Citation: WANG Wu-Gang, ZHANG Shao-Long, ZHANG Lan-Lan, WANG Yan, LIU Xiao-Ling, NG Yan-Jun, DOU Tao. Synthesis and Characterization of Nanosheet ZSM-5 Zeolites with Different SiO₂/Al₂O₃ Molar Ratios[J]. Acta Physico-Chimica Sinica, ;2013, 29(09): 2035-2040. doi: 10.3866/PKU.WHXB201306183 shu

Synthesis and Characterization of Nanosheet ZSM-5 Zeolites with Different SiO₂/Al₂O₃ Molar Ratios

1.
State Key Laboratory of Heavy Oil Processing, Key Laboratory of Catalysis, China National Petroleum Corporation, College of Chemistry Engineering, University of Petroleum-Beijing, Beijing 102249, P. R. China

Received Date: 25 April 2013
Available Online: 18 June 2013
Fund Project: 国家重点基础研究发展计划(973)项目(2012CB215002) (973)项目(2012CB215002)国家自然科学基金(21276278, 21176255) (21276278, 21176255)中国石油天然气集团公司项目(2011A-2101)资助 (2011A-2101)

Nanosheet ZSM-5 zeolites with different SiO₂/Al₂O₃ molar ratios have been hydrothermally synthesized by an organic surfactant with a diquaternary ammoniumgroup. The samples were characterized by X-ray diffraction (XRD), N₂ adsorption-desorption, X-ray fluorescence spectroscopy (XRF), scanning electron microscopy (SEM) and ²⁷Al magic angle spinning nuclear magnetic resonance (²⁷Al MAS-NMR) techniques. The synthesis conditions of the nanosheets ZSM-5 were studied, including the synthesis factors such as crystallization temperature and time, the amount of structure-directing agent (SDA) and alkalinity. The results showed that shorter crystallization times were required when synthesis was conducted at higher crystallization temperatures, higher SiO₂/Al₂O₃ ratios, larger amounts of structure-directing agent were used, and higher SiO₂/Al₂O₃ ratios. The morphology, BET and mesopore volume changed with increasing SiO₂/Al₂O₃.
- Nanosheet,
- ZSM-5 zeolite,
- Synthetic chemistry,
- SiO₂/Al₂O₃ ratio
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Synthesis and Characterization of Nanosheet ZSM-5 Zeolites with Different SiO2/Al2O3 Molar Ratios

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Synthesis and Characterization of Nanosheet ZSM-5 Zeolites with Different SiO₂/Al₂O₃ Molar Ratios