Citation: ZHU Li-Jie, HUANG Dan-Dan, LI Qin-Tang, XU Guan-Chen, CHEN Xiao. Nanofibers and Vesicles Self-Assembled fromGemini Surfactant Complexes with Bile Salts[J]. Acta Physico-Chimica Sinica, ;2013, 29(11): 2415-2421. doi: 10.3866/PKU.WHXB201309243 shu

Nanofibers and Vesicles Self-Assembled fromGemini Surfactant Complexes with Bile Salts

1.
Key Laboratory of Colloid and Interface Chemistry of the Ministry of Education, Shandong University, Jinan 250100, P. R. China

Received Date: 18 July 2013
Available Online: 24 September 2013
Fund Project: 国家自然科学基金(20973104,21033005,21373127)资助项目 (20973104,21033005,21373127)

Nanofibers and vesicles are fabricated in aqueous solution by self-assembly of complexes of cationic Gemini surfactants ((C_sH_2s-α,ω-(Me₂N⁺C_mH_2m+1Br^-)₂, m-s-m) and anionic bile salts (BS). Their morphology, structure, and properties are characterized by polarized optical microscopy (POM), transmission electron microscopy (TEM), field-emission scanning electron microscopy (FE-SEM), and X-ray powder diffraction (XRD). The morphology of these aggregates was significantly influenced by minor structural changes of the building blocks, including the spacer and alkyl chain lengths of m-s-m, and the hydroxyl group number and position on the steroid skeleton of the BS. The formation of these aggregates is considered to arise mainly fromelectrostatic interactions, with contributions fromhydrogen bonding and hydrophobic interactions. The results obtained may be helpful for understanding the mechanisms of ionic self-assembly and aid the design of novel supramolecular aggregates.
- Self-assembly,
- Gemini surfactant,
- Bile salt,
- Aggregate,
- Supramolecular interaction
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