Citation: ZHANG Hui, YAN Jian-Xin, WU Shu-Ting, LI Dan, WAN Shi-Gang, DING Lei, LIN Li-Rong. Further Understanding on the Measurement Methods for Solid-State Circular Dichroism Spectroscopy——Discussion on Concentration Effects[J]. Acta Physico-Chimica Sinica, ;2013, 29(12): 2481-2497. doi: 10.3866/PKU.WHXB201310152 shu

Further Understanding on the Measurement Methods for Solid-State Circular Dichroism Spectroscopy——Discussion on Concentration Effects

ZHANG Hui ^1,3, ,
YAN Jian-Xin ¹ ,
WU Shu-Ting ^2, ,
LI Dan ¹ ,
WAN Shi-Gang ¹ ,
DING Lei ¹ ,
LIN Li-Rong ¹

1.
1 Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China;
2 Department of Chemistry, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, P. R. China;
3 State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Struture of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China

Received Date: 19 July 2013
Available Online: 15 October 2013
Fund Project: 国家自然科学基金(21273175, 21271150, 21001026) (21273175, 21271150, 21001026)中国科学院福建物质结构研究所结构化学国家重点实验室基金(20110006, 20130008)资助项目 (20110006, 20130008)

In this paper, the recent developments in measurement methods of solid-state circular dichroism (CD) spectroscopy were summarized and discussed, especially the effects of concentration on solid-state CD spectral distortions. By reinspection and introspection of the solid-state CD spectra of four reported compounds, concentration gradient measurements were proved to be necessary for appropriate concentrations, which are greatly related to the chiroptical properties. The thin film solid-state CD measurements of the inherently chiral atropisomer (S)-1,1'-bi-2-naphthol (S-BINOL) were carried out with concentration gradient measurements. Using this film-state technique for the first time, the results show some subtle correlations between the CD curves and the special concentrations.
- Solid-state chiroptical spectroscopy,
- Circular dichroism,
- Method of measurement,
- Concentration effect,
- Atropisomerism,
- Mirror symmetry breaking
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