Citation: ZHU Lei, QIANG Ying-Huai, ZHAO Yu-Long, GU Xiu-Quan, SONG Duan-Ming, SONG Chang-Bin. Facile Synthesis of Cu₂SnSe₃ as Counter Electrodes for Dye-Sensitized Solar Cells[J]. Acta Physico-Chimica Sinica, ;2013, 29(11): 2339-2344. doi: 10.3866/PKU.WHXB201309031 shu

Facile Synthesis of Cu₂SnSe₃ as Counter Electrodes for Dye-Sensitized Solar Cells

1.
1 School of Materials Science and Engineering, China University of Mining and Technology, Xuzhou 221116, Jiangsu Province, P. R. China;
2 School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou 221116, Jiangsu Province, P. R. China

Received Date: 15 May 2013
Available Online: 3 September 2013
Fund Project: 中央高校基本科研基金(2592012184) (2592012184)

Cu₂SnSe₃ (CTSe) nanoparticles with diameters of 150-250 nm were synthesized by a facile solvothermal method. The nanoparticles drop-casted onto fluorine dope tin oxide (FTO) substrate were used as counter electrode in dye-sensitized solar cells (DSSCs). The morphology, structure and composition of the CTSe nanoparticles were characterized by field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), Raman spectroscopy, and energy dispersive X-ray spectroscopy (EDS). The results indicated the formation of the nanoparticles with a single crystal phase and approximately stoichiometric composition. DSSCs fabricated with the CTSe-based counter electrodes exhibited a power conversion efficiency of 7.75%, which is similar to that of Ptbased devices (7.21%). The current-voltage curves of the DSSCs demonstrated that the thickness of the CTSe layer strongly influenced the photocurrent density and fill factor as a result of changes in the number of electrocatalytic sites and the resistance of the layers. Electrochemical impedance spectroscopy (EIS) measurements were performed and the results indicated that CTSe exhibited Pt-like electrocatalytic activity for the reduction of I₃^- to I^- in DSSCs. This work presents a new approach for expanding the possibilities for developing low-cost DSSCs that do not require expensive and rare Pt counter electrodes.
- Cu₂SnSe₃,
- Nanoparticle,
- Solvothermal,
- Counter electrode,
- Dye-sensitized solar cell
1. [1]
  
  (1) O'Regan, B.; Grätzel, M. Nature 1991, 353, 737. doi: 10.1038/353737a0
2. [2]
  (2) Liu, J. C.;Wang, Y. J.; Sun, D. D. J. Alloy. Compd. 2012, 545,99. doi: 10.1016/j.jallcom.2012.08.050
3. [3]
  (3) Zhang, C. R.;Wu, Y. Z.; Chen, Y. H.; Chen, H. S. Acta Phys. -Chim. Sin. 2009, 25, 53. [张材荣, 吴有智, 陈玉红,陈宏善. 物理化学学报, 2009, 25, 53.] doi: 10.3866/PKU.WHXB20090110
4. [4]
  (4) Nazeeruddin, M. K.; Kay, A.; Rodicio, I.; Humphry-Baker, R.;Müller, E.; Liska, P.; Vlachopoulos, N.; Grätzel, M. J. Am. Chem. Soc. 1993, 115, 6382. doi: 10.1021/ja00067a063
5. [5]
  (5) O'Regan, B.; Schwartz, D. T.; Zakeeruddin, S. M.; Grätzel, M.Adv. Mater. 2000, 12, 1263.
6. [6]
  (6) Kay, A.; Grätzel, M. Sol. Energy Mater. Sol. Cells 1996, 44,99. doi: 10.1016/0927-0248(96)00063-3
7. [7]
  (7) Trancik, J. E.; Barton, S. C.; Hone, J. Nano Lett. 2008, 8, 982.doi: 10.1021/nl071945i
8. [8]
  (8) Yang, J.; Liu, Y. F.; Chen, X. M.; Hu, Z. H.; Zhao, G. H. Acta Phys. -Chim. Sin. 2008, 24, 13. [杨静, 刘亚菲, 陈晓妹, 胡中华, 赵国华. 物理化学学报, 2008, 24, 13.] doi: 10.1016/S1872-1508(08)60002-9
9. [9]
  (9) Wang, S. F.; Rao, K. K.; Yang, T. C. K.;Wang, H. P. J. Alloy. Compd. 2011, 509, 1969. doi: 10.1016/j.jallcom.2010.10.103
10. [10]
  (10) Olsen, E.; Hagen, G.; Lindquist, S. E. Sol. Energy Mater. Sol. Cells 2000, 63, 267. doi: 10.1016/S0927-0248(00)00033-7
11. [11]
  (11) Wu, Y. C.; Liu, X. L.; Ye, M.; Xie, T.; Huang, X. M. Acta Phys. -Chim. Sin. 2008, 24, 97. [吴玉程, 刘晓璐, 叶敏,解挺, 黄新民. 物理化学学报, 2008, 24, 97.] doi: 10.3866/PKU.WHXB20080117
12. [12]
  (12) Papageorgiou, N. Chem. Rev. 2004, 241, 1421.
13. [13]
  (13) Cai, F. J.; Chen, T.; Peng, H. S. J. Mater. Chem. 2012, 22,14856. doi: 10.1039/c2jm32256k
14. [14]
  (14) Wang, M. K.; Anghel, A. M.; Marsan, B.; Ha, N. C.;Pootrakulchote, N.; Zakeeruddin, S. M.; Grätzel, M. J. Am. Chem. Soc. 2009, 131, 15976. doi: 10.1021/ja905970y
15. [15]
  (15) Xia, J. B.; Yuan, C. C.; Yanagida, S. ACS Appl. Mater. Interfaces2010, 2, 2136. doi: 10.1021/am100380w
16. [16]
  (16) Li, G. R.; Song, J.; Pan, G. L.; Gao, X. P. Energy Environ. Sci.2011, 4, 1680. doi: 10.1039/c1ee01105g
17. [17]
  (17) Miettunen, K.; Toivola, M.; Hashmi, G.; Salpakari, J.; Asghar,I.; Lund, P. Carbon 2011, 49, 528. doi: 10.1016/j.carbon.2010.09.052
18. [18]
  (18) Xin, X.; He, M.; Han,W.; Jung, J.; Lin, Z. Angew. Chem. Int. Edit. 2011, 50, 11739. doi: 10.1002/anie.201104786
19. [19]
  (19) Du, Y. F.; Fan, J. Q.; Zhou,W. H.; Zhou, Z. J.; Jiao, J.;Wu, S.X. ACS Appl. Mater. Interfaces 2012, 4, 1796. doi: 10.1021/am3000616
20. [20]
  (20) Marcano, G.; Rincon, C.; Chalbaud, L. M.; Bracho, D. B.;Perez, G. S. J. Appl. Phys. 2001, 90, 1847. doi: 10.1063/1.1383984
21. [21]
  (21) Katagiri, H.; Jimbo, K.; Maw,W. S.; Oishi, K.; Yamazaki, M.;Araki, H.; Takeuchi, A. Thin Solid Films 2009, 517, 2455. doi: 10.1016/j.tsf.2008.11.002
22. [22]
  (22) Chaudhuri, T. K.; Tiwari, D. Sol. Energy Mater. Sol. Cells 2012,101, 46. doi: 10.1016/j.solmat.2012.02.012
23. [23]
  (23) Guo, Q. J.; Ford, G. M.; Yang,W. C.;Walker, B. C.; Stach, E.A.; Hillhouse, H.W.; Agrawal, R. J. Am. Chem. Soc. 2010, 132,17384. doi: 10.1021/ja108427b
24. [24]
  (24) Lin, X. P.; Song, D. M.; Gu, X. Q.; Zhao, Y. L.; Qiang, Y. H.Appl. Surf. Sci. 2012, 263, 816. doi: 10.1016/j.apsusc.2012.10.016
25. [25]
  (25) Wang, J.; Zhao, L.; Lin, V. S. Y.; Lin, Z. J. Mater. Chem. 2009,19, 3682. doi: 10.1039/b904247d
26. [26]
  (26) Marcano, G.; De Chalbaud, L. M.; Rincon, C.; Sanchez, P. G.Mater. Lett. 2002, 53, 151. doi: 10.1016/S0167-577X(01)00466-9
27. [27]
  (27) Chandrasekhar, H. R.; Humphreys, R. G.; Zwick, U.; Cardona,M. Phys. Rev. B 1977, 15, 2177. doi: 10.1103/PhysRevB.15.2177
28. [28]
  (28) Dai, P. C.; Zhang, G.; Chen, Y. C.; Jiang, H. C.; Feng, Z. Y.; Lin,Z. J.; Zhan, J. H. Chem. Commun. 2012, 48, 3006. doi: 10.1039/c2cc17652a
29. [29]
  (29) Wu, M.; Lin, X.; Hagfeldt, A.; Ma, T. Angew. Chem. Int. Edit.2011, 123, 3582.
30. [30]
  (30) Hauch, A.; Georg, A. Electrochim. Acta 2001, 46, 3457. doi: 10.1016/S0013-4686(01)00540-0
31. [31]
  (31) Lee, B.; Buchholz, D. B.; Chang, R. P. H. Energy Environ. Sci.2012, 5, 6941. doi: 10.1039/c2ee02950b
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通讯作者: 陈斌, bchen63@163.com

Facile Synthesis of Cu₂SnSe₃ as Counter Electrodes for Dye-Sensitized Solar Cells