Citation: LUAN Yun-Bo, FENG Yu-Jie, WANG Wen-Xin, XIE Ming-Zheng, JING Li-Qiang. Synthesis of BiOBr-TiO₂ Nanocrystalline Composite by Microemulsion-Like Chemical Precipitation Method and Its Photocatalytic Activity[J]. Acta Physico-Chimica Sinica, ;2013, 29(12): 2655-2660. doi: 10.3866/PKU.WHXB201310141 shu

Synthesis of BiOBr-TiO₂ Nanocrystalline Composite by Microemulsion-Like Chemical Precipitation Method and Its Photocatalytic Activity

1.
1 National Engineer Research Centar of Urban Water Resources, Harbin Institute of Technology, State Key Laboratory of Urban Water Resource and Environment, Harbin 150090, P. R. China;
2 Key Laboratory of Functional Inorganic Materials Chemistry, Ministry of Education, Heilongjiang University, Harbin 150080, P. R. China

Received Date: 17 July 2013
Available Online: 14 October 2013
Fund Project: 国家自然科学基金(21071048)资助项目 (21071048)

Nanocrystalline BiOBr-TiO₂ composite has been prepared using a microemulsion-like chemical precipitation method. The key to this method is the dual role of Br^- in the synthetic process. The Br^- of cetyl trimethyl ammonium bromide is able to link the cetyltrimethyl ammonium cation with anatase TiO₂ to form a water-in-oil microemulsion-like system. Meanwhile, Br^- is also a bromine source favorable for the fabrication of a nanoheterostructure between BiOBr and TiO₂. Compared with pure TiO₂ and BiOBr-TiO₂ composite obtained using a traditional aqueous system, the as-obtained BiOBr-TiO₂ displays high photogenerated charge separation, responsible for excellent photocatalytic activity for degrading liquid-phase phenol solution and gas-phase acetaldehyde. This result is ascribed to its effective heterostructure.
- TiO₂,
- BiOBr,
- Microemulsion-like chemical precipitation method,
- Nanocomposite,
- Photocatalysis
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of BiOBr-TiO2 Nanocrystalline Composite by Microemulsion-Like Chemical Precipitation Method and Its Photocatalytic Activity

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通讯作者: 陈斌, bchen63@163.com

Synthesis of BiOBr-TiO₂ Nanocrystalline Composite by Microemulsion-Like Chemical Precipitation Method and Its Photocatalytic Activity