Citation: ZHANG Yu, LIN Shen, ZHANG Yu, SONG Xi-Ming. Properties of Photogenerated Charge Carriers and Visible-Light Surface Photocurrent of Heterogeneous ZnO/BiVO₄-V₂O₅ Structures[J]. Acta Physico-Chimica Sinica, ;2013, 29(11): 2399-2404. doi: 10.3866/PKU.WHXB201309061 shu

Properties of Photogenerated Charge Carriers and Visible-Light Surface Photocurrent of Heterogeneous ZnO/BiVO₄-V₂O₅ Structures

1.
Liaoning Key Laboratory for Green Synthesis and Preparative Chemistry of Advanced Materials, College of Chemistry, Liaoning University, Shenyang 110036, P. R. China

Received Date: 27 May 2013
Available Online: 6 September 2013
Fund Project: 国家自然科学基金(21203082,51273087,21071070) (21203082,51273087,21071070)辽宁省教育厅自然科学基金(LT2011001) (LT2011001)辽宁省科技厅自然科学基金(201102084) (201102084)辽宁大学青年基金(2011LDQN02)资助项目 (2011LDQN02)

Spherical and flower-like ZnO micro/nanomaterials are synthesized through a hydrothermal method. ZnO/BiVO₄-V₂O₅ composite structures are then prepared in a solution containing Bi(NO₃)₃ and NH₄VO₃.The samples were characterized by scanning electron microscopy (SEM), transmission electron microscopic (TEM), and X-ray diffraction (XRD). Surface photovoltage (SPV), surface photocurrent (SPC), and transient photovoltage (TPV) techniques were used to investigate the generation and transport mechanisms of the photogenerated charge carriers in the heterogeneous ZnO/BiVO₄-V₂O₅ structure. The composite materials show od photoelectric response to visible light. Highly efficient separation of photogenerated charge carriers is observed, and the so-formed charge carriers are long lived. Measurements of surface photocurrent by comb-like electrode were performed on the ZnO/BiVO₄-V₂O₅ system. Under irradiation by weak monochromatic light (wavelength: 500 nm), the ZnO/BiVO₄-V₂O₅composite materials generate surface photocurrent responses with od reproducibility.
- Heterogeneous structure,
- Surface photocurrent,
- Surface photovoltage,
- Transient photovoltage,
- Photogenerated charge
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Properties of Photogenerated Charge Carriers and Visible-Light Surface Photocurrent of Heterogeneous ZnO/BiVO4-V2O5 Structures

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通讯作者: 陈斌, bchen63@163.com

Properties of Photogenerated Charge Carriers and Visible-Light Surface Photocurrent of Heterogeneous ZnO/BiVO₄-V₂O₅ Structures