Citation: XING Wei-Nan, NI Liang, YAN Xue-Sheng, LIU Xin-Lin, LUO Ying-Ying, LU Zi-Yang, YAN Yong-Sheng, HUO Peng-Wei. Preparation of C@CdS/Halloysite Nanotube Composite Photocatalyst Using One-Step Pyrolytic Method and Its Photodegradation Properties[J]. Acta Physico-Chimica Sinica, ;2014, 30(1): 141-149. doi: 10.3866/PKU.WHXB201311211 shu

Preparation of C@CdS/Halloysite Nanotube Composite Photocatalyst Using One-Step Pyrolytic Method and Its Photodegradation Properties

1.
1 School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu Province, P. R. China;
2 JiangSu BeiSiTi Environmental Technology Project Co., Ltd., Zhenjiang 212013, Jiangsu Province, P. R. China;
3 School of Material Science and Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu Province, P. R. China

Received Date: 15 July 2013
Available Online: 21 November 2013
Fund Project: 国家自然科学基金(21207053)，江苏省自然科学基金(SBK2011460)，博士后科学基金(2011M500861，2012M511219，2011M500869) (21207053)，江苏省自然科学基金(SBK2011460)，博士后科学基金(2011M500861，2012M511219，2011M500869)江苏大学研究生创新项目(CXLX12_0634)资助 (CXLX12_0634)

A novel photocatalyst, C@CdS/halloysite nanotubes (HNTs), was synthesized using a facile and effective pyrolytic method. The as-prepared photocatalyst was characterized using scanning electron microscopy, transmission electron microscopy, X-ray diffraction, specific surface area measurements, and X-ray energy dispersive, ultraviolet-visible diffuse reflectance, Fourier-transform infrared, specific surface area, and Raman spectroscopies. The photocatalytic activity of the sample was evaluated by the degradation of tetracycline (TC) under visible-light irradiation. The influence of different pyrolysis temperatures on the photocatalytic degradation of TC was investigated. The optimal pyrolysis temperature was found to be 400 ℃. The photodegradation rate reached 86% in 60 min under visible-light irradiation. In addition, benefiting from the common effects of carbon, CdS, and HNTs, the photocatalyst exhibited od chemical stability. After being laid aside for one year, the photocatalytic efficiency was unaffected and the photocatalyst retained its high catalytic activity after three catalytic cycles. Based on our experimental results, the preparation mechanism and degradation of the intermediate product of TC are discussed.
- Cadmium sulfide,
- Carbon,
- Halloysite nanotube,
- Photocatalytic degradation,
- Tetracycline,
- Reusability
1. [1]
  
  (1) Marshall, B. M.; Levy, S. B. Clin. Microbiol. Rev. October2011, 24, 718. doi: 10.1128/CMR.00002-11
2. [2]
  (2) Baquero, F.; Martínez, J. L.; Canton, R. Curr. Opin. Biotechnol.2008, 19, 260. doi: 10.1016/j.copbio.2008.05.006
3. [3]
  (3) Jiao, S. J.; Zheng, S. R.; Yin, D. Q.;Wang, L. H.; Chen, L. Y.Chemosphere 2008, 73, 377.
4. [4]
  (4) Zhao, C.; Deng, H. P.; Li, Y.; Liu, Z. Z. J. Hazard. Mater. 2010,176, 884. doi: 10.1016/j.jhazmat.2009.11.119
5. [5]
  (5) Pereira, J. H. O. S.; Vilar, V. J. P.; Borges, M. T.; nzález, O.;Esplugas, S.; Boaventura, R. A. R. Sol. Energy 2011, 85, 2732.doi: 10.1016/j.solener.2011.08.012
6. [6]
  (6) Lin, X.; Yu, L. L.; Yan, L, N.; Guan, Q. F.; Yan, Y. S.; Zhao, H.Acta Phys. -Chim. Sin. 2013, 29, 1771. [林雪, 于丽丽, 闫丽娜, 关庆丰, 闫永胜, 赵晗. 物理化学学报, 2013, 29, 1771.]doi: 10.3866/PKU.WHXB201305131
7. [7]
  (7) Nayak, J.; Sahu, S. N.; Kasuya, J.; Nozaki, S. Appl. Surf. Sci.2008, 254, 7215. doi: 10.1016/j.apsusc.2008.05.268
8. [8]
  (8) Shi, J.W.; Yan, X.; Cui, H. J.; Zong, X.; Fu, M. L.; Chen, S. H.;Wang, L. Z. J. Mol. Catal. A: Chem. 2012, 356, 53. doi: 10.1016/j.molcata.2012.01.001
9. [9]
  (9) Barpuzary, D.; Khan, Z.; Vinothkumar, N.; De, M.; Qureshi, M.J. Phys. Chem. C 2012, 116, 150.
10. [10]
  (10) Ryu, S. Y.; Balcerski,W.; Lee, T. K.; Hoffmann, M. R. J. Phys.Chem. C 2007, 111, 18195. doi: 10.1021/jp074860e
11. [11]
  (11) Zhang, H.; Zhu, Y. F. J. Phys. Chem. C 2010, 114, 5822. doi: 10.1021/jp910930t
12. [12]
  (12) Guo, Y.;Wang, H. S.; He, C. L. Langmuir 2009, 25, 4678. doi: 10.1021/la803530h
13. [13]
  (13) Zhong, J.; Chen, F.; Zhan, J. L. J. Phys. Chem. C 2010, 114,933. doi: 10.1021/jp909835m
14. [14]
  (14) Yang, H. P.; Zhang, Y. C.; Fu, X. F.; Song, S. S.;Wu, J. M. ActaPhys. -Chim. Sin. 2013, 29, 1327. [杨汉培, 张颖超, 傅小飞,宋双双, 吴俊明. 物理化学学报, 2013, 29, 1327.] doi: 10.3866/PKU.WHXB201303212
15. [15]
  (15) Li, S. K.; Huang, F. Z.;Wang, Y.; Shen, Y. H.; Qiu, L. G.; Xie,A. J.; Xu, S. J. J. Mater. Chem. 2011, 21, 7459. doi: 10.1039/c0jm04569a
16. [16]
  (16) Gao, Z. Y.; Liu, N.;Wu, D. P.; Tao,W. G.; Xu, F.; Jiang, K.Appl. Surf. Sci. 2012, 258, 2473. doi: 10.1016/j.apsusc.2011.10.075
17. [17]
  (17) Papoulis, D.; Komarneni, S.; Nikolopoulou, A.; Tsolis-Katagas,P.; Panagiotaras, D., Kacandes, H. G.; Zhang, P.; Yin, S.; Satoe,T.; Katsuk, H. Appl. Clay Sci. 2010, 50, 118. doi: 10.1016/j.clay.2010.07.013
18. [18]
  (18) Pan, J. M.; Yao, H.; Xu, L. C.; Ou, H. X.; Huo, P.W.; Li, X. X.;Yan, Y. S. J. Phys. Chem. C 2011, 115, 5440. doi: 10.1021/jp111120x
19. [19]
  (19) Wang, L.; Chen, J. L.; Ge, L.; Zhu, Z. H.; Rudolph, V. EnergyFuels 2011, 25, 3408. doi: 10.1021/ef200719v
20. [20]
  (20) Vergaro, V.; Abdullayev, E.; Lvov, Y. M.; Zeitoun, A.; Cin lani,R.; Rinaldi, R.; Leporatti, S. Biomacromolecules 2010, 11,820. doi: 10.1021/bm9014446
21. [21]
  (21) Reshmi, R.; Sanjay, G.; Sugunan, S. Catal. Commun. 2006, 7,460. doi: 10.1016/j.catcom.2006.01.001
22. [22]
  (22) Zhao, M. F.; Liu, P. Microporous Mesoporous Mat. 2008, 112,419. doi: 10.1016/j.micromeso.2007.10.018
23. [23]
  (23) Zhang, K. J.; Liu, X. H. J. Solid State Chem. 2011, 184, 2701.doi: 10.1016/j.jssc.2011.08.011
24. [24]
  (24) Wang, Q. Q.; Zhao, G. L.; Han, G. R. Mater. Lett. 2005, 59,2625. doi: 10.1016/j.matlet.2005.04.004
25. [25]
  (25) Wang, R. J.; Jiang, G. H.; Ding, Y.W.;Wang, Y.; Sun, X. K.;Wang, X. H.; Chen,W. X. Appl. Mater. Interfaces 2011, 3,4154. doi: 10.1021/am201020q
26. [26]
  (26) Bhattacharyya, S. Y.; Zitoun, D.; Gedanken, A. J. Phys. Chem.C 2008, 112, 7624. doi: 10.1021/jp801353w
27. [27]
  (27) Bhattacharyya, S. Y.; Estrin, Y.; Rich, D. H.; Zitoun, D.;Gedanken, A. J. Phys. Chem. C 2010, 114, 22002. doi: 10.1021/jp107083f
28. [28]
  (28) Mahendirana, C.; Maiyalaganb, T.; Scottb, K.; Gedanken, A.Mater. Chem. Phys. 2011, 128, 341. doi: 10.1016/j.matchemphys.2011.02.067
29. [29]
  (29) Yang, H.; An, T. C.; Li, G. Y.; Song,W. H.; Cooper,W. J.; Luo,H. Y.; Guo, X. D. J. Hazard. Mater. 2010, 179, 834. doi: 10.1016/j.jhazmat.2010.03.079
30. [30]
  (30) Wu, J.; Zhang, H.; Oturan, N.;Wang, Y.; Chen, L.; Oturan, M.A. Chemosphere 2012, 87, 614. doi: 10.1016/j.chemosphere.2012.01.036
31. [31]
  (31) Lu, Z. Y.; Huo, P.W.; Luo, Y. Y.; Liu, X. L.;Wu, D.; Gao, X.;Li, C. X.; Yan, Y. S. J. Mol. Catal. A: Chem. 2013, 378, 91.doi: 10.1016/j.molcata.2013.06.001
1. [1]
  Jiahui YU , Jixian DONG , Yutong ZHAO , Fuping ZHAO , Bo GE , Xipeng PU , Dafeng ZHANG . The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO₄:Yb³⁺,Er³⁺ photocatalyst. Journal of Fuel Chemistry and Technology, 2025, 53(3): 348-359. doi: 10.1016/S1872-5813(24)60514-1
2. [2]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
3. [3]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
4. [4]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
5. [5]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
6. [6]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
7. [7]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
8. [8]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013
9. [9]
  Xinzhe HUANG , Lihui XU , Yue YANG , Liming WANG , Zhangyong LIU , Zhongjian WANG . Preparation and visible light responsive photocatalytic properties of BiSbO₄/BiOBr. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 284-292. doi: 10.11862/CJIC.20240212
10. [10]
  Jinwang Wu , Qijing Xie , Chengliang Zhang , Haifeng Shi . 自旋极化增强ZnFe_1.2Co_0.8O₄/BiVO₄ S型异质结光催化性能降解四环素. Acta Physico-Chimica Sinica, 2025, 41(5): 100050-. doi: 10.1016/j.actphy.2025.100050
11. [11]
  Zhinan GUO , Junli WANG , Qiang ZHAO , Zhifang JIA , Zuopeng LI , Kewei WANG , Yong GUO . Cu₂O/Bi₂CrO₆ Z-scheme heterojunction: Construction and photocatalytic degradation properties for tetracycline. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 741-752. doi: 10.11862/CJIC.20240403
12. [12]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
13. [13]
  Guojie Xu , Fang Yu , Yunxia Wang , Meng Sun . Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones. University Chemistry, 2024, 39(8): 169-173. doi: 10.3866/PKU.DXHX202401060
14. [14]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
15. [15]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
16. [16]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
17. [17]
  Ping Ye , Lingshuang Qin , Mengyao He , Fangfang Wu , Zengye Chen , Mingxing Liang , Libo Deng . 荷叶衍生多孔碳的零电荷电位调节实现废水中电化学捕集镉离子. Acta Physico-Chimica Sinica, 2025, 41(3): 2311032-. doi: 10.3866/PKU.WHXB202311032
18. [18]
  Jimin HOU , Mengyang LI , Chunhua GONG , Shaozhuang ZHANG , Caihong ZHAN , Hao XU , Jingli XIE . Synthesis, structures, and properties of metal-organic frameworks based on bipyridyl ligands and isophthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 549-560. doi: 10.11862/CJIC.20240348
19. [19]
  Qingwang LIU . MoS₂/Ag/g-C₃N₄ Z-scheme heterojunction: Preparation and photocatalytic performance. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 821-832. doi: 10.11862/CJIC.20240148
20. [20]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094

Get Citation

PDF

XML

Metrics

PDF Downloads(559)
Abstract views(1179)
HTML views(49)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142