Citation: PANG Rui-Zhi, LI Xin, LI Jian-Sheng, LU Zhuang-Yu, HUANG Cheng, SUN Xiu-Yun, WANG Lian-Jun. In situ Preparation and Antifouling Performance of ZrO₂/PVDF Hybrid Membrane[J]. Acta Physico-Chimica Sinica, ;2013, 29(12): 2592-2598. doi: 10.3866/PKU.WHXB201310291 shu

In situ Preparation and Antifouling Performance of ZrO₂/PVDF Hybrid Membrane

1.
School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, P. R. China

Received Date: 24 June 2013
Available Online: 29 October 2013
Fund Project: 国家自然科学基金(51278247)资助项目 (51278247)

Polymers used in porous membrane manufacture are highly susceptible to adsorption of organic foulants. In this study, a new method for in situ preparation of a poly(vinylidene fluoride) (PVDF) based hybrid membrane is reported. The strategy in this method is to combine an ion-exchange process with a traditional immersion precipitation process. A hydrous ZrO₂ sol was synthesized by the addition of anion-exchange resin to N,N-dimethylformamide (DMF) containing zirconyl chloride. A homogeneous ZrO₂/PVDF casting solution was then obtained by dissolving PVDF in the ZrO₂ sol. The presence and dispersion states of ZrO₂ nanoparticles in the resultant membrane matrix were determined using X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM). The results indicate that the ZrO₂ nanoparticles were well dispersed throughout the PVDF matrix, and the size of the formed nanoparticles was about 10-20 nm. The membrane formation mechanism was investigated based on the viscosity, precipitation kinetics, and membrane morphology. The results indicate that the introduction of ZrO₂ nanoparticles accelerates phase inversion of the casting solution. The membrane hydrophilicity was determined using contact angle measurements. The antifouling properties were examined using antifouling experiments. The results confirm that the presence of ZrO₂ nanoparticles improves the membrane hydrophilicity and reduces protein adsorption on the membrane. This method for in situ preparation of ZrO₂/PVDF hybrid membranes by combining an ion-exchange process with a traditional immersion precipitation process is valuable in the fabrication and applications of organic-inorganic hybrid membranes.
- PVDF membrane,
- In situ preparation,
- Ion-exchange,
- ZrO₂ sol,
- Sol-gel process
1. [1]
  
  (1) Shannon, M. A.; Bohn, P.W.; Elimelech, M.; Georgiadis, J. G.;Marinas, B. J.; Mayes, A. M. Nature 2008, 452, 301. doi: 10.1038/nature06599
2. [2]
  (2) Rosenberger, S.; Laabs, C.; Lesjean, B.; Gnirss, R.; Amy, G.;Jekel, M.; Schrotter, J. C. Water Res. 2006, 40, 710. doi: 10.1016/j.watres.2005.11.028
3. [3]
  (3) Yang,W.; Cicek, N.; IIg, J. J. Membr. Sci. 2006, 270, 201. doi: 10.1016/j.memsci.2005.07.010
4. [4]
  (4) Kimura, K.; Yamato, N.; Yamamura, H.;Watanabe, Y. Environ. Sci. Technol. 2005, 39, 6293. doi: 10.1021/es0502425
5. [5]
  (5) Rana, D.; Matsuura, T. Chem. Rev. 2010, 110 (4), 2448. doi: 10.1021/cr800208y
6. [6]
  (6) Tamaki, R.; Chujo, Y.; Kuraoka, K.; Yazawa, T. J. Mater. Chem.1999, 9, 1741. doi: 10.1039/a809059i
7. [7]
  (7) Navarra, M. A.; Croce, F.; Scrosati, B. J. Mater. Chem. 2007,17, 3210. doi: 10.1039/b702322g
8. [8]
  (8) Wen, S.; ng, C. L.; Tsai, F. C.; Yeh, J. T. Acta Phys. -Chim. Sin. 2011, 27 (8), 1886. [文胜, 龚春丽, 蔡芳昌, 叶正涛.物理化学学报, 2011, 27 (8), 1886.] doi: 10.3866/PKU.WHXB20110737
9. [9]
  (9) ng, C. L.; Zhou, Y.; Yan, L. C.;Wen, S.; Zheng, G.W. Acta Phys. -Chim. Sin. 2010, 26 (11), 2967. [龚春丽, 周毅, 闫礼成, 文胜, 郑根稳. 物理化学学报, 2010, 26 (11), 2967.] doi: 10.3866/PKU.WHXB20101124
10. [10]
  (10) Lu, Y.; Yu, S. L.; Chai, B. X.; Shun, X. J. Membr. Sci. 2006,276, 162. doi: 10.1016/j.memsci.2005.09.044
11. [11]
  (11) Yu, L. Y.; Xu, Z. L.; Shen, H. M.; Yang, H. J. Membr. Sci. 2009,337, 257. doi: 10.1016/j.memsci.2009.03.054
12. [12]
  (12) Han, P.; Yahui, H.; Yang,W.; Linlin, L. J. Membr. Sci. 2006,284, 9. doi: 10.1016/j.memsci.2006.07.052
13. [13]
  (13) Bottino, A.; Capannelli, G.; Comite, A. Desalination 2002, 146,35. doi: 10.1016/S0011-9164(02)00469-1
14. [14]
  (14) Oh, S. J.; Kim, N.; Lee, Y. T. J. Membr. Sci. 2009, 345, 13. doi: 10.1016/j.memsci.2009.08.003
15. [15]
  (15) Li, J. S.; Liang, Y.;Wang, H. Y.; Sun, X. Y.;Wang, L. J. Acta Polym. Sin. 2004, No. 5, 709. [李健生, 梁祎, 王慧雅, 孙秀云, 王连军. 高分子学报, 2004, No. 5, 709.]
16. [16]
  (16) Maximous, N.; Nakhla, G.;Wan,W.;Wong, K. J. Membr. Sci.2010, 352, 222. doi: 10.1016/j.memsci.2010.02.021
17. [17]
  (17) PukÃnszky, B.; Fekete, E. Polym. Polym. Compos. 1998, 6, 313.
18. [18]
  (18) Razmjou, A.; Mansouri, J.; Chen, V. J. Membr. Sci. 2011, 378,73. doi: 10.1016/j.memsci.2010.10.019
19. [19]
  (19) Pang, R. Z.; Li, J. S.;Wei, K. J.; Sun, X. Y.; Shen, J. Y.; Han,W.Q.;Wang, L. J. J. Colloid Interface Sci. 2011, 364, 373. doi: 10.1016/j.jcis.2011.09.001
20. [20]
  (20) Yang, X.; Zhang, B.; Liu, Z.; Deng, B.; Yu, M.; Li, L.; Jiang, H.;Li, J. J. Mater. Chem. 2011, 21, 11908. doi: 10.1039/c1jm11348h
21. [21]
  (21) Deng, B.; Yu, M.; Yang, X.; Zhang, B.; Li, L.; Xie, L.; Li, J.;Lu, X. J. Membr. Sci. 2010, 350, 252. doi: 10.1016/j.memsci.2009.12.035
22. [22]
  (22) Bhattarai, J.; Akiyama, E.; Habazaki, H.; Kawashima, A.;Asami, K.; Hashimoto, K. Corrosion Sci. 1997, 39, 355. doi: 10.1016/S0010-938X(97)83351-3
23. [23]
  (23) Cao, X.; Ma, J.; Shi, X.; Ren, Z. Appl. Surf. Sci. 2006, 253,2003. doi: 10.1016/j.apsusc.2006.03.090
24. [24]
  (24) Yang, Y. N.;Wu, J.; Chen, X. S.; Zhang, H. X. J. Membr. Sci.2008, 311, 200. doi: 10.1016/j.memsci.2007.12.014
25. [25]
  (25) Otsuka, T.; Chujo, Y. Polymer 2009, 50, 3174. doi: 10.1016/j.polymer.2009.05.018
26. [26]
  (26) Kim, I. C.; Lee, K. H.; Tak, T. M. J. Membr. Sci. 2001, 183,235. doi: 10.1016/S0376-7388(00)00588-3
27. [27]
  (27) Yang, Y.; Zhang, H.;Wang, P.; Zheng, Q.; Li, J. J. Membr. Sci.2007, 288, 231. doi: 10.1016/j.memsci.2006.11.019
28. [28]
  (28) Liu, F.; Abed, M. R. M.; Li, K. J. Membr. Sci. 2011, 366,97. doi: 10.1016/j.memsci.2010.09.044
1. [1]
  Feng Liang , Desheng Li , Yuting Jiang , Jiaxin Dong , Dongcheng Liu , Xingcan Shen . Method Exploration and Instrument Innovation for the Experiment of Colloid ζ Potential Measurement by Electrophoresis. University Chemistry, 2024, 39(5): 345-353. doi: 10.3866/PKU.DXHX202312009
2. [2]
  Xinyu Liu , Weiran Hu , Zhengkai Li , Wei Ji , Xiao Ni . Algin Lab: Surging Luminescent Sea. University Chemistry, 2024, 39(5): 396-404. doi: 10.3866/PKU.DXHX202312021
3. [3]
  Yan ZHAO , Jiaxu WANG , Zhonghu LI , Changli LIU , Xingsheng ZHAO , Hengwei ZHOU , Xiaokang JIANG . Gd³⁺-doped Sc₂W3O₁₂: Eu³⁺ red phosphor: Preparation and luminescence performance. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 461-468. doi: 10.11862/CJIC.20240316
4. [4]
  Ziliang KANG , Jiamin ZHANG , Hong AN , Xiaohua LIU , Yang CHEN , Jinping LI , Libo LI . Preparation and water adsorption properties of CaCl₂@MOF-808 in-situ composite moulded particles. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2133-2140. doi: 10.11862/CJIC.20240282
5. [5]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
6. [6]
  Shiqi Peng , Yongfang Rao , Tan Li , Yufei Zhang , Jun-ji Cao , Shuncheng Lee , Yu Huang . Regulating the electronic structure of Ir single atoms by ZrO₂ nanoparticles for enhanced catalytic oxidation of formaldehyde at room temperature. Chinese Chemical Letters, 2024, 35(7): 109219-. doi: 10.1016/j.cclet.2023.109219
7. [7]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
8. [8]
  Lan Ma , Cailu He , Ziqi Liu , Yaohan Yang , Qingxia Ming , Xue Luo , Tianfeng He , Liyun Zhang . Magical Surface Chemistry: Fabrication and Application of Oil-Water Separation Membranes. University Chemistry, 2024, 39(5): 218-227. doi: 10.3866/PKU.DXHX202311046
9. [9]
  Qiuyang LUO , Xiaoning TANG , Shu XIA , Junnan LIU , Xingfu YANG , Jie LEI . Application of a densely hydrophobic copper metal layer in-situ prepared with organic solvents for protecting zinc anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1243-1253. doi: 10.11862/CJIC.20240110
10. [10]
  Pengyang FAN , Shan FAN , Qinjin DAI , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Xiaoxiao HUANG , Yong ZHANG . Preparation and performance of rich 1T-MoS₂ nanosheets for high-performance aqueous zinc ion battery cathode materials. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 675-682. doi: 10.11862/CJIC.20240339
11. [11]
  Shasha Ma , Zujin Yang , Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr₂O₇²⁻: A Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(8): 314-323. doi: 10.3866/PKU.DXHX202401008
12. [12]
  Dong-Bing Cheng , Junxin Duan , Haiyu Gao . Experimental Teaching Design on Chitosan Extraction and Preparation of Antibacterial Gel. University Chemistry, 2024, 39(2): 330-339. doi: 10.3866/PKU.DXHX202308053
13. [13]
  Qingyang Cui , Feng Yu , Zirun Wang , Bangkun Jin , Wanqun Hu , Wan Li . From Jelly to Soft Matter: Preparation and Properties-Exploring of Different Kinds of Hydrogels. University Chemistry, 2024, 39(9): 338-348. doi: 10.3866/PKU.DXHX202309046
14. [14]
  Haoxiang Zhang , Zhihan Zhao , Yongchen Jin , Zhiqiang Niu , Jinlei Tian . Synthesis of an Efficient Absorbent Gel: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(11): 251-258. doi: 10.12461/PKU.DXHX202401084
15. [15]
  Biao Fang , Runwei Mo . PVDF-based solid-state battery. Chinese Journal of Structural Chemistry, 2024, 43(8): 100347-100347. doi: 10.1016/j.cjsc.2024.100347
16. [16]
  Jianyu Qin , Yuejiao An , Yanfeng Zhang . In Situ Assembled ZnWO₄/g-C₃N₄ S-Scheme Heterojunction with Nitrogen Defect for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408002-. doi: 10.3866/PKU.WHXB202408002
17. [17]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
18. [18]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
19. [19]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-. doi: 10.3866/PKU.WHXB202402016
20. [20]
  Lijuan Liu , Xionglei Wang . Preparation of Hydrogels from Waste Thermosetting Unsaturated Polyester Resin by Controllable Catalytic Degradation: A Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 313-318. doi: 10.12461/PKU.DXHX202403060

Get Citation

PDF

XML

Metrics

PDF Downloads(742)
Abstract views(658)
HTML views(12)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

In situ Preparation and Antifouling Performance of ZrO2/PVDF Hybrid Membrane

Metrics

通讯作者: 陈斌, bchen63@163.com

In situ Preparation and Antifouling Performance of ZrO₂/PVDF Hybrid Membrane