Citation: LIN Xing-Yi, MA Jun-Tao, CHEN Chong-Qi, ZHAN Ying-Ying, ZHENG Qi. Influence of Copper Species on Performance of Cu/Fe₂O₃ Catalysts for Water Gas Shift Reaction[J]. Acta Physico-Chimica Sinica, ;2014, 30(1): 157-163. doi: 10.3866/PKU.WHXB201311271 shu

Influence of Copper Species on Performance of Cu/Fe₂O₃ Catalysts for Water Gas Shift Reaction

1.
National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, P. R. China

Received Date: 2 September 2013
Available Online: 27 November 2013
Fund Project: 福建省教育厅A类科技项目(JA08021) (JA08021)

A series of Cu/Fe₂O₃ catalysts with different Cu loadings were prepared using a co-precipitation method, and the relationship between their structures and catalytic activities for the water gas shift (WGS) reaction was carefully examined. It was found that the as-prepared Cu/Fe₂O₃ catalysts exhibit excellent WGS performances, in particular, the one containing 20% (w) CuO (CF-20) shows the best catalytic activity, with CO conversion of 97.2% at 250 ℃. Its catalytic stability is also outstanding during the temperature range of 250-400 ℃. X-ray diffraction (XRD), N₂ physisorption, and H₂ temperature program reduction (H₂-TPR) techniques were used to characterize the crystal phases, textures, and reduction properties of the Cu/Fe₂O₃ catalysts. The results show that the generation of CuFe₂O₄, which has a spinel structure in stabilizing Cu microcrystals and is easier to be reduced at low temperature, resulting in enhancing their reduction properties and facilitating electrons transfer between Cu and Fe₂O₃, thus greatly improving the catalytic performance. Furthermore, (NH₄)₂CO₃ solution treatment of the as-prepared catalysts was performed to study the effect of bulk CuO existed in the Cu/Fe₂O₃ catalysts. The result suggests that the bulk CuO is favor for H atom transfer between Cu and Fe₂O₃, thus promoting the reduction of CuFe₂O₄, finally improving the catalytic performance.
- Water gas shift,
- Cu/Fe₂O₃ catalyst,
- Copper loading,
- CuFe₂O₄
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Influence of Copper Species on Performance of Cu/Fe2O3 Catalysts for Water Gas Shift Reaction

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通讯作者: 陈斌, bchen63@163.com

Influence of Copper Species on Performance of Cu/Fe₂O₃ Catalysts for Water Gas Shift Reaction