Citation: CHEN Qiang, NULI Yan-Na, YANG Jun, WANG Jiu-Lin, GUO Yu-Guo. PTMA/Graphene as a Novel Cathode Material for Rechargeable Magnesium Batteries[J]. Acta Physico-Chimica Sinica, ;2013, 29(11): 2295-2299. doi: 10.3866/PKU.WHXB201309241 shu

PTMA/Graphene as a Novel Cathode Material for Rechargeable Magnesium Batteries

CHEN Qiang ^1,2 ,
NULI Yan-Na ^1,2, ,
³ ,
YANG Jun ^1,2 ,
WANG Jiu-Lin ^1,2 ,
GUO Yu-Guo ^3,

1.
1 School of Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China;
2 Hirano Institute for Materials Innovation, Shanghai Jiao Tong University, Shanghai 200240, P. R. China;
3 Key Laboratory of Molecular Nanostructures and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

Received Date: 26 June 2013
Available Online: 24 September 2013
Fund Project: 国家自然科学基金(21273147) (21273147)上海市科委(11JC1405700)资助项目 (11JC1405700)

We report the synthesis of a poly(2,2,6,6-tetramethylpiperidinyloxy-4-yl methacrylate) (PTMA)/graphene nanocomposite in which graphene is used as a support for improving electronic conductivity. The structure and morphology of the nanocomposite were characterized by Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). These results reveal that a graphene surface is decorated by nanoparticles of PTMAwith an average size of 10 nm. The electrochemical performance of the PTMA/graphene composite as a cathode material in rechargeable magnesium batteries was investigated using cyclic voltammetry and galvanostatic charge/discharge techniques. In a "first generation" electrolyte Mg(AlCl₂BuEt)₂/tetrahydrofuran (THF) (0.25 mol·L^-1), the material exhibits an initial discharge capacity of 81.2 mAh·g^-1 at 22.8 mA·g^-1. Further studies will focus on improving the capacity using electrolytes with a wider electrochemical window.
- Energy storage and conversion,
- Rechargeable magnesium battery,
- Nanocomposite,
- Organic cathode material,
- Graphene
1. [1]
  
  (1) Song, Z. P.; Zhan, H.; Zhou, Y. H. Angew. Chem. Int. Edit. 2010,49, 8444. doi: 10.1002/anie.201002439
2. [2]
  (2) Chen, H.; Armand, M.; Courty, M.; Jiang, M.; Grey, C. P.;Dolhem, F.; Tarascon, J. M.; Poizot, P. J. Am. Chem. Soc. 2009,131, 8984. doi: 10.1021/ja9024897
3. [3]
  (3) Tarascon, J. M. ChemSusChem 2008, 1, 777. doi: 10.1002/cssc.v1:8/9
4. [4]
  (4) Armand, M.; Grugeon, S.; Vezin, H.; Laruelle, S.; Pibière, P.;Poizot, P.; Tarascon, J. M. Nat. Mater. 2009, 8, 120. doi: 10.1038/nmat2372
5. [5]
  (5) Armand, M.; Tarascon, J. M. Nature 2008, 451, 652. doi: 10.1038/451652a
6. [6]
  (6) Poizot, P.; Dolhem, F. Energy Environ. Sci. 2011, 4, 2003. doi: 10.1039/c0ee00731e
7. [7]
  (7) Gao, X. P.; Yang, H. X. Energy Environ. Sci. 2010, 3, 174. doi: 10.1039/b916098a
8. [8]
  (8) Novák, P.; Müller, K.; Santhanam, K. S. V.; Hass, O. Chem. Rev.1997, 97, 207. doi: 10.1021/cr941181o
9. [9]
  (9) Oyama, N.; Tatsuma, T.; Sato, T.; Sotomura, T. Nature 1995,373, 598. doi: 10.1038/373598a0
10. [10]
  (10) Song, Z. P.; Zhan, H.; Zhou, Y. H. Chem. Commun. 2009, 448.
11. [11]
  (11) Han, X. Y.; Chang, C. X.; Yuan, L. J.; Sun, T. L.; Sun, J. T. Adv. Mater. 2007, 19, 1616.
12. [12]
  (12) Zeng, R. H.; Li, X. P.; Qiu, Y. C.; Li,W. S.; Yi, J.; Lu, D. S.;Tan, C. L.; Xu, M. Q. Electrochem. Commun. 2010, 12, 1253.doi: 10.1016/j.elecom.2010.06.033
13. [13]
  (13) Suga, T.; Ohshiro, H.; Sugita, S.; Qyaizu, K.; Nishide, H. Adv. Mater. 2009, 21, 1627. doi: 10.1002/adma.v21:16
14. [14]
  (14) Qyaizu, K.; Nishide, H. Adv. Mater. 2009, 21, 2339. doi: 10.1002/adma.v21:22
15. [15]
  (15) Nakahara, K.; Iwasa, S.; Satoh, M.; Morioka, Y.; Iriyama, J.;Suguro, M.; Hasegawa, E. Chem. Phys. Lett. 2002, 359, 351.doi: 10.1016/S0009-2614(02)00705-4
16. [16]
  (16) Kim, J. K.; Ahn, J. H.; Cheruvally, G.; Chauhan, G. S.; Choi, J.W.; Kim, D. S.; Ahn, H. J.; Lee, S. H.; Song, C. E. Met. Mater. Int. 2009, 15, 77. doi: 10.1007/s12540-009-0077-9
17. [17]
  (17) Guo,W.; Yin, Y. X.; Xin, S.; Guo, Y. G.;Wan, L. J. Energy Environ. Sci. 2012, 5, 5221. doi: 10.1039/c1ee02148f
18. [18]
  (18) Aurbach, D.; Lu, Z.; Schechter, A.; fer, Y.; Gizbar, H.;Turgeman, R.; Cohen, Y.; Moshkovich, M.; Levi, E. Nature2007, 407, 724.
19. [19]
  (19) Muldoon, J.; Bucur, C. B.; Oliver, A. G.; Sugimoto, T.; Matsui,M.; Kim, H. S.; Allred, G. D.; Zajicek, J.; Kotani, Y. Energy Environ. Sci. 2012, 5, 5941. doi: 10.1039/c2ee03029b
20. [20]
  (20) Hummers,W. S.; Offeman, R. E., Jr. J. Am. Chem. Soc. 1958,80, 1339. doi: 10.1021/ja01539a017
21. [21]
  (21) Aurbach, D.; Schechter, A.; Moshkovich, M.; Cohen, Y.J. Electrochem. Soc. 2001, 148, A1004.
22. [22]
  (22) Aurbach, D.; Gizbar, H.; Schechter, A.; Chusid, O.; ttlieb, H.E.; fer, Y.; ldberg, I. J. Electrochem. Soc. 2002, 149, A115.
23. [23]
  (23) Vestfried, Y.; Chusid, O.; fer, Y.; Aped, P.; Aurbach, D.Organometallics 2007, 26, 3130. doi: 10.1021/om061076s
24. [24]
  (24) Vestfried, Y.; Levi, M. D.; fer, Y.; Aurbach, D. J. Electroanal. Chem. 2005, 576, 183. doi: 10.1016/j.jelechem.2004.09.034
25. [25]
  (25) Choucair, M.; Thordarson, P.; Stride, J. A. Nat. Nanotechnol.2009, 4, 30. doi: 10.1038/nnano.2008.365
1. [1]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
2. [2]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
3. [3]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
4. [4]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
5. [5]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
6. [6]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
7. [7]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
8. [8]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
9. [9]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
10. [10]
  Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139
11. [11]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
12. [12]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
13. [13]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
14. [14]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
15. [15]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
16. [16]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
17. [17]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
18. [18]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
19. [19]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
20. [20]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084

Get Citation

PDF

XML

Metrics

PDF Downloads(1023)
Abstract views(1692)
HTML views(88)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142