Citation: CAO Chong-Jiang, LIU Xiao-Geng, JU Xing-Rong, CHEN Xiao-Rong. Design, Synthesis and Characterization of Pt/Fe Bimetallic Fischer-Tropsch Catalyst[J]. Acta Physico-Chimica Sinica, ;2013, 29(11): 2475-2480. doi: 10.3866/PKU.WHXB201310101 shu

Design, Synthesis and Characterization of Pt/Fe Bimetallic Fischer-Tropsch Catalyst

1.
1 Department of Applied Catalysis, Nanjing University of Finance and Economics, Nanjing 210046, P. R. China;
2 Department of Chemical Engineering, University of Illinois, Chica , IL 60607, USA;
3 College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, P. R. China

Received Date: 29 July 2013
Available Online: 10 October 2013
Fund Project: 国家科技部支撑计划(2011BAD03B02)资助 (2011BAD03B02)

An efficient method for preparing highly dispersed bimetallic catalysts is described based on the different Point Zero Charges of Fe₂O₃ and SiO₂. The strong electrostatic adsorption (SEA) technique was applied to the preparation of Pt-promoted Fe/SiO₂ by driving the Pt precursor onto the Fe₂O₃ phase instead of the silica support. Characterization of the samples was carried out using N₂ adsorptiondesorption, X-ray diffraction (XRD), scanning transmission electron microscopy (STEM), and energy dispersive X-ray spectroscopy (EDS). The results showed that the SEA method can control the uptake of Pt onto the transition metal oxide instead of silica, forming tight coupling between the Pt and transition metal after reduction. Compared with the incipient wetness (IW) method, the SEA technique produced more intimately designed bimetallic particles with small, uniform distribution after reduction. The particle size is about 2 nm. From Fischer-Tropsch (F-T) reaction, the catalyst using SEA shows higher F-T activity and stability. The conversion is more than 51% after 150 h on the stream.
- Strong electrostatic adsorption,
- Catalyst,
- Fischer-Tropsch synthesis,
- Iron oxide,
- Silica
1. [1]
  
  (1) Liu, L. T.; Sun, G.;Wang, C.; Yang, J. H.; Xiao, C. X.;Wang,H.; Ma, D.; Kou, Y. Catal. Today 2012, 183, 136. doi: 10.1016/j.cattod.2011.09.040
2. [2]
  (2) Kang, J. C.; Cheng, K.; Zhang, L.; Zhang, Q.; Ding, J. S.; Hua,W. Q.; Lou, Y. C.; Zhai, Q. G.;Wang, Y. Angew. Chem. 2011,123, 5306. doi: 10.1002/ange.v123.22
3. [3]
  (3) Zhou,W.; Fang, K. G.; Chen, J. G.; Sun, Y. H. Chem. J. Chin. Univ. 2006, 27, 1080. [周玮, 房克功, 陈建刚, 孙予罕. 高等学校化学学报, 2006, 27, 1080.]
4. [4]
  (4) Wan, H. J.;Wu, B. S.; An, X.; Tao, Z. C. Acta Phys. -Chim. Sin.2007, 23, 1151. [万海军, 吴宝山, 安霞, 陶智超. 物理化学学报, 2007, 23, 1151.] doi: 10.1016/S1872-1508(07)60059-X
5. [5]
  (5) Yang, Y.; Xiang, H.W.; Xu, Y. Y.; Bai, L.; Li, Y.W. Appl. Catal. A 2004, 266, 181. doi: 10.1016/j.apcata.2004.02.018
6. [6]
  (6) Bukur, D.; B.; Sivaraj, C. Appl. Catal. A 2002, 231, 201. doi: 10.1016/S0926-860X(02)00053-4
7. [7]
  (7) Zhang, H.; Chu,W. Progress in Chemistry 2009, 21, 622.[张辉, 储伟. 化学进展, 2009, 21, 622.]
8. [8]
  (8) Schanke, D.; Vada, S.; Blekkan, E. A.; Hilmen, A. M.; Hoff, A.;Holmen, A. J. Catal. 1995, 156, 85. doi: 10.1006/jcat.1995.1234
9. [9]
  (9) Yu,W. Q.;Wu, B. S.; Jian, X.; Tao, Z. C.; Xiang, H.W.; Li, Y.W. Catal. Lett. 2008, 125, 116. doi: 10.1007/s10562-008-9524-3
10. [10]
  (10) Regalbuto, J. R.; Navada, A.; Shadid, S.; Bricker, M. L.; Chen,Q. J. Catal. 1999, 184, 335. doi: 10.1006/jcat.1999.2471
11. [11]
  (11) D′Souza, L.; Jiao, L.; Regalbuto, J. R.; Miller, J. T.; Kropf, A. J.J. Catal. 2007, 248, 165. doi: 10.1016/j.jcat.2007.03.010
12. [12]
  (12) Park, J.; Regalbuto, J. R. J. Colloid Interface Sci. 1995, 175,239. doi: 10.1006/jcis.1995.1452
13. [13]
  (13) Nath, M.; Satishkumar, B. C.; vindaraj, A.; Vinod, C. P.; Rao,C. N. R. Chem. Phys. Lett. 2000, 322, 333. doi: 10.1016/S0009-2614(00)00437-1
14. [14]
  (14) Xiang, L.; Royer, S.; Zhang, H.; Tatibouet, J. M.; Barrault, J.;Valange, S. J. Hazardous Mater. 2009, 172, 1175. doi: 10.1016/j.jhazmat.2009.07.121
15. [15]
  (15) Zhang, C. H.; Yang, Y.; Teng, B. T.; Li, T. Z.; Zheng, H. Y.;Xiang, H.W.; Li, Y.W. J. Catal. 2006, 237, 405. doi: 10.1016/j.jcat.2005.11.004
16. [16]
  (16) Jian, X.; Calvin, H. B.; Jeremy, S.; Dennis, L. E. Top. Catal.2003, 26, 55. doi: 10.1023/B:TOCA.0000012987.76556.63
17. [17]
  (17) Yang, C.; Zhao, H.; Hou, Y. L.; Ma, D. J. Am. Chem. Soc. 2012,134, 15814. doi: 10.1021/ja305048p
18. [18]
  (18) Bukur, D. B.; Sivaraj, C. Appl. Catal. A:Gen. 2002, 231, 201.doi: 10.1016/S0926-860X(02)00053-4
19. [19]
  (19) Ding, M. Y.; Yang, Y.; Xu, J.; Tao, Z. C.;Wang, H. L.;Wang,H.; Xiang, H.W.; Li, Y.W. Appl. Catal. A 2008, 345, 176. doi: 10.1016/j.apcata.2008.04.036
20. [20]
  (20) Ding, M. Y.; Yang, Y.; Xiang, H.W.; Li, Y.W. Chin. J. Catal.2010, 31, 1145. [定明月, 杨勇, 相宏伟, 李永旺. 催化学报,2010, 31, 1145.]
21. [21]
  (21) Jin, Y.; Datye, A. K. J. Catal. 2000, 196, 8. doi: 10.1006/jcat.2000.3024
22. [22]
  (22) Boudart, M.; Delbouille, A.; Dumesic, J. A.; Khammouma, S.;Topsoe, H. J. Catal. 1975, 37, 486. doi: 10.1016/0021-9517(75)90184-0
23. [23]
  (23) Guczi, L.; Kiricsi, I. Appl. Catal. A 1999, 186, 375. doi: 10.1016/S0926-860X(99)00156-8
24. [24]
  (24) Guczi, L.; Beck, A.; Horvath, A.; Horvath, D. Top. Catal. 2002,19, 157. doi: 10.1023/A:1015216205320
1. [1]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
2. [2]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
3. [3]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
4. [4]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
5. [5]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
6. [6]
  Jun LI , Huipeng LI , Hua ZHAO , Qinlong LIU . Preparation and photocatalytic performance of AgNi bimetallic modified polyhedral bismuth vanadate. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 601-612. doi: 10.11862/CJIC.20230401
7. [7]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
8. [8]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
9. [9]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
10. [10]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
11. [11]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
12. [12]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
13. [13]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
14. [14]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
15. [15]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
16. [16]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
17. [17]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
18. [18]
  Yongpo Zhang , Xinfeng Li , Yafei Song , Mengyao Sun , Congcong Yin , Chunyan Gao , Jinzhong Zhao . Synthesis of Chlorine-Bridged Binuclear Cu(I) Complexes Based on Conjugation-Driven Cu(II) Oxidized Secondary Amines. University Chemistry, 2024, 39(5): 44-51. doi: 10.3866/PKU.DXHX202309092
19. [19]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
20. [20]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346

Get Citation

PDF

XML

Metrics

PDF Downloads(585)
Abstract views(825)
HTML views(21)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142