Citation: SU Tong-Yu, XIAO Xiao-Jian, YE Meng-Wei, TIAN Xiao-Chun, LIN Jian-Hang, TANG Jing. Preparation of AuPd and Au Microarrays on ITO and Characterization of Electrocatalytic Activity with SECM[J]. Acta Physico-Chimica Sinica, ;2014, 30(2): 325-330. doi: 10.3866/PKU.WHXB201312242 shu

Preparation of AuPd and Au Microarrays on ITO and Characterization of Electrocatalytic Activity with SECM

1.
1 Key Laboratory of Analysis and Detection Technology for Food Safety, Ministry of Education, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350116, P. R. China;
2 Instrumental Measurement and Analysis Center, Fuzhou University, Fuzhou 350002, P. R. China

Received Date: 29 October 2013
Available Online: 24 December 2013
Fund Project: 国家自然科学基金(21173048，21073038)资助项目 (21173048，21073038)

Au and AuPd arrays were deposited onto an indium tin oxide (ITO) surface by the electrochemical wet stamping method. Agarose stamp with microstructures and solution was used to electrodeposit and generate patterns of a certain thickness. Field emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray analysis (EDX), and atomic force microscopy (AFM) were employed to characterize the morphology and components on the surface. Tip generation-substrate collection (TG-SC) mode and redox-competition (RC) mode of scanning electrochemical microscopy (SECM) combined with cyclic voltammetry were used to explore the electrocatalytic activity of the alloy arrays. In the study of the electrocatalysis, AuPd exhibited higher activity for the reduction of H₂O₂ than pure Au, but lower activity for that of ferrocenemethanol oxide (FcMeOH⁺).
- Agarose,
- AuPd alloy array,
- Electrochemical wet stamping method,
- Scanning electrochemical microscopy
1. [1]
  
  (1) Lee, K. R.; Jung, Y.;Woo, S. I. ACS Combinatorial Science2012, 14, 10. doi: 10.1021/co200056d
2. [2]
  (2) Walsh, D. A.; Fernández, J. L.; Bard, A. J. Journal of The Electrochemical Society 2006, 153, E99.
3. [3]
  (3) Tang,W.; Jayaraman, S.; Jaramillo, T. F.; Stucky, G. D.;McFarland, E.W. Journal of Physical Chemistry C 2009, 113,5014. doi: 10.1021/jp8089209
4. [4]
  (4) Qiu, H.; Zou, F. ACS Applied Materials & Interfaces 2013, 5,6775. doi: 10.1021/am4022472
5. [5]
  (5) Lee, Y.W.; Kim, M.; Kim, Y.; Kang, S.W.; Lee, J. H.; Han, S.W. Journal of Physical Chemistry C 2010, 114, 7689. doi: 10.1021/jp9119588
6. [6]
  (6) Hernández-Fernández, P.; Rojas, S.; Ocón, P.; Gómez de laFuente, J. L.; San Fabián, J.; Sanza, J.; Peña, M. A.; García-García, F. J.; Terreros, P.; Fierro, J. L. G. Journal of Physical Chemistry C 2007, 111, 2913. doi: 10.1021/jp066812k
7. [7]
  (7) Lee, K. R.; Jung, Y.;Woo, S. I. ACS Combinatorial Science2011, 14, 10.
8. [8]
  (8) Choi, S. I.; Lee, S. U.; Kim,W. Y.; Choi, R.; Hong, K.; Nam, K.M.; Han, S.W.; Park, J. T. ACS Applied Materials & Interfaces2012, 4, 6228. doi: 10.1021/am301824w
9. [9]
  (9) Fernández, J. L.; Bard, A. J. Analytical Chemistry 2003, 75,2967. doi: 10.1021/ac0340354
10. [10]
  (10) Calabretta, A.;Wasserberg, D.; Posthuma-Trumpie, G. A.;Subramaniam, V.; van Amerongen, A.; Corradini, R.; Tedeschi,T.; Sforza, S.; Reinhoudt, D. N.; Marchelli, R.; Huskens, J.;Jonkheijm, P. Langmuir 2010, 27, 1536.
11. [11]
  (11) Nagaiah, T. C.; Schäfer, D.; Schuhmann,W.; Dimcheva, N.Analytical Chemistry 2013, 85, 7897.
12. [12]
  (12) Wendeln, C.; Ravoo, B. J. Langmuir 2012, 28, 5527. doi: 10.1021/la204721x
13. [13]
  (13) Lin, C. L.; Rodríguez-López, J. N.; Bard, A. J. Analytical Chemistry 2009, 81, 8868. doi: 10.1021/ac901434a
14. [14]
  (14) Zhang, L.; Zhuang, J. L.; Ma, X. Z.; Tang, J.; Tian, Z.W.Electrochemistry Communications 2007, 9, 2529. doi: 10.1016/j.elecom.2007.07.035
15. [15]
  (15) Tang, J.; Zhuang, J. L.; Zhang, L.;Wang,W. H.; Tian, Z.W.Electrochimica Acta 2008, 53, 5628. doi: 10.1016/j.electacta.2008.03.006
16. [16]
  (16) Tang, J.; Zhang, L.; Tian, X. Journal of Micromechanics and Microengineering 2010, 20, 115030. doi: 10.1088/0960-1317/20/11/115030
17. [17]
  (17) Bowyer,W. J.; Xie, J.; Engstrom, R. C. Analytical Chemistry1996, 68, 2005. doi: 10.1021/ac9512259
18. [18]
  (18) Shan, X.; Diez-Perez, I.;Wang, L.;Wiktor, P.; Gu, Y.; Zhang,L.;Wang,W.; Lu, J.;Wang, S.; ng, Q.; Li, J.; Tao, N. Nat. Nano 2012, 7, 668. doi: 10.1038/nnano.2012.134
19. [19]
  (19) Lin, X.; Zheng, L.; Gao, G.; Chi, Y.; Chen, G. Analytical Chemistry 2012, 84, 7700. doi: 10.1021/ac300875x
20. [20]
  (20) Mezour, M. A.; Cornut, R.; Hussien, E. M.; Morin, M.;Mauzeroll, J. Langmuir 2010, 26, 13000. doi: 10.1021/la100444n
21. [21]
  (21) Dumitrescu, I.; Dudin, P. V.; Edgeworth, J. P.; Macpherson, J.V.; Unwin, P. R. Journal of Physical Chemistry C 2010, 114,2633.
22. [22]
  (22) Sanchez-Sanchez, C. M.; Rodriguez-Lopez, J.; Bard, A. J.Analytical Chemistry 2008, 80, 3254. doi: 10.1021/ac702453n
23. [23]
  (23) Minguzzi, A.; Alpuche-Aviles, M. A.; López, J. R.; Rondinini,S.; Bard, A. J. Analytical Chemistry 2008, 80, 4055. doi: 10.1021/ac8001287
24. [24]
  (24) Weng, Y. C.; Fan, F. R. F.; Bard, A. J. Journal of the American Chemical Society 2005, 127, 17576. doi: 10.1021/ja054812c
25. [25]
  (25) Jayaraman, S.; Hillier, A. C. Journal of Physical Chemistry B2003, 107, 5221. doi: 10.1021/jp0274886
26. [26]
  (26) Zeradjanin, A. R.; Schilling, T.; Seisel, S.; Bron, M.;Schuhmann,W. Analytical Chemistry 2011, 83, 7645. doi: 10.1021/ac200677g
27. [27]
  (27) Nagaiah, T. C.; Maljusch, A.; Chen, X.; Bron, M.; Schuhmann,W. ChemPhysChem 2009, 10, 2711. doi: 10.1002/cphc.v10:15
28. [28]
  (28) Eckhard, K.; Chen, X.; Turcu, F.; Schuhmann,W. Physical Chemistry Chemical Physics 2006, 8, 5359. doi: 10.1039/b609511a
29. [29]
  (29) Mayer, M.; Yang, J.; Gitlin, I.; Gracias, D. H.; Whitesides, G.M. Proteomics 2004, 4, 2366.
30. [30]
  (30) Tang, J.; Tian, X. C.; Pang,W. H.; Liu, Y. Q.; Lin, J. H.Electrochimica Acta 2012, 81, 8. doi: 10.1016/j.electacta.2012.07.048
1. [1]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
2. [2]
  Yongming Zhu , Huili Hu , Yuanchun Yu , Xudong Li , Peng Gao . Construction and Practice on New Form Stereoscopic Textbook of Electrochemistry for Energy Storage Science and Engineering: Taking Basic Course of Electrochemistry as an Example. University Chemistry, 2024, 39(8): 44-47. doi: 10.3866/PKU.DXHX202312086
3. [3]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
4. [4]
  Jinyao Du , Xingchao Zang , Ningning Xu , Yongjun Liu , Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039
5. [5]
  Yong Zhou , Jia Guo , Yun Xiong , Luying He , Hui Li . Comprehensive Teaching Experiment on Electrochemical Corrosion in Galvanic Cell for Chemical Safety and Environmental Protection Course. University Chemistry, 2024, 39(7): 330-336. doi: 10.3866/PKU.DXHX202310109
6. [6]
  Zhengli Hu , Jia Wang , Yi-Lun Ying , Shaochuang Liu , Hui Ma , Wenwei Zhang , Jianrong Zhang , Yi-Tao Long . Exploration of Ideological and Political Elements in the Development History of Nanopore Electrochemistry. University Chemistry, 2024, 39(8): 344-350. doi: 10.3866/PKU.DXHX202401072
7. [7]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
8. [8]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
9. [9]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
10. [10]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
11. [11]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
12. [12]
  Jinfu Ma , Hui Lu , Jiandong Wu , Zhongli Zou . Teaching Design of Electrochemical Principles Course Based on “Cognitive Laws”: Kinetics of Electron Transfer Steps. University Chemistry, 2024, 39(3): 174-177. doi: 10.3866/PKU.DXHX202309052
13. [13]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
14. [14]
  Li Jiang , Changzheng Chen , Yang Su , Hao Song , Yanmao Dong , Yan Yuan , Li Li . Electrochemical Synthesis of Polyaniline and Its Anticorrosive Application: Improvement and Innovative Design of the “Chemical Synthesis of Polyaniline” Experiment. University Chemistry, 2024, 39(3): 336-344. doi: 10.3866/PKU.DXHX202309002
15. [15]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013
16. [16]
  Jiarong Feng , Yejie Duan , Chu Chu , Dezhen Xie , Qiu'e Cao , Peng Liu . Preparation and Application of a Streptomycin Molecularly Imprinted Electrochemical Sensor: A Suggested Comprehensive Analytical Chemical Experiment. University Chemistry, 2024, 39(8): 295-305. doi: 10.3866/PKU.DXHX202401016
17. [17]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
18. [18]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
19. [19]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
20. [20]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414

Get Citation

PDF

XML

Metrics

PDF Downloads(510)
Abstract views(818)
HTML views(5)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142