Citation: ZHANG Yu, LIN Shen, ZHANG Yu, SONG Xi-Ming. Properties of Photogenerated Charge Carriers and Visible-Light Surface Photocurrent of Heterogeneous ZnO/BiVO₄-V₂O₅ Structures[J]. Acta Physico-Chimica Sinica, ;2013, 29(11): 2399-2404. doi: 10.3866/PKU.WHXB201309061 shu

Properties of Photogenerated Charge Carriers and Visible-Light Surface Photocurrent of Heterogeneous ZnO/BiVO₄-V₂O₅ Structures

1.
Liaoning Key Laboratory for Green Synthesis and Preparative Chemistry of Advanced Materials, College of Chemistry, Liaoning University, Shenyang 110036, P. R. China

Received Date: 27 May 2013
Available Online: 6 September 2013
Fund Project: 国家自然科学基金(21203082,51273087,21071070) (21203082,51273087,21071070)辽宁省教育厅自然科学基金(LT2011001) (LT2011001)辽宁省科技厅自然科学基金(201102084) (201102084)辽宁大学青年基金(2011LDQN02)资助项目 (2011LDQN02)

Spherical and flower-like ZnO micro/nanomaterials are synthesized through a hydrothermal method. ZnO/BiVO₄-V₂O₅ composite structures are then prepared in a solution containing Bi(NO₃)₃ and NH₄VO₃.The samples were characterized by scanning electron microscopy (SEM), transmission electron microscopic (TEM), and X-ray diffraction (XRD). Surface photovoltage (SPV), surface photocurrent (SPC), and transient photovoltage (TPV) techniques were used to investigate the generation and transport mechanisms of the photogenerated charge carriers in the heterogeneous ZnO/BiVO₄-V₂O₅ structure. The composite materials show od photoelectric response to visible light. Highly efficient separation of photogenerated charge carriers is observed, and the so-formed charge carriers are long lived. Measurements of surface photocurrent by comb-like electrode were performed on the ZnO/BiVO₄-V₂O₅ system. Under irradiation by weak monochromatic light (wavelength: 500 nm), the ZnO/BiVO₄-V₂O₅composite materials generate surface photocurrent responses with od reproducibility.
- Heterogeneous structure,
- Surface photocurrent,
- Surface photovoltage,
- Transient photovoltage,
- Photogenerated charge
1. [1]
  
  (1) Wu, J. J.; Chen, G. R.; Yang, H. H.; Ku, C. H.; Lai, J. Y. Applied Physics Letters 2007, 90, 213109. doi: 10.1063/1.2742639
2. [2]
  (2) ng, J.; Li, Y. H.; Chai, X. S.; Hu, Z. S.; Deng, Y. L. J. Phys. Chem. C 2010, 114, 1293. doi: 10.1021/jp906043k
3. [3]
  (3) Wang, Z. Y.; Huang, B. B.; Dai, Y.; Qin, X. Y.; Zhang, X. Y.;Wang, P.; Liu, H. X.; Yu, J. X. J. Phys. Chem. C 2009, 113,4612. doi: 10.1021/jp8107683
4. [4]
  (4) Lin, D. D.;Wu, H.; Zhang, R.; Pan,W. Chem. Mater. 2009, 21,3479. doi: 10.1021/cm900225p
5. [5]
  (5) Mitra, P.; Chatterjee, A. P.; Maiti, H. S. Mater. Lett. 1998, 35,33. doi: 10.1016/S0167-577X(97)00215-2
6. [6]
  (6) le , N.; Studenikin, S. A.; Cocivera, M. J. Electrochem. Soc. 2000, 147, 1592. doi: 10.1149/1.1393400
7. [7]
  (7) Hu, X. L.; Li, G. S.; Jimmy, C. Y. Langmuir 2010, 26 (5), 3031.doi: 10.1021/la902142b
8. [8]
  (8) Sun,W. T.; Yu, Y.; Pan, H. Y.; Gao, X. F.; Chen, Q.; Peng, L. M.J. Am. Chem. Soc. 2008, 130, 1124. doi: 10.1021/ja0777741
9. [9]
  (9) Lee, H. J.; Yum, J. H.; Leventis, H. C.; Zakeeruddin, S. M.;Haque, S. A.; Chen, P.; Seok, S. I.; Grätzel, M.; Nazeeruddin,M. K. J. Phys. Chem. C 2008, 112, 11600. doi: 10.1021/jp802572b
10. [10]
  (10) Plass, R.; Serge, P.; Krüger, J.; Grätzel, M. J. Phys. Chem. B2002, 106, 7578. doi: 10.1021/jp020453l
11. [11]
  (11) Leschkies, K. S.; Divakar, R.; Basu, J.; Enache-Pommer, E.;Boercker, J. E.; Carter, C. B.; Kortshagen, U. R.; Norris, D. J.;Aydil, E. S. Nano Lett. 2007, 7, 1793. doi: 10.1021/nl070430o
12. [12]
  (12) Wang, G. M.; Yang, X. Y.; Qian, F.; Zhang, J. Z.; Li, Y. Nano Lett. 2010, 10 (3), 1088. doi: 10.1021/nl100250z
13. [13]
  (13) Hu, Y.; Li, D. Z.; Zheng, Y.; Chen,W.; He, Y. H.; Shao, Y.; Fu,X. Z.; Xiao, G. G. Applied Catalysis B: Environmental 2011,104, 30. doi: 10.1016/j.apcatb.2011.02.031
14. [14]
  (14) Xu, Y.; Schoonen, M. A. A. American Mineralogist 2000, 85,543.
15. [15]
  (15) Yang, M.;Wang, D. J.; Lin, Y. H.; Li, Z. H., Zhang, Q. L.Materials Chemistry and Physics 2004, 88, 333. doi: 10.1016/j.matchemphys.2004.07.022
16. [16]
  (16) Su, J.; Zou, X. X.; Li, G. D.;Wei, X.; Yan, C.;Wang, Y. N.;Zhao, J.; Zhou, L. J.; Chen, J. S. J. Phys. Chem. C 2011, 115,8064.
17. [17]
  (17) Cho, S.; Jang, J.W.; Jung, S. H.; Lee, B. R.; Oh, E.; Lee, K. H.Langmuir 2009, 25 (6), 3825. doi: 10.1021/la804009g
18. [18]
  (18) Gross, D.; Mora-Seró, I.; Dittrich, T.; Belaidi, A.; Mauser, C.;Houtepen, A. J.; Como, E. D.; Rogach, A. L.; Feldmann, J.J . Am. Chem. Soc. 2010, 132, 5981. doi: 10.1021/ja101629c
19. [19]
  (19) Duzhko, V.; Timoshenko, V. Y.; Koch, F.; Dittrich, T. Phys. Rev. B 2001, 64, 075204. doi: 10.1103/PhysRevB.64.075204
20. [20]
  (20) Zhang, X. R.; Lin, Y. H.; Zhang, J. F.; He, D. Q.;Wang, D. J.Acta Phys. -Chim. Sin. 2010, 26 (10), 2733. [张晓茹, 林艳红,张健夫, 何冬青, 王德军. 物理化学学报, 2010, 26 (10),2733.] doi: 10.3866/PKU.WHXB20101007
21. [21]
  (21) Zhang, Y.; Xie, T. F.; Jiang, T. F.;Wei, X., Pang, S.;Wang, X.;Wang, D. J. Nanotechnology 2009, 20, 155707. doi: 10.1088/0957-4484/20/15/155707
22. [22]
  (22) Xiao,W.; Xie, T. F.; Dan, X.; Zhao, Q. D.; Shan, P.;Wang, D. J.Nanotechnology 2008, 19, 275707. doi: 10.1088/0957-4484/19/27/275707
23. [23]
  (23) Peng, L.; Zhao, Q. D.;Wang, D. J.; Zhai, J. L.,Wang, P.; Pang,S.; Xie, T. F. Sensors and Actuators B 2009, 136, 80.
24. [24]
  (24) Anothainart, K.; Burgmai, M.; Karthigeyan, A.; Zimmer, M.;Eisele, I. Sensors and Actuators B 2003, 93, 580. doi: 10.1016/S0925-4005(03)00220-X
25. [25]
  (25) Zhang, D.; Li, C.; Han, D.; Liu, X.; Tang, T.; Jin,W.; Zhou, C.Appl. Phys. A: Mater. Sci. Process. 2003, 77, 163. doi: 10.1007/s00339-003-2099-3
26. [26]
  (26) Han, L. N.;Wang, D. J., Cui, J. B.; Chen, L. P.; Jiang, T. F.; Lin,Y. H. J. Mater. Chem. 2012, 22, 12915. doi: 10.1039/c2jm16105b
1. [1]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . 钠离子电池中铁基异质结构负极材料的最新研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-. doi: 10.3866/PKU.WHXB202311015
2. [2]
  Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
3. [3]
  Liyong DU , Yi LIU , Guoli YANG . Preparation and triethylamine sensing performance of ZnSnO₃/NiO heterostructur. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 729-740. doi: 10.11862/CJIC.20240404
4. [4]
  Yujia LI , Tianyu WANG , Fuxue WANG , Chongchen WANG . Direct Z-scheme MIL-100(Fe)/BiOBr heterojunctions: Construction and photo-Fenton degradation for sulfamethoxazole. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 481-495. doi: 10.11862/CJIC.20230314
5. [5]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
6. [6]
  Xin Lv , Hongxing Zhang , Kaibo Duan , Wenhui Dai , Zhihui Wen , Wei Guo , Junsheng Hao . Lighting the Way Against Cancer: Photodynamic Therapy. University Chemistry, 2024, 39(5): 70-79. doi: 10.3866/PKU.DXHX202309090
7. [7]
  Yuejiao An , Wenxuan Liu , Yanfeng Zhang , Jianjun Zhang , Zhansheng Lu . Revealing Photoinduced Charge Transfer Mechanism of SnO₂/BiOBr S-Scheme Heterostructure for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2407021-. doi: 10.3866/PKU.WHXB202407021
8. [8]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
9. [9]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
10. [10]
  Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 650-660. doi: 10.11862/CJIC.20240386
11. [11]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
12. [12]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
13. [13]
  Ruoxi Sun , Yiqian Xu , Shaoru Rong , Chunmiao Han , Hui Xu . The Enchanting Collision of Light and Time Magic: Exploring the Footprints of Long Afterglow Lifetime. University Chemistry, 2024, 39(5): 90-97. doi: 10.3866/PKU.DXHX202310001
14. [14]
  Rui Gao , Ying Zhou , Yifan Hu , Siyuan Chen , Shouhong Xu , Qianfu Luo , Wenqing Zhang . Design, Synthesis and Performance Experiment of Novel Photoswitchable Hybrid Tetraarylethenes. University Chemistry, 2024, 39(5): 125-133. doi: 10.3866/PKU.DXHX202310050
15. [15]
  Wanmin Cheng , Juan Du , Peiwen Liu , Yiyun Jiang , Hong Jiang . Photoinitiated Grignard Reagent Synthesis and Experimental Improvement in Triphenylmethanol Preparation. University Chemistry, 2024, 39(5): 238-242. doi: 10.3866/PKU.DXHX202311066
16. [16]
  Yuhang Jiang , Weijie Liu , Jiaqi Cai , Jiayue Chen , Yanping Ren , Pingping Wu , Liulin Yang . A Journey into the Science and Art of Sugar: “Dispersion of Light and Optical Rotation of Matter” Science Popularization Experiment. University Chemistry, 2024, 39(9): 288-294. doi: 10.12461/PKU.DXHX202401054
17. [17]
  Xiaxue Chen , Yuxuan Yang , Ruolin Yang , Yizhu Wang , Hongyun Liu . Adjustable Polychromatic Fluorescence: Investigating the Photoluminescent Properties of Copper Nanoclusters. University Chemistry, 2024, 39(9): 328-337. doi: 10.3866/PKU.DXHX202308019
18. [18]
  Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuO_x/TiO₂ Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 100038-. doi: 10.3866/PKU.WHXB202408015
19. [19]
  Qingjun PAN , Zhongliang GONG , Yuwu ZHONG . Advances in modulation of the excited states of photofunctional iron complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 45-58. doi: 10.11862/CJIC.20240365
20. [20]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282

Get Citation

PDF

XML

Metrics

PDF Downloads(668)
Abstract views(908)
HTML views(17)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Properties of Photogenerated Charge Carriers and Visible-Light Surface Photocurrent of Heterogeneous ZnO/BiVO4-V2O5 Structures

Metrics

通讯作者: 陈斌, bchen63@163.com

Properties of Photogenerated Charge Carriers and Visible-Light Surface Photocurrent of Heterogeneous ZnO/BiVO₄-V₂O₅ Structures