Citation: LI Bo, LÜ ng Xuan. Highly Active and Stable Catalyst for Visible Light Hydrogen Production Based on Oxidative Quenching of Eosin Y[J]. Acta Physico-Chimica Sinica, ;2013, 29(08): 1778-1784. doi: 10.3866/PKU.WHXB201305302 shu

Highly Active and Stable Catalyst for Visible Light Hydrogen Production Based on Oxidative Quenching of Eosin Y

LI Bo ^1,2 ,
LÜ ng Xuan ^1,

1.
1 Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Tianshui Zhong Road 18, Lanzhou 730000, P. R. China;
2 University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received Date: 16 April 2013
Available Online: 30 May 2013
Fund Project: 国家自然科学基金(21173242) (21173242) 国家重点基础研究发展规划项目(973) (2009CB22003) (973) (2009CB22003)国家高技术研究发展计划项目(863) (2012AA051501)资助 (863) (2012AA051501)

The effects and mechanism of methyl viologen (MV²⁺) on photocatalytic hydrogen production over an active, stable catalyst sensitized by Eosin Y (EY) under visible light were studied by UV-Vis absorption, fluorescence spectroscopies and photoelectric experiments. The results showed that MV²⁺ increased the efficiency of electron transfer from excited states of EY to the surface of Pt/TiO₂ and suppressed accumulation of unstable intermediate EY^3-· by an oxidative and reductive quenching mechanism. MV²⁺ also improved the activity and stability of photocatalytic hydrogen production by an EY-sensitized Pt/TiO₂ system with triethanolamine (TEOA) as an electron donor. The effects of transient photocurrent and concentration of EY on the hydrogen production activity of dye-sensitized systems with and without MV²⁺ provided further evidence that MV²⁺ acted as an electron transfer agent to effectively improve photoinduced electron transfer and utilization efficiency.
- Methyl violet,
- Activity,
- Stability,
- Hydrogen production,
- Photocatalysis
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