Citation: SHI Qin, MEN Chun-Yan, LI Juan. Preparation and Electrochemical Capacitance Properties of Graphene Oxide/Polypyrrole Intercalation Composite[J]. Acta Physico-Chimica Sinica, ;2013, 29(08): 1691-1697. doi: 10.3866/PKU.WHXB201306031 shu

Preparation and Electrochemical Capacitance Properties of Graphene Oxide/Polypyrrole Intercalation Composite

1.
College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, P. R. China

Received Date: 8 March 2013
Available Online: 3 June 2013
Fund Project: 新疆大学博士启动基金项目(BS110112) (BS110112) 乌鲁木齐科技计划项目(H101133001) (H101133001)国家自然科学基金(21262035)资助 (21262035)

Graphene oxide/polypyrrole ( /PPy) intercalation composite was successfully prepared via in-situ chemical oxidative polymerization of pyrrole monomers by using methyl orange (MO) as a template agent. The morphology and microstructure of the composite were characterized by X-ray diffraction (XRD) analysis, Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). In addition, the electrochemical properties of the composite material were investigated by cyclic voltammetry (CV), galvanostatic charge/discharge and electrochemical impedance spectroscopy techniques in two different aqueous electrolytes (1 mol·L^-1 Na₂SO₄ and 1 mol·L^-1 H₂SO₄). The results indicated that the /PPy intercalation composite displayed considerable specific capacitance in both neutral and acid electrolytes, which is attributed to taking full advantage of the superior properties and synergy of graphene oxide and polypyrrole. The /PPy intercalation composite exhibited the specific capacitance of 449.1 and 619.0 F·g^-1 in the Na₂SO₄ and H₂SO₄ electrolytes, respectively, at a current density of 0.5 A·g^-1. This is significantly higher than the corresponding specific capacitance of pure PPy. After 800 cycling test, the specific capacitance of the composite remained about 92% and 62% of the initial capacitance in the two different electrolytes, respectively. A higher initial capacitance was obtained in the acidic electrolyte, but the composite showed better electrochemical cyclic stability in the neutral electrolyte.
- Graphene oxide,
- Polypyrrole,
- Intercalation composite,
- Electrode material,
- Electrochemical capacitance property
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沈阳化工大学材料科学与工程学院沈阳 110142