Citation: ZHANG Cui-Mei, ZHANG Zhi-Guo, HUANG Cun-Shun, ZHANG Qun, CHEN Yang. Photodissociation Dynamics of Carbonyl Sulfide in Helium Droplets[J]. Acta Physico-Chimica Sinica, ;2013, 29(09): 1886-1890. doi: 10.3866/PKU.WHXB201306191 shu

Photodissociation Dynamics of Carbonyl Sulfide in Helium Droplets

1.
1 Hefei National Laboratory for Physical Sciences at the Microscale and Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, P. R. China;
2 State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning Province, P. R. China

Received Date: 3 May 2013
Available Online: 19 June 2013
Fund Project: 国家自然科学基金项目(21073187, 21273212, 21173205) (21073187, 21273212, 21173205)国家重点基础研究项目(973)(2010CB923302) (973)(2010CB923302)中国科学技术大学-同步辐射联合基金(KY2340000021)资助 (KY2340000021)

The photodissociation dynamics of carbonyl sulfide (OCS) in helium droplets was studied using a velocity-map-imaging technique. The CO fragments were detected by (2+1)-resonance-enhanced multiphoton ionization. It was found that in the helium droplet environment, rotational cooling is much more efficient than vibrational cooling. The velocity map images for both CO (v=0) and CO (v=1) exhibit nearly isotropic angular distributions. The kinetic energy distributions show that most of the translational energies are relaxed in the finite-sized superfluid helium system. However, the average translational energies of the CO (v=1) images are higher than those of the CO (v=0) images. The relevant mechanism is briefly discussed.
- Heliumdroplet,
- Time-sliced ion imaging,
- OCS
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