Citation: XING Wei-Nan, NI Liang, YAN Xue-Sheng, LIU Xin-Lin, LUO Ying-Ying, LU Zi-Yang, YAN Yong-Sheng, HUO Peng-Wei. Preparation of C@CdS/Halloysite Nanotube Composite Photocatalyst Using One-Step Pyrolytic Method and Its Photodegradation Properties[J]. Acta Physico-Chimica Sinica, ;2014, 30(1): 141-149. doi: 10.3866/PKU.WHXB201311211 shu

Preparation of C@CdS/Halloysite Nanotube Composite Photocatalyst Using One-Step Pyrolytic Method and Its Photodegradation Properties

1.
1 School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu Province, P. R. China;
2 JiangSu BeiSiTi Environmental Technology Project Co., Ltd., Zhenjiang 212013, Jiangsu Province, P. R. China;
3 School of Material Science and Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu Province, P. R. China

Received Date: 15 July 2013
Available Online: 21 November 2013
Fund Project: 国家自然科学基金(21207053)，江苏省自然科学基金(SBK2011460)，博士后科学基金(2011M500861，2012M511219，2011M500869) (21207053)，江苏省自然科学基金(SBK2011460)，博士后科学基金(2011M500861，2012M511219，2011M500869)江苏大学研究生创新项目(CXLX12_0634)资助 (CXLX12_0634)

A novel photocatalyst, C@CdS/halloysite nanotubes (HNTs), was synthesized using a facile and effective pyrolytic method. The as-prepared photocatalyst was characterized using scanning electron microscopy, transmission electron microscopy, X-ray diffraction, specific surface area measurements, and X-ray energy dispersive, ultraviolet-visible diffuse reflectance, Fourier-transform infrared, specific surface area, and Raman spectroscopies. The photocatalytic activity of the sample was evaluated by the degradation of tetracycline (TC) under visible-light irradiation. The influence of different pyrolysis temperatures on the photocatalytic degradation of TC was investigated. The optimal pyrolysis temperature was found to be 400 ℃. The photodegradation rate reached 86% in 60 min under visible-light irradiation. In addition, benefiting from the common effects of carbon, CdS, and HNTs, the photocatalyst exhibited od chemical stability. After being laid aside for one year, the photocatalytic efficiency was unaffected and the photocatalyst retained its high catalytic activity after three catalytic cycles. Based on our experimental results, the preparation mechanism and degradation of the intermediate product of TC are discussed.
- Cadmium sulfide,
- Carbon,
- Halloysite nanotube,
- Photocatalytic degradation,
- Tetracycline,
- Reusability
1. [1]
  
  (1) Marshall, B. M.; Levy, S. B. Clin. Microbiol. Rev. October2011, 24, 718. doi: 10.1128/CMR.00002-11
2. [2]
  (2) Baquero, F.; Martínez, J. L.; Canton, R. Curr. Opin. Biotechnol.2008, 19, 260. doi: 10.1016/j.copbio.2008.05.006
3. [3]
  (3) Jiao, S. J.; Zheng, S. R.; Yin, D. Q.;Wang, L. H.; Chen, L. Y.Chemosphere 2008, 73, 377.
4. [4]
  (4) Zhao, C.; Deng, H. P.; Li, Y.; Liu, Z. Z. J. Hazard. Mater. 2010,176, 884. doi: 10.1016/j.jhazmat.2009.11.119
5. [5]
  (5) Pereira, J. H. O. S.; Vilar, V. J. P.; Borges, M. T.; nzález, O.;Esplugas, S.; Boaventura, R. A. R. Sol. Energy 2011, 85, 2732.doi: 10.1016/j.solener.2011.08.012
6. [6]
  (6) Lin, X.; Yu, L. L.; Yan, L, N.; Guan, Q. F.; Yan, Y. S.; Zhao, H.Acta Phys. -Chim. Sin. 2013, 29, 1771. [林雪, 于丽丽, 闫丽娜, 关庆丰, 闫永胜, 赵晗. 物理化学学报, 2013, 29, 1771.]doi: 10.3866/PKU.WHXB201305131
7. [7]
  (7) Nayak, J.; Sahu, S. N.; Kasuya, J.; Nozaki, S. Appl. Surf. Sci.2008, 254, 7215. doi: 10.1016/j.apsusc.2008.05.268
8. [8]
  (8) Shi, J.W.; Yan, X.; Cui, H. J.; Zong, X.; Fu, M. L.; Chen, S. H.;Wang, L. Z. J. Mol. Catal. A: Chem. 2012, 356, 53. doi: 10.1016/j.molcata.2012.01.001
9. [9]
  (9) Barpuzary, D.; Khan, Z.; Vinothkumar, N.; De, M.; Qureshi, M.J. Phys. Chem. C 2012, 116, 150.
10. [10]
  (10) Ryu, S. Y.; Balcerski,W.; Lee, T. K.; Hoffmann, M. R. J. Phys.Chem. C 2007, 111, 18195. doi: 10.1021/jp074860e
11. [11]
  (11) Zhang, H.; Zhu, Y. F. J. Phys. Chem. C 2010, 114, 5822. doi: 10.1021/jp910930t
12. [12]
  (12) Guo, Y.;Wang, H. S.; He, C. L. Langmuir 2009, 25, 4678. doi: 10.1021/la803530h
13. [13]
  (13) Zhong, J.; Chen, F.; Zhan, J. L. J. Phys. Chem. C 2010, 114,933. doi: 10.1021/jp909835m
14. [14]
  (14) Yang, H. P.; Zhang, Y. C.; Fu, X. F.; Song, S. S.;Wu, J. M. ActaPhys. -Chim. Sin. 2013, 29, 1327. [杨汉培, 张颖超, 傅小飞,宋双双, 吴俊明. 物理化学学报, 2013, 29, 1327.] doi: 10.3866/PKU.WHXB201303212
15. [15]
  (15) Li, S. K.; Huang, F. Z.;Wang, Y.; Shen, Y. H.; Qiu, L. G.; Xie,A. J.; Xu, S. J. J. Mater. Chem. 2011, 21, 7459. doi: 10.1039/c0jm04569a
16. [16]
  (16) Gao, Z. Y.; Liu, N.;Wu, D. P.; Tao,W. G.; Xu, F.; Jiang, K.Appl. Surf. Sci. 2012, 258, 2473. doi: 10.1016/j.apsusc.2011.10.075
17. [17]
  (17) Papoulis, D.; Komarneni, S.; Nikolopoulou, A.; Tsolis-Katagas,P.; Panagiotaras, D., Kacandes, H. G.; Zhang, P.; Yin, S.; Satoe,T.; Katsuk, H. Appl. Clay Sci. 2010, 50, 118. doi: 10.1016/j.clay.2010.07.013
18. [18]
  (18) Pan, J. M.; Yao, H.; Xu, L. C.; Ou, H. X.; Huo, P.W.; Li, X. X.;Yan, Y. S. J. Phys. Chem. C 2011, 115, 5440. doi: 10.1021/jp111120x
19. [19]
  (19) Wang, L.; Chen, J. L.; Ge, L.; Zhu, Z. H.; Rudolph, V. EnergyFuels 2011, 25, 3408. doi: 10.1021/ef200719v
20. [20]
  (20) Vergaro, V.; Abdullayev, E.; Lvov, Y. M.; Zeitoun, A.; Cin lani,R.; Rinaldi, R.; Leporatti, S. Biomacromolecules 2010, 11,820. doi: 10.1021/bm9014446
21. [21]
  (21) Reshmi, R.; Sanjay, G.; Sugunan, S. Catal. Commun. 2006, 7,460. doi: 10.1016/j.catcom.2006.01.001
22. [22]
  (22) Zhao, M. F.; Liu, P. Microporous Mesoporous Mat. 2008, 112,419. doi: 10.1016/j.micromeso.2007.10.018
23. [23]
  (23) Zhang, K. J.; Liu, X. H. J. Solid State Chem. 2011, 184, 2701.doi: 10.1016/j.jssc.2011.08.011
24. [24]
  (24) Wang, Q. Q.; Zhao, G. L.; Han, G. R. Mater. Lett. 2005, 59,2625. doi: 10.1016/j.matlet.2005.04.004
25. [25]
  (25) Wang, R. J.; Jiang, G. H.; Ding, Y.W.;Wang, Y.; Sun, X. K.;Wang, X. H.; Chen,W. X. Appl. Mater. Interfaces 2011, 3,4154. doi: 10.1021/am201020q
26. [26]
  (26) Bhattacharyya, S. Y.; Zitoun, D.; Gedanken, A. J. Phys. Chem.C 2008, 112, 7624. doi: 10.1021/jp801353w
27. [27]
  (27) Bhattacharyya, S. Y.; Estrin, Y.; Rich, D. H.; Zitoun, D.;Gedanken, A. J. Phys. Chem. C 2010, 114, 22002. doi: 10.1021/jp107083f
28. [28]
  (28) Mahendirana, C.; Maiyalaganb, T.; Scottb, K.; Gedanken, A.Mater. Chem. Phys. 2011, 128, 341. doi: 10.1016/j.matchemphys.2011.02.067
29. [29]
  (29) Yang, H.; An, T. C.; Li, G. Y.; Song,W. H.; Cooper,W. J.; Luo,H. Y.; Guo, X. D. J. Hazard. Mater. 2010, 179, 834. doi: 10.1016/j.jhazmat.2010.03.079
30. [30]
  (30) Wu, J.; Zhang, H.; Oturan, N.;Wang, Y.; Chen, L.; Oturan, M.A. Chemosphere 2012, 87, 614. doi: 10.1016/j.chemosphere.2012.01.036
31. [31]
  (31) Lu, Z. Y.; Huo, P.W.; Luo, Y. Y.; Liu, X. L.;Wu, D.; Gao, X.;Li, C. X.; Yan, Y. S. J. Mol. Catal. A: Chem. 2013, 378, 91.doi: 10.1016/j.molcata.2013.06.001
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