Citation: ZHAO Xue-Ting, DONG Yong-Chun, CHENG Bo-Wen, KANG Wei-Min. Coordination Kinetics of Fe³⁺ with Membranes Based on Modified PAN Nanofibers with Different Diameters, and Catalytic Effect of Their Complexes on Decomposition of Organic Dye[J]. Acta Physico-Chimica Sinica, ;2013, 29(12): 2513-2522. doi: 10.3866/PKU.WHXB201310233 shu

Coordination Kinetics of Fe³⁺ with Membranes Based on Modified PAN Nanofibers with Different Diameters, and Catalytic Effect of Their Complexes on Decomposition of Organic Dye

1.
1 Division of Textile Chemistry & Ecology, School of Textiles, Tianjin Polytechnic University, Tianjin 300387, P. R. China;
2 Key Laboratory of Advanced Textile Composites, Ministry of Education, Tianjin Polytechnic University, Tianjin 300387, P. R. China

Received Date: 12 August 2013
Available Online: 23 October 2013
Fund Project: 天津市应用基础与前沿技术重点研究计划(11JCZDJC24600, 11ZCKFGX03200) (11JCZDJC24600, 11ZCKFGX03200)国家自然科学基金(2020773093, 51102178)资助项目 (2020773093, 51102178)

Membranes produced from modified polyacrylonitrile (PAN) nanofibers with different diameters were prepared by electrospinning and amidoximation. They were then used as ligands to coordinate with Fe³⁺ for preparing modified PAN nano-fibrous membrane Fe complexes. The coordination kinetics of three modified PAN nano-fibrous membranes with Fe³⁺ were studied, and the effects of temperature and the Fe³⁺ initial concentration on the coordination kinetics were also examined. Finally, the catalytic activities of the three modified PAN nano- fibrous membrane Fe complexes were evaluated as heterogeneous Fenton catalysts in the degradation of an organic dye. The effect of fiber diameter on the catalytic activity of the complexes was investigated. The results indicated that within the observed temperature and concentration ranges, the equilibrium data for the coordination of Fe³⁺ with the modified PAN nano-fibrous membranes correlated with the Langmuir and Freundlich isotherm equations, but the coordination kinetics showed better agreement with the Lagergren second-order equation. Modified PAN nanofibrous membranes with small diameters showed higher Fe- coordinating capacities and reaction rate constants under the same conditions, indicating that they reacted with Fe³⁺ more easily than the others did. Better catalytic activities for dye degradation were found for the three modified PAN nanofibrous membrane Fe complexes in the dark, and these were further improved by light irradiation. The catalytic activities of the complexes were significantly affected by the nanofiber diameter. The complex prepared using a modified PAN nanofibrous membrane with fibers of an appropriate diameter exhibited the best catalytic activity.
- PAN nano-fibrous membrane,
- Fe³⁺,
- Coordination kinetics,
- Photocatalysis,
- Fenton reaction,
- Dye degradation
1. [1]
  
  (1) Janiak, C. Chem. Soc. Dalton Trans. 2003, 14 (6), 2781.
2. [2]
  (2) Vassilev, K.; Turmanova, S. Polym. Bull. 2008, 60 (2), 243.
3. [3]
  (3) Wu, S. H.; Xie, Q. X.; Zhu, C. Y.; Huang,W. P.; Yang, X. L.;Wu,W. Y. Polym. Mater. Sci. Eng. 2000, 16 (3), 1. [吴世华,解勤兴, 朱常英, 黄唯平, 杨秀檩, 吴文艳. 高分子材料科学与工程, 2000, 16 (3), 1.]
4. [4]
  (4) Espenson, J. H. Chemical Kinetics and Reaction Mechanisms,2nd ed.; McGraw-Hill Inc: New York, 1995; pp 1-3.
5. [5]
  (5) Xu, Y. Chemical Reaction Kinetics; Chemical Industry Press:Beijing, 2005; pp 151-153. [许越. 化学反应动力学. 北京:化学工业出版社, 2005: 151-153.]
6. [6]
  (6) Zhang, D. Y.;Wu, Z. C.; Zhou, K.; Chen, P. G. Polym. Mater. Sci. Eng. 2008, 24 (6), 38. [张宇东, 吴之传, 周凯, 陈培根.高分子材料科学与工程, 2008, 24 (6), 38.]
7. [7]
  (7) Dong, Y. C.;Wu, J. N.; Sun, S. T.; Zheng, X.; Han, Z. B.; Liu,C. Y. Journal of Sichuan University (Engineering Science Edition) 2011, 43 (1), 173. [董永春, 武金娜, 孙苏婷, 郑戌,韩振邦, 刘春燕. 四川大学学报(工程科学版), 2011, 43 (1),173.]
8. [8]
  (8) Han, Z. B.; Dong, Y. C.; Liu, C. Y. Chem. J. Chin. Univ. 2010,31 (5), 986. [韩振邦, 董永春, 刘春燕. 高等学校化学学报,2010, 31 (5), 986.]
9. [9]
  (9) Bagheri, B.; Abdouss, M.; Aslzadeh, M. M.; Shoushtari, A. M.Iran. Polym. J. 2010, 19 (12), 911.
10. [10]
  (10) Feng, Q.;Wang, Q. Q.; Tang, B.;Wei, A. F.;Wang, X. Q.;Wei,Q. F.; Huang, F. L.; Cai, Y. B.; Hou, D. Y.; Bi, S. M. Polym. Int.2013, 62 (2), 251. doi: 10.1002/pi.2013.62.issue-2
11. [11]
  (11) Kampalanonwat, P.; Supaphol, P. ACS Appl. Mater. Inter. 2010,2 (2), 3619.
12. [12]
  (12) Ishtchenko, V. V.; Huddersman, K. D.; Vitkovskaya, R. F. Appl. Catal. A. 2003, 242 (1), 123. doi: 10.1016/S0926-860X(02)00511-2
13. [13]
  (13) Ishtchenko, V. V.; Huddersman, K. D.; Vitkovskaya, R. F. Appl. Catal. A 2003, 242 (2), 221. doi: 10.1016/S0926-860X(02)00512-4
14. [14]
  (14) Vitkovskaya, R. F.; Rumynskaya, I. G.; Romanova, E. P.;Tereshchenko, L. Y. Fiber Chem. 2003, 35 (3), 202. doi: 10.1023/A:1026109923284
15. [15]
  (15) Dong, Y. C.; Du, F.; Han, Z. B. Acta Phys. -Chim. Sin. 2008, 24 (11), 2114. [董永春, 杜芳, 韩振邦. 物理化学学报, 2008,24 (11), 2114.] doi: 10.3866/PKU.WHXB20081130
16. [16]
  (16) Dong, Y. C.; Han, Z. B.; Liu, C. Y.; Du, F. Sci. Total. Environ.2010, 408 (10), 2245. doi: 10.1016/j.scitotenv.2010.01.020
17. [17]
  (17) Han, Z. B.; Dong, Y. C.; Dong, S. M. J. Hazard. Mater. 2011,189 (1-2), 241. doi: 10.1016/j.jhazmat.2011.02.026
18. [18]
  (18) Dong, Y. C.; Dong,W. J.; Han, Z. B. Catal. Today 2011, 175 (1),299. doi: 10.1016/j.cattod.2011.04.026
19. [19]
  (19) Yang, X.W.; Luo, Y. Y. Textbook of Chemical Products: Dyestuffs; Chemical Industry Press: Beijing, 2005; pp 156-541.[杨新玮, 罗钰言. 化工产品手册: 染料. 北京: 化学工业出版社, 2005: 156-541.]
20. [20]
  (20) Li, S. F.; Chen, J. P.;Wu,W. T. J. Mol. Catal. B 2007, 47 (3-4),117. doi: 10.1016/j.molcatb.2007.04.010
21. [21]
  (21) Feng, Q.;Wang, X. Q.;Wei, Q. F.; Hou, D. Y.;Wei, L.; Liu, X.H.;Wang, Z. Q. Fiber. Polym. 2011, 12 (8), 1025. doi: 10.1007/s12221-011-1025-0
22. [22]
  (22) Neghlani, P. K.; Rafizadeh, M.; Taromi, F. A. J. Hazard. Mater.2011, 186 (1), 182. doi: 10.1016/j.jhazmat.2010.10.121
23. [23]
  (23) Lee, K. H.; Kim, H. Y.; Khil, M. S.; Ra, Y. M.; Lee, D. R.Polym. 2003, 44 (4), 1287. doi: 10.1016/S0032-3861(02)00820-0
24. [24]
  (24) Vassilev, K.; Turmanova, S. Polym. Bull. 2005, 1 (5), 575.
25. [25]
  (25) Qin, X. H.;Wang, X.W.; Hu, Z. M.; Liu, Z. F.;Wang, S. Y.Journal of Donghua University (Natural Science) 2005, 31 (6),16. [覃小红, 王新威, 胡祖明, 刘兆峰, 王善元. 东华大学学报(自然科学版), 2005, 31 (6), 16.]
26. [26]
  (26) Yordem, O. S.; Papila, M.; Menceloglu, Y. Z. Mater. Des. 2008,29 (1), 34. doi: 10.1016/j.matdes.2006.12.013
27. [27]
  (27) Wang, N.; Burugapalli, K.; Song,W.; Hall, J.; Moussy, F.;Zheng, Y. D.; Ma, Y. X.;Wu, Z. T.; Li, K. J. Membr. Sci. 2013,427 (10), 207.
28. [28]
  (28) Chen, X.; Chen, N. L. Journal of DongHua University (Natural Science) 2009, 35 (1), 30. [陈霄, 陈南梁. 东华大学学报(自然科学版), 2009, 35 (1), 30.]
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Coordination Kinetics of Fe3+ with Membranes Based on Modified PAN Nanofibers with Different Diameters, and Catalytic Effect of Their Complexes on Decomposition of Organic Dye

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通讯作者: 陈斌, bchen63@163.com

Coordination Kinetics of Fe³⁺ with Membranes Based on Modified PAN Nanofibers with Different Diameters, and Catalytic Effect of Their Complexes on Decomposition of Organic Dye