alloy Surfaces[J]. Acta Physico-Chimica Sinica, ;2014, 30(3): 551-558. doi: 10.3866/PKU.WHXB201312272 shu

Correlation between Galvanic Corrosion and Electronic Work Function of Al Alloy Surfaces

WANG Jian ^1,2,3, ,
WANG Shao-Qing ¹

1.
1 Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, P. R. China;
2 School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026, P. R. China;
3 College of Science, University of Science and Technology Liaoning, Anshan 114051, Liaoning Province, P. R. China

Received Date: 11 October 2013
Available Online: 27 December 2013
Fund Project: 国家重点基础研究发展规划项目(973) (2011CB606403)资助 (973) (2011CB606403)

Al alloys contain some secondary phases to improve their properties. These secondary phases have different potentials to the Al matrix, which greatly affect the localized corrosion of Al alloys. In order to reveal the physical nature of Al alloy corrosion, we use the first-principles method based upon density functional theory to calculate the work function of the main secondary phases (Al₂Cu, Al₃Ti, and Al₇Cu₂Fe). The difficulty of electrons escaping from various crystal planes was analyzed, and the potential difference between the secondary phases and Al matrix was obtained. We find that different crystal planes exposed to the outmost layer significantly impacted on the potential difference. Different atomic types at the outmost layer play different roles in Al alloy corrosion, even for the same crystal surface. The causes of galvanic corrosion were thus revealed.
- Al alloy,
- Second phase,
- Electronic work function,
- Galvanic corrosion,
- First-principles
1. [1]
  
  (1) Grilli R. Corrosion Sci. 2011, 53, 1214. doi: 10.1016/j.corsci.2010.12.006
2. [2]
  (2) Ma, J. L.;Wen, L. B.; Li, X. D.; Zhao, S. L.; Yan, Y. F. Rare Metals 2009, 28, 187. doi: 10.1007/s12598-009-0037-z
3. [3]
  (3) Cai, J. P.; Lu, F.;Wu, X. M. J. Aeronaut. Mater. 2006, 26 (3), 271. [蔡健平, 陆峰, 吴小美. 航空材料学报, 2006, 26 (3),271.]
4. [4]
  (4) Li, L. J. Corros. Sci. Prot. Technol. 2004, 16 (5), 342. [李丽洁. 腐蚀科学与防护技术, 2004, 16 (5), 342.]
5. [5]
  (5) DeRose, J. A.; Suter, T.; Balkowiec, A.; Michalski, J.; Kurzydlowski, K. J.; Schmutz, P. Corrosion Sci. 2012, 55, 313. doi: 10.1016/j.corsci.2011.10.035
6. [6]
  (6) Fratila-Apachitei, L. E.; Apachitei, I.; Duszczyk, J. Electrochim. Acta 2006, 51, 5892. doi: 10.1016/j.electacta.2006.03.027
7. [7]
  (7) Zaldívar-Cadena, A. A.; Flores-Valdés, A. Mater. Charact. 2007, 58, 834. doi: 10.1016/j.matchar.2006.12.006
8. [8]
  (8) Afshar, F. N.; Glenn, A. M.; deWit, J. H.W.; Terryn, H.; Mol, J. M. C. Electrochim. Acta 2013, 104, 48. doi: 10.1016/j.electacta.2013.04.080
9. [9]
  (9) Peter; C. K.; Ivan, S. C.; Penny, A. C.; Anthony, E. H.; Tim, H. M. Corrosion Sci. 2011, 53, 1086. doi: 10.1016/j.corsci.2010.12.004
10. [10]
  (10) Peter, C. K.; Ivan, S. C.; Penny, A. C.; Anthony, E. H.; Tim, H. M.; Sebastian, T. Corrosion Sci. 2012, 55, 116. doi: 10.1016/j.corsci.2011.10.012
11. [11]
  (11) Guillaumin, V.; Schmutz, P.; Frankel, G. S. J. Electrochem. Soc. 2001, 148 (5), B163.
12. [12]
  (12) Liu,W. J.; Cao, F. H.; Chen, A. N.; Chang, L. R.; Zhang, J. Q.; Cao, C. Corrosion Sci. 2010, 52, 627. doi: 10.1016/j.corsci.2009.10.031
13. [13]
  (13) Schmutz, P.; Frankel, G. S. J. Electrochem. Soc.1998, 145 (7), 2295. doi: 10.1149/1.1838634
14. [14]
  (14) Shao, M. H.; Fu, Y.; Hu, R. G.; Lin, C. J. Acta Phys. -Chim. Sin. 2002, 18 (4), 350. [邵敏华, 付燕, 胡融刚, 林昌健. 物理化学学报, 2002, 18 (4), 350.] doi: 10.3866/PKU.WHXB20020413
15. [15]
  (15) Birbilis, N.; Buchheit, R. G. J. Electrochem. Soc. 2005, 152 (4), B140.
16. [16]
  (16) Zhao, Y.; Xue,W. B.; Liu, H. F. Acta Phys. -Chim. Sin. 2011, 27 (11), 2618. [赵勇, 薛文斌, 刘宏芳. 物理化学学报, 2011, 27 (11), 2618.] doi: 10.3866/PKU.WHXB20111109
17. [17]
  (17) Schmutz, P.; Frankel, G. S. J. Electrochem. Soc. 1998, 145 (7), 2285. doi: 10.1149/1.1838633
18. [18]
  (18) deWit, J. H.W. Electrochim. Acta 2001, 46, 3641. doi: 10.1016/S0013-4686(01)00642-9
19. [19]
  (19) deWit, J. H.W. Electrochim. Acta 2004, 49, 2841. doi: 10.1016/j.electacta.2004.01.045
20. [20]
  (20) Andreatta, F.; Terryn, H.; deWit, J. H.W. Electrochim. Acta 2004, 49, 2851. doi: 10.1016/j.electacta.2004.01.046
21. [21]
  (21) Rohwerder, M.; Turcu, F. Electrochim. Acta 2007, 53, 290. doi: 10.1016/j.electacta.2007.03.016
22. [22]
  (22) Zhang, G. Y.; Zhang, H.; Fang, G. L.; Yang, L. N. Acta Metall. Sin. 2009, 45, 687. [张国英, 张辉, 方戈亮, 杨丽娜. 金属学报, 2009, 45, 687.]
23. [23]
  (23) Zhang, G. Y.; Zhang, H.; Zhao, Z. F.; Li, Y. C. Acta Phys. Sin. 2006, 55, 2439. [张国英, 张辉, 赵子夫, 李昱材. 物理学报, 2006, 55, 2439.]
24. [24]
  (24) Zhang, G. Y.; Zhang, H.; Fang, G. L.; Li, Y. C. Acta Phys. Sin. 2005, 54, 5288. [张国英, 张辉, 方戈亮, 李昱材. 物理学报, 2006, 54, 5288.]
25. [25]
  (25) Huang, K.; Han, R. Q. Solid State physics; Higher Education Press: Beijing, 1988; pp 286-290. [黄昆, 韩汝琦. 固体物理学. 北京: 高等教育出版社, 1988: 286-290.]
26. [26]
  (26) Fang, J. X.; Lu, D. Solid State Physics, Volume 1; Shanghai Science and Technology Press: Shanghai, 1980; pp 196-200. [方俊鑫, 陆栋. 固体物理学. 上册. 上海: 上海科学技术出版社, 1980: 196-200.]
27. [27]
  (27) Lee, R. N.; Farnsworth H. E. Surf. Sci. 1965, 3, 461. doi: 10.1016/0039-6028(65)90026-9
28. [28]
  (28) Blöchl, P. E. Phys. Rev. B 1994, 50, 17953. doi: 10.1103/PhysRevB.50.17953
29. [29]
  (29) Perdew, J. P.; Burke, K. Ernzerhof, M. Phys. Rev. Lett. 1996, 77, 3865. doi: 10.1103/PhysRevLett.77.3865
30. [30]
  (30) Neugebauer, J.; Scheffler, M. Phys. Rev. B 1992, 46 (24), 16067. doi: 10.1103/PhysRevB.46.16067
31. [31]
  (31) Singh-Miller, N. E.; Marzari, N. Phys. Rev. B 2009, 80, 235407. doi: 10.1103/PhysRevB.80.235407
32. [32]
  (32) Grepstad, J. K.; Gartland, P. O.; Slagsvold, B. J. Surf. Sci. 1976, 57, 348. doi: 10.1016/0039-6028(76)90187-4
33. [33]
  (33) Fall, C. J.; Binggeli, N.; Baldereschi, A. Phys. Rev. B 1998, 58 (12), R7544.
34. [34]
  (34) Ogle, K.; Serdechnova, M.; Mokaddem, M.; Volovitch, P. Electrochim. Acta 2011, 56 (4), 1711. doi: 10.1016/j.electacta.2010.09.058
35. [35]
  (35) Osorio,W. R.; Spinelli, J. E.; Ferreira, I. L.; Garcia, A. Electrochim. Acta 2007, 52, 3265. doi: 10.1016/j.electacta.2006.10.004
36. [36]
  (36) Li, J. F.; Zheng, Z. Q.; Jiang, N.; Tan, C. Y. Mater. Chem. Phys. 2005, 91, 325.
37. [37]
  (37) Liu,W. B.; Zhang, S. C.; Li, N.; Zheng, J.W.; An, S. S.; Xing, Y. L. Int. J. Electrochem. Sci. 2012, 7, 2240.
38. [38]
  (38) Oltra, R.; Vuillemin, B.; Rechou, F.; Henon, C. Electrochem. Solid-State Lett. 2009, 12 (12), C29
39. [39]
  (39) Gao, K.; Li, S. M.; Fu, H. Z. Adv. Mater. Lett. 2011, 2 (5), 368.
40. [40]
  (40) Meetsma, A.; de Boer, J. L.; Van Smaalen, S. J. Solid State Chem.1989, 83, 370. doi: 10.1016/0022-4596(89)90188-6
41. [41]
  (41) Srinivasan, S.; Desch, P. B.; Schwarz, R. B. Scr. Metall. Mater. 1991, 25, 2513. doi: 10.1016/0956-716X(91)90059-A
42. [42]
  (42) Wang, S. C.; Starink, M. J. Int. Mater. Rev. 2005, 50, 193. doi: 10.1179/174328005X14357
43. [43]
  (43) deWit, J. H.W. Electrochim. Acta 2004, 49, 17.
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