Citation: ZHU Li-Jie, HUANG Dan-Dan, LI Qin-Tang, XU Guan-Chen, CHEN Xiao. Nanofibers and Vesicles Self-Assembled fromGemini Surfactant Complexes with Bile Salts[J]. Acta Physico-Chimica Sinica, ;2013, 29(11): 2415-2421. doi: 10.3866/PKU.WHXB201309243 shu

Nanofibers and Vesicles Self-Assembled fromGemini Surfactant Complexes with Bile Salts

1.
Key Laboratory of Colloid and Interface Chemistry of the Ministry of Education, Shandong University, Jinan 250100, P. R. China

Received Date: 18 July 2013
Available Online: 24 September 2013
Fund Project: 国家自然科学基金(20973104,21033005,21373127)资助项目 (20973104,21033005,21373127)

Nanofibers and vesicles are fabricated in aqueous solution by self-assembly of complexes of cationic Gemini surfactants ((C_sH_2s-α,ω-(Me₂N⁺C_mH_2m+1Br^-)₂, m-s-m) and anionic bile salts (BS). Their morphology, structure, and properties are characterized by polarized optical microscopy (POM), transmission electron microscopy (TEM), field-emission scanning electron microscopy (FE-SEM), and X-ray powder diffraction (XRD). The morphology of these aggregates was significantly influenced by minor structural changes of the building blocks, including the spacer and alkyl chain lengths of m-s-m, and the hydroxyl group number and position on the steroid skeleton of the BS. The formation of these aggregates is considered to arise mainly fromelectrostatic interactions, with contributions fromhydrogen bonding and hydrophobic interactions. The results obtained may be helpful for understanding the mechanisms of ionic self-assembly and aid the design of novel supramolecular aggregates.
- Self-assembly,
- Gemini surfactant,
- Bile salt,
- Aggregate,
- Supramolecular interaction
1. [1]
  
  (1) Lehn, J. M. Science 2002, 295 (5564), 2400. doi: 10.1126/science.1071063
2. [2]
  (2) Soto, E.; MacDonald, J. C.; Cooper, C. G. F.; McGimpsey,W.G. J. Am. Chem. Soc. 2003, 125 (10), 2838. doi: 10.1021/ja0289548
3. [3]
  (3) Sanchez-Ouesada, J.; Isler, M. P.; Ghadiri, M. R. J. Am. Chem. Soc. 2002, 124 (34), 10004. doi: 10.1021/ja025983+
4. [4]
  (4) Lee, M.; Jang, C. J.; Ryu, J. H. J. Am. Chem. Soc. 2004, 126 (26), 8082. doi: 10.1021/ja048264z
5. [5]
  (5) Li, C.; Numata, M.; Bae, A. H.; Sakurai, K.; Shinkai, S. J. Am. Chem. Soc. 2005, 127 (13), 4548. doi: 10.1021/ja050168q
6. [6]
  (6) Hoeben, F. J. M.; Jonkheijm, P.; Meijer, E.W.; Schenning, A.Chem. Rev. 2005, 105 (4), 1491. doi: 10.1021/cr030070z
7. [7]
  (7) Lv, C.; Chen, X.; Jing, B.; Zhao, Y.; Ma, F. J. Colloid Interface Sci. 2010, 351 (1), 63. doi: 10.1016/j.jcis.2010.07.057
8. [8]
  (8) Lv, C.; Xu, G.; Chen, X. Chem. Lett. 2012, 41 (10), 1201. doi: 10.1246/cl.2012.1201
9. [9]
  (9) Wang, X.; Chen, X.; Zhao, Y.; Yue, X.; Li, Q.; Li, Z. Langmuir2012, 28 (5), 2476. doi: 10.1021/la204489v
10. [10]
  (10) Menger, F. M.; Littau, C. A. J. Am. Chem. Soc. 1991, 113 (4),1451. doi: 10.1021/ja00004a077
11. [11]
  (11) Zana, R. Adv. Colloid Interface Sci. 2002, 97 (1-3), 205. doi: 10.1016/S0001-8686(01)00069-0
12. [12]
  (12) Zana, R.; Xia, J. D. Introduction. In Gemini Surfactants: Synthesis, Interfacial and Solution-Phase Behavior, and applications (Surfactant Science Series 117); Zana, R., Xia, J.D. Eds.; Marcel Dekker Inc.: New York, 2004; pp 1-8.
13. [13]
  (13) Menger, F. M.; Keiper, J. S. Angew. Chem. Int. Edit. 2000, 39 (11), 1907.
14. [14]
  (14) Han, Y. C.;Wang, Y. L. Phys. Chem. Chem. Phys. 2011, 13 (6),1939. doi: 10.1039/c0cp01196g
15. [15]
  (15) Zhang, L.;Wang, J. B.; Liu, M. H. Acta Phys. -Chim. Sin. 2004,20 (4), 368. [张莉, 王金本, 刘鸣华. 物理化学学报, 2004,20 (4), 368.]
16. [16]
  (16) Bombelli, C.; Giansanti, L.; Luciani, P.; Mancini, G. Curr. Med. Chem. 2009, 16 (2), 171. doi: 10.2174/092986709787002808
17. [17]
  (17) Li, Y. X.; Dias, J. R. Chem. Rev. 1997, 97 (1), 283. doi: 10.1021/cr9600565
18. [18]
  (18) Wallimann, P.; Marti, T.; Fürer, A.; Diederich, F. Chem. Rev.1997, 97 (5), 1567. doi: 10.1021/cr960373b
19. [19]
  (19) Virtanen, E.; Kolehmainen, E. Eur. J. Org. Chem. 2004, 2004 (16), 3385.
20. [20]
  (20) Cai, L. C.;Wang, Y. J.; Li, J.; Huang, J. B. Acta Phys. -Chim. Sin. 2012, 28 (10), 2298. [蔡龙成, 王一杰, 李娟, 黄建滨.物理化学学报, 2012, 28 (10), 2298.] doi: 10.3866/PKU.WHXB201209112
21. [21]
  (21) Zhang, L.; Yang, Z. L.; Xiong, Y.; Peng, T. T.;Weng, S. F.;Wu,J. G. Acta Phys. -Chim. Sin. 2004, 20 (10), 1196. [张莉, 杨展澜, 熊尧, 彭疼疼, 翁诗甫, 吴瑾光. 物理化学学报, 2004,20 (10), 1196.] doi: 10.3866/PKU.WHXB20041006
22. [22]
  (22) Zana, R.; Benrraou, M.; Rueff, R. Langmuir 1991, 7 (6),1072. doi: 10.1021/la00054a008
23. [23]
  (23) Oda, R.; Huc, I.; Candau, S. J. Chem. Commun. 1997, No. 21,2105.
24. [24]
  (24) Guan, Y.; Antonietti, M.; Faul, C. F. J. Langmuir 2002, 18 (15),5939. doi: 10.1021/la0257182
25. [25]
  (25) Fuller, S.; Shinde, N. N.; Tiddy, G. J. T. Langmuir 1996, 12 (5),1117. doi: 10.1021/la950702f
26. [26]
  (26) Wei, Z. B.;Wei, X. L.; Sun, D. Z.; Liu, J. Q.; Tang, X. J.J. Colloid Interface Sci. 2011, 354 (2), 677. doi: 10.1016/j.jcis.2010.11.009
27. [27]
  (27) Jing, B.; Chen, X.; Zhao, Y.;Wang, X.; Cai, J.; Qiu, H. J. Phys. Chem. B 2008, 112 (24), 7191. doi: 10.1021/jp801061g
28. [28]
  (28) Jing, B.; Chen, X.; Zhao, Y.;Wang, X.; Ma, F.; Yue, X. J. Mater. Chem. 2009, 19 (14), 2037. doi: 10.1039/b818006g
29. [29]
  (29) Oakenfull, D. G.; Fisher, L. R. J. Phys. Chem. 1977, 81 (19),1838. doi: 10.1021/j100534a010
30. [30]
  (30) Small, D. M.; Penkett, S. A.; Chapman, D. Biochim. Biophys. Acta 1969, 176 (1), 178. doi: 10.1016/0005-2760(69)90086-1
31. [31]
  (31) Qiao, Y.; Lin, Y. Y.;Wang, Y. J.; Yang, Z. Y.; Liu, J.; Zhou, J.;Yan, Y.; Huang, J. B. Nano Lett. 2009, 9 (12), 4500. doi: 10.1021/nl9028335
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沈阳化工大学材料科学与工程学院沈阳 110142