Citation: SU Chang, HUANG Qi-Fei, XU Li-Huan, ZHANG Cheng. Preparation and Performances of C-LiFePO₄/Polytriphenylamine Composite as Cathode Material for Lithium-Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2014, 30(1): 88-94. doi: 10.3866/PKU.WHXB201311072 shu

Preparation and Performances of C-LiFePO₄/Polytriphenylamine Composite as Cathode Material for Lithium-Ion Batteries

1.
1 State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, P. R. China;
2 College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang 110142, P. R. China

Received Date: 6 August 2013
Available Online: 7 November 2013
Fund Project: 国家自然科学基金(51003095，51103132) (51003095，51103132)浙江省公益性技术应用研究计划(2010C31121)资助项目 (2010C31121)

An olivine LiFePO₄/carbon (C-LiFePO₄) nanocrystallinematerial was prepared using a low-temperature solvothermalmethod, followed by a high-temperature post-annealing process. Then polytriphenylamine (PTPAn)-modified C-LiFePO₄ (C-LiFePO₄/PTPAn) was prepared, as a composite for novel cathodes for lithium-ion batteries, by solution blending of the C-LiFePO₄ nanocrystallinematerial and the electroactive conducting polymer PTPAn. The effects of PTPAn coating of the C-LiFePO₄/PTPAn samples were investigated using X-ray diffraction (XRD), scanning electronmicroscopy (SEM), transmission electronmicroscopy (TEM), electrochemical impedance spectroscopy (EIS), and galvanostatic charge-discharge testing. The results indicated that the solution blending method produced a compact PTPAn coating on the C-LiFePO₄, providing an effective electronic/ionic conducting pathway and enhancing the electrochemical activities of C-LiFePO₄-based composites. The C-LiFePO₄/10%(w) PTPAn electrode displayed an improved initial discharge capacity of 154.5mAh·g^-1 at 0.1C, a superior high-rate performance discharge capacity of 114.2 mAh·g^-1 at 10C, and excellent cycling stability.With further increases in the PTPAn content of the coating on the C-LiFePO₄/PTPAn composite, the electrochemical properties of the composite decreased. Electrochemical impedance measurements also demonstrated that the PTPAn coating significantly decreased the charge-transfer resistance of the C-LiFePO₄ electrode.
- Lithium-ion battery,
- Polytriphenylamine,
- Cathode material,
- Solution blending method,
- Electrochemical property
1. [1]
  
  (1) Srinivasan, V.; Newman, J. J. Electrochem. Soc. 2004, 151,1517. doi: 10.1149/1.1785012
2. [2]
  (2) Chung, S. Y.; Chiang, Y. M. Electrochem. Solid State Lett. 2003,6, 278. doi: 10.1149/1.1621289
3. [3]
  (3) Xie, H. M.;Wang, R. S.; Ying, J. R.; Zhang, L. Y.; Jalbout, A.F.; Yu, H. Y.; Yang, G. L.; Pan, X. M.; Su, Z. M. Adv. Mater.2006, 18, 2609.
4. [4]
  (4) Kim, D. K.; Park, H. M.; Jung, S. J.; Jeong, Y. U.; Lee, J. H.;Kim, J. J. J. Power Sources 2006, 159, 237. doi: 10.1016/j.jpowsour.2006.04.086
5. [5]
  (5) Bewlay, S. L.; Konstantinov, K.;Wang, G. X.; Dou, S. X.; Liu,H. K. Mater. Lett. 2004, 58, 1788. doi: 10.1016/j.matlet.2003.11.008
6. [6]
  (6) Wu, S. H.; Hsiao, K. M.; Liu,W. R. J. Power Sources 2005,146, 550. doi: 10.1016/j.jpowsour.2005.03.128
7. [7]
  (7) Alvaro, C.; Manuel, C. Y.; Julian, M.; Jesus, S. P.; Enrique, R.C. Eur. J. Inorg. Chem. 2006, 2006, 1758.
8. [8]
  (8) Wang, G. X.; Bewlay, S. L.; Konstantinov, K.; Liu, H. K.; Dou,S. X.; Ahn, J. H. Electrochem. Acta 2004, 50, 443. doi: 10.1016/j.electacta.2004.04.047
9. [9]
  (9) Barker, J.; Saidi, M. Y.; Swoyer, J. L. Electrochem. Solid State Lett. 2003, 6, 252. doi: 10.1149/1.1621288
10. [10]
  (10) Ni, J. F.; Zhou, H. H.; Chen, J. T.; Su, G. Y. Acta Phys. -Chim. Sin. 2004, 20, 582. [倪江锋, 周恒辉, 陈继涛, 苏光耀. 物理化学学报, 2004, 20, 582.] doi: 10.3866/PKU.WHXB20040606
11. [11]
  (11) Sun, C. S.; Zhou, Z.; Xu, Z. G.;Wei, J. P.; Bian, X. K.; Yan, J.J. Power Sources 2009, 193, 841. doi: 10.1016/j.jpowsour.2009.03.061
12. [12]
  (12) Yu, C. Y.;Wang, Z. L.; Chen, Y.; Xia, D. G.; Chu,W. S.;Wu, Z.Y. Rare Metals 2009, 28, 317. doi: 10.1007/s12598-009-0062-y
13. [13]
  (13) Liu, H.; Cao, Q.; Fu, L. J.;Wu, Y. P.;Wu, Q. H. Electrochem. Commun. 2006, 8, 1553. doi: 10.1016/j.elecom.2006.07.014
14. [14]
  (14) Sun, G.; Jin, B.; Sun, G. P.; Jin, E.; Gu, H. B.; Jiang, Q. J. Appl. Electrochem. 2011, 41, 99. doi: 10.1007/s10800-010-0213-8
15. [15]
  (15) Saravanan, K.; Balaya, P.; Reddy, M. V.; Chowdari, B. V. R.;Vittal, J. J. Energy Environ. Sci. 2010, 3, 457. doi: 10.1039/b923576k
16. [16]
  (16) Malik, R.; Burch, D.; Bazant, M.; Ceder, G. Nano Lett. 2010,10, 4123. doi: 10.1021/nl1023595
17. [17]
  (17) Recham, N.; Dupont, L.; Courty, M.; Djellab, K.; Larcher, D.;Armand, M.; Tarascon, J. M. Chem. Mater. 2009, 21, 1096. doi: 10.1021/cm803259x
18. [18]
  (18) Yang, H.;Wu, X. L.; Cao, M. H.; Guo, Y. G. J. Phys. Chem. C2009, 113, 3345. doi: 10.1021/jp808080t
19. [19]
  (19) Tarascon, J. M.; Recham, N.; Armand, M.; Chotard, J. N.;Barpanda, P.;Walker,W.; Dupont, L. Chem. Mater. 2010, 22,724. doi: 10.1021/cm9030478
20. [20]
  (20) Murugan, A. V.; Muraliganth, T.; Manthiram, A. J. Phys. Chem. C 2008, 112, 14665. doi: 10.1021/jp8053058
21. [21]
  (21) Ellis, B.; Kan,W. H.; Makahnouk,W. R. M.; Nazar, L. F.J. Mater. Chem. 2007, 17, 3248. doi: 10.1039/b705443m
22. [22]
  (22) Dokko, K.; Koizumi, S.; Kanamura, K. Chem. Lett. 2006, 35,338. doi: 10.1246/cl.2006.338
23. [23]
  (23) Dokko, K.; Koizumi, S.; Nakano, H.; Kanamura, K. J. Mater. Chem. 2007, 17, 4803. doi: 10.1039/b711521k
24. [24]
  (24) Murugan, A. V.; Muraliganth, T.; Manthiram, A. Electrochem. Commun. 2008, 10, 903. doi: 10.1016/j.elecom.2008.04.004
25. [25]
  (25) Lei, G. T.; Yi, X. H.;Wang, L.; Li, Z. H.; Zhou, J. Polym. Adv. Technol. 2009, 20, 576. doi: 10.1002/pat.v20:6
26. [26]
  (26) Huang, Y. H.; odenough, J. B. Chem. Mater. 2008, 20, 7237.doi: 10.1021/cm8012304
27. [27]
  (27) Zhao, H. B.; Yuan, A. B.; Liu, B. D.; Xing, S. Y.;Wu, X. Y.; Xu,J. Q. J. Appl. Electrochem. 2012, 42, 139. doi: 10.1007/s10800-012-0380-x
28. [28]
  (28) Liu, L. L.;Wang, X. J.; Zhu, Y. S.; Hu, C. L.;Wu, Y. P.; Holze,R. J. Power Sources 2013, 224, 290. doi: 10.1016/j.jpowsour.2012.09.100
29. [29]
  (29) Feng, J. K.; Cao, Y. L.; Ai, X. P.; Yang, H. X. J. Power Sources2008, 177, 199. doi: 10.1016/j.jpowsour.2007.10.086
30. [30]
  (30) Wang, Y.;Wang, Y.; Hosono, E.;Wang, K.; Zhou, H. Angew. Chem. Int. Edit. 2008, 47, 7461. doi: 10.1002/anie.v47:39
31. [31]
  (31) Nobili, F.; Croce, F.; Scrosat, I. B.; Marassi, R. Chem. Mater.2001, 13, 1642. doi: 10.1021/cm000600x
32. [32]
  (32) Rodrigues, S.; Munichandraiah, N.; Shukla, A. K. J. Solid State Electrochem. 1999, 3, 397. doi: 10.1007/s100080050173
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Performances of C-LiFePO4/Polytriphenylamine Composite as Cathode Material for Lithium-Ion Batteries

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通讯作者: 陈斌, bchen63@163.com

Preparation and Performances of C-LiFePO₄/Polytriphenylamine Composite as Cathode Material for Lithium-Ion Batteries