Citation: HUANG Jian-Ye, WANG Feng-Hui, ZHAO Xiang, ZHANG Kai. Wetting Transition and Stability Testing of Superhydrophobic State[J]. Acta Physico-Chimica Sinica, ;2013, 29(11): 2459-2464. doi: 10.3866/PKU.WHXB201310081 shu

Wetting Transition and Stability Testing of Superhydrophobic State

1.
Department of Engineering Mechanics, Northwestern Polytechnical University, Xi'an 710129, Shanxi Province, P. R. China

Received Date: 31 May 2013
Available Online: 8 October 2013
Fund Project: 国家自然科学基金(11372251) (11372251)西北工业大学研究生种子基金(Z2013056)资助项目 (Z2013056)

Superhydrophobic surfaces exhibit self-cleaning, water-repellency and anti-sticking properties, and thus have potential applications in various fields. Maintaining the stability of superhydrophobicity and avoiding the intrusion of water are essential preconditions for realization of these properties. Based on the total reflection of underwater superhydrophobic interface and vacuum technique, we propose a continuous and visual method for investigating the wetting behavior and critical pressure of Cassie-Wenzel transition. The results indicate that, for a typical surface covered by asperities, the wetting transition has four stages; non-wetting stage, primary wetting stage, enhanced wetting stage, and complete wetting stage. The critical pressure during the primary wetting stage agrees with the theoretical one. The enhanced wetting stage takes place at a relatively high pressure, which drives the solid/liquid system into the complete wetting stage. In comparison with columnar microstructures, the lotus leaf does not exhibit the non-wetting stage during the wetting transition. This difference lies in their resistance mechanisms; columnar microstructures adapt to external pressure by increasing the curvature of the meniscus that hangs between pillars, while papillary microstructures adapt to external pressure by enhancing the capillary force via increased density of three-phase contact line during the wetting process.
- Superhydrophobicity,
- Wetting transition,
- Stability,
- Total reflection,
- Cassie state,
- Wenzel state
1. [1]
  
  (1) Neinhuis, C.; Barthlott,W. Ann. Botany 1997, 79, 667. doi: 10.1006/anbo.1997.0400
2. [2]
  (2) Bixler, G. D.; Bhushan, B. Phil. Trans. R. Soc. A 2011, 370,2381.
3. [3]
  (3) Gao, X. F.; Yan, X.; Yao, X.; Xu, L.; Zhang, K.; Zhang, J. H.;Yang, B.; Jiang, L. Adv. Mater. 2007, 19, 2213.
4. [4]
  (4) Sun, T.; Guo, Y.; Li,W. C.; Lu, A. H. Acta Phys. -Chim. Sin.2012, 28, 1432. [孙涛, 郭悦, 李文翠, 陆安慧. 物理化学学报, 2012, 28, 1432.] doi: 10.3866/PKU.WHXB201203151
5. [5]
  (5) Zhang, Y. F.; Yu, X. Q.; Zhou, Q. H.; Li, K. N. Acta Phys. -Chim. Sin. 2010, 26, 1457. [张友法, 余新泉, 周荃卉,李康宁. 物理化学学报, 2010, 26, 1457.] doi: 10.3866/PKU.WHXB20100532
6. [6]
  (6) Wang, S. T.; Jiang, L. Adv. Mater. 2007, 19, 3423.
7. [7]
  (7) Cassie, A. B. D.; Baxter, S. Trans. Faraday Soc. 1944, 40, 540.
8. [8]
  (8) Lichao, G.; McCarthy, T. J. Langmuir 2006, 22, 6234. doi: 10.1021/la060254j
9. [9]
  (9) Oner, D.; McCarthy, T. J. Langmuir 2000, 16, 7777. doi: 10.1021/la000598o
10. [10]
  (10) Lafuma, A.; Quéré, D. Nat. Mater. 2003, 2, 457. doi: 10.1038/nmat924
11. [11]
  (11) Tao, D.; Kripa, K. V.; Ming, H.; Nitin, B.; Chris, K.; Judith, S.;Margaret, B. Appl. Phys. Lett. 2009, 94, 133109. doi: 10.1063/1.3110054
12. [12]
  (12) Zheng, Q. S.; Yu, Y.; Zhao, Z. H. Langmuir 2005, 21, 12207.doi: 10.1021/la052054y
13. [13]
  (13) Lei, L.; Li, H.; Shi, J.; Chen, Y. Langmuir 2010, 26, 3666. doi: 10.1021/la903150h
14. [14]
  (14) Wenzel, R. N. Ind. Eng. Chem. 1936, 28, 988. doi: 10.1021/ie50320a024
15. [15]
  (15) Extrand, C.W. Langmuir 2005, 21, 10370. doi: 10.1021/la0513050
16. [16]
  (16) Extrand, C.W. Langmuir 2006, 22, 1711. doi: 10.1021/la052540l
17. [17]
  (17) Bhushan, B.; Jung, Y. C. Prog. Mater. Sci. 2011, 56, 1. doi: 10.1016/j.pmatsci.2010.04.003
18. [18]
  (18) Patankar, N. A. Langmuir 2004, 20, 7097. doi: 10.1021/la049329e
19. [19]
  (19) Patankar, N. A. Langmuir 2010, 26, 8941. doi: 10.1021/la9047424
20. [20]
  (20) Whyman, G.; Bormashenko, B. Langmuir 2011, 27, 8171. doi: 10.1021/la2011869
21. [21]
  (21) Poetes, R.; Holtzmann, K.; Franze, K.; Steiner, U. Phys. Rev. Lett. 2010, 105, 166104. doi: 10.1103/PhysRevLett.105.166104
22. [22]
  (22) Tuberquia, J. C.; Song,W. S.; Jennings, G. K. Anal. Chem.2011, 83, 6184. doi: 10.1021/ac200650z
23. [23]
  (23) Wan, Y.;Wang, Z. Q.; Xu, Z.; Liu, C. S.; Zhang, J. Y. Appl. Surf. Sci. 2011, 257, 7486. doi: 10.1016/j.apsusc.2011.03.060
24. [24]
  (24) Wang, Q.; Zhang, B.; Qua, M.; Zhang, J.; He, D. Appl. Surf. Sci.2008, 254, 2009. doi: 10.1016/j.apsusc.2007.08.039
25. [25]
  (25) Sakai, M.; Yanagisawa, T.; Nakajima, A.; Kameshima, Y.;Okada, K. Langmuir 2009, 25, 13. doi: 10.1021/la802763h
26. [26]
  (26) Zhong, X. H. Modern Fundamentals of Optics, 1st ed.; Press ofBeijing University: Beijing, 2003; pp 3-5. [钟锡华. 现代光学基础. 第一版. 北京: 北京大学出版社, 2003: 3-5.]
27. [27]
  (27) Hu, Y.; Lu, R. D.; Liu, G. J.; Hei, E. C. Physical Chemistry, 5thed.; Higher Education Press: Beijing, 2007; pp 519-528.[胡颖. 吕瑞东. 刘国杰. 黑恩成. 物理化学. 第五版. 北京: 高等教育出版社, 2007: 519-528.]
28. [28]
  (28) Emami, B.; Vahedi Tafreshi, H.; Gad-el-Hak, M.; Tepper, G. C.Appl. Phys. Lett. 2011, 98, 203106. doi: 10.1063/1.3590268
29. [29]
  (29) Christian, D.; Jurgen, R. Langmuir 2006, 22, 7652. doi: 10.1021/la061452d
1. [1]
  Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049
2. [2]
  Shitao Fu , Jianming Zhang , Cancan Cao , Zhihui Wang , Chaoran Qin , Jian Zhang , Hui Xiong . Study on the Stability of Purple Cabbage Pigment. University Chemistry, 2024, 39(4): 367-372. doi: 10.3866/PKU.DXHX202401059
3. [3]
  Xiyuan Su , Zhenlin Hu , Ye Fan , Xianyuan Liu , Xianyong Lu . Change as You Want: Multi-Responsive Superhydrophobic Intelligent Actuation Material. University Chemistry, 2024, 39(5): 228-237. doi: 10.3866/PKU.DXHX202311059
4. [4]
  Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
5. [5]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
6. [6]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
7. [7]
  Cunming Yu , Dongliang Tian , Jing Chen , Qinglin Yang , Kesong Liu , Lei Jiang . Chemistry “101 Program” Synthetic Chemistry Experiment Course Construction: Synthesis and Properties of Bioinspired Superhydrophobic Functional Materials. University Chemistry, 2024, 39(10): 101-106. doi: 10.12461/PKU.DXHX202408008
8. [8]
  Chunai Dai , Yongsheng Han , Luting Yan , Zhen Li , Yingze Cao . Preparation of Superhydrophobic Surfaces and Their Application in Oily Wastewater Treatment: Design of a Comprehensive Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(2): 34-40. doi: 10.3866/PKU.DXHX202307081
9. [9]
  Jin Tong , Shuyan Yu . Crystal Engineering for Supramolecular Chirality. University Chemistry, 2024, 39(3): 86-93. doi: 10.3866/PKU.DXHX202308113
10. [10]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013
11. [11]
  Geyang Song , Dong Xue , Gang Li . Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides. University Chemistry, 2024, 39(2): 321-329. doi: 10.3866/PKU.DXHX202308030
12. [12]
  Jia Yao , Xiaogang Peng . Theory of Macroscopic Molecular Systems: Theoretical Framework of the Physical Chemistry Course in the Chemistry “101 Plan”. University Chemistry, 2024, 39(10): 27-37. doi: 10.12461/PKU.DXHX202408117
13. [13]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
14. [14]
  Qiuyang LUO , Xiaoning TANG , Shu XIA , Junnan LIU , Xingfu YANG , Jie LEI . Application of a densely hydrophobic copper metal layer in-situ prepared with organic solvents for protecting zinc anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1243-1253. doi: 10.11862/CJIC.20240110
15. [15]
  Yangrui Xu , Yewei Ren , Xinlin Liu , Hongping Li , Ziyang Lu . 具有高传质和亲和表面的NH₂-UIO-66基疏水多孔液体用于增强CO₂光还原. Acta Physico-Chimica Sinica, 2024, 40(11): 2403032-. doi: 10.3866/PKU.WHXB202403032
16. [16]
  Rui Li , Jiayu Zhang , Anyang Li . Two Levels of Understanding of Chemical Bonds: a Case of the Bonding Model of Hypervalent Molecules. University Chemistry, 2024, 39(2): 392-398. doi: 10.3866/PKU.DXHX202308051
17. [17]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
18. [18]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
19. [19]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149

Get Citation

PDF

XML

Metrics

PDF Downloads(613)
Abstract views(715)
HTML views(11)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142