Citation: LI Bo, LÜ ng Xuan. Highly Active and Stable Catalyst for Visible Light Hydrogen Production Based on Oxidative Quenching of Eosin Y[J]. Acta Physico-Chimica Sinica, ;2013, 29(08): 1778-1784. doi: 10.3866/PKU.WHXB201305302 shu

Highly Active and Stable Catalyst for Visible Light Hydrogen Production Based on Oxidative Quenching of Eosin Y

LI Bo ^1,2 ,
LÜ ng Xuan ^1,

1.
1 Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Tianshui Zhong Road 18, Lanzhou 730000, P. R. China;
2 University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received Date: 16 April 2013
Available Online: 30 May 2013
Fund Project: 国家自然科学基金(21173242) (21173242) 国家重点基础研究发展规划项目(973) (2009CB22003) (973) (2009CB22003)国家高技术研究发展计划项目(863) (2012AA051501)资助 (863) (2012AA051501)

The effects and mechanism of methyl viologen (MV²⁺) on photocatalytic hydrogen production over an active, stable catalyst sensitized by Eosin Y (EY) under visible light were studied by UV-Vis absorption, fluorescence spectroscopies and photoelectric experiments. The results showed that MV²⁺ increased the efficiency of electron transfer from excited states of EY to the surface of Pt/TiO₂ and suppressed accumulation of unstable intermediate EY^3-· by an oxidative and reductive quenching mechanism. MV²⁺ also improved the activity and stability of photocatalytic hydrogen production by an EY-sensitized Pt/TiO₂ system with triethanolamine (TEOA) as an electron donor. The effects of transient photocurrent and concentration of EY on the hydrogen production activity of dye-sensitized systems with and without MV²⁺ provided further evidence that MV²⁺ acted as an electron transfer agent to effectively improve photoinduced electron transfer and utilization efficiency.
- Methyl violet,
- Activity,
- Stability,
- Hydrogen production,
- Photocatalysis
1. [1]
  
  (1) Zhou, P.; Lu, G. X.; Ma, J. T. J. Mol. Catal. (China) 2011, 25 (4), 328. [周鹏, 吕功煊, 马建泰. 分子催化, 2011, 25 (4),328.]
2. [2]
  (2) Zhou, P.; Zhao, C. J.; Dong,W. P.; Lu, G. X. J. Mol. Catal. (China) 2012, 26 (3), 265. [周鹏, 赵成坚, 董文平, 吕功煊.分子催化, 2012, 26 (3), 265.]
3. [3]
  (3) Wu, Y. Q.; Lu, G. X.; Li, S. B. J. Mol. Catal. (China) 2004, 18 (2), 125. [吴玉琪, 吕功煊, 李树本. 分子催化, 2004, 18 (2),125.]
4. [4]
  (4) Elvington, M.; Brown, J.; Arachchige, S. M.; Brewer, K. J.J. Am. Chem. Soc. 2007, 129 (35), 10644. doi: 10.1021/ja073123t
5. [5]
  (5) Li, Q.; Guo, B.; Yu, J. G.; Ran, J. R.; Zhang, B. H.; Yan, H. J.; ng, J. R. J. Am. Chem. Soc. 2011, 133 (28), 10878.doi: 10.1021/ja2025454
6. [6]
  (6) Wu, Y. Q.; Lu, G. X. J. Mol. Catal. (China) 2001, 15 (6), 467.[吴玉琪, 吕功煊. 分子催化, 2001, 15 (6), 467.]
7. [7]
  (7) Silva, L. A.; Ryu, S. Y.; Choi, J.; Choi,W. Y.; Hoffmann, M. R.J. Phys. Chem. C 2008, 112 (32), 12069. doi: 10.1021/jp8037279
8. [8]
  (8) Teets, T. S.; Nocera, D. G. Chem. Commun. 2011, 47 (33), 9268.doi: 10.1039/c1cc12390d
9. [9]
  (9) Wang, X.; Maeda, K.; Thomas, A.; Takanabe, K.; Xin, G.;Carlsson, J. M.; Domen, K.; Antonietti, M. Nat. Mater. 2008, 8 (1), 76.
10. [10]
  (10) Yan, H. J.; Yang, J. H.; Ma, G. J.;Wu, G. P.; Zong, X.; Lei, Z.B.; Shi, J. Y.; Li, C. J. Catal. 2009, 266 (2), 165. doi: 10.1016/j.jcat.2009.06.024
11. [11]
  (11) Yu, J.; Qi, L.; Jaroniec, M. J. Phys. Chem. C 2010, 114 (30),13118. doi: 10.1021/jp104488b
12. [12]
  (12) Zheng, X. H.; Zhang, B.; Li, Q. L.; Jin, Z. S. J. Mol. Catal. (China) 1991, 5 (4), 340. [郑新华, 张兵, 李庆霖, 金振声.分子催化, 1991, 5 (4), 340.]
13. [13]
  (13) Min, S. X.; Lü, G. X. Acta Phys. -Chim. Sin. 2011, 27 (9), 2178.[敏世雄, 吕功煊. 物理化学学报, 2011, 27 (9), 2178.]doi: 10.3866/PKU.WHXB20110904
14. [14]
  (14) Chen, K. S.; Liu,W. H.;Wang, Y. H.; Lai, C. H.; Chou, P. T.;Lee, G. H.; Chen, K.; Chen, H. Y.; Chi, Y.; Tung, F. C. Adv. Funct. Mater. 2007, 17 (15), 2964.
15. [15]
  (15) Kubo,W.; Murakoshi, K.; Kitamura, T.; Yoshida, S.; Haruki,M.; Hanabusa, K.; Shirai, H.;Wada, Y.; Yanagida, S. J. Phys. Chem. B 2001, 105 (51), 12809. doi: 10.1021/jp012026y
16. [16]
  (16) Li, Y. X.; Xie, C. F.; Peng, S. Q.; Lu, G. X.; Li, S. B. J. Mol. Catal. A: Chem. 2008, 282 (1), 117.
17. [17]
  (17) Li, Y.; Zhang, J. Laser & Photonics Rev. 2010, 4 (4), 517.
18. [18]
  (18) Hashimoto, K.; Kawai, T.; Sakata, T. Chem. Lett. 1983, 12 (5),709.
19. [19]
  (19) Misawa, H.; Sakuragi, H.; Usui, Y.; Tokumaru, K. Chem. Lett.1983, 7, 1021.
20. [20]
  (20) Li, Y. X.; Guo, M. M.; Peng, S. Q.; Lu, G. X.; Li, S. B. Int. J. Hydrog. Energy 2009, 34 (14), 5629. doi: 10.1016/j.ijhydene.2009.05.100
21. [21]
  (21) Abe, R.; Hara, K.; Sayama, K.; Domen, K.; Arakawa, H.J. Photochem. Photobiol. A: Chem. 2000, 137 (1), 63.doi: 10.1016/S1010-6030(00)00351-8
22. [22]
  (22) Shimidzu, T.; Iyoda, T.; Koide, Y. J. Am. Chem. Soc. 1985, 107 (1), 35. doi: 10.1021/ja00287a007
23. [23]
  (23) Kalyanasundaram, K.; Kiwi, J.; Grätzel, M. Helv. Chim. Acta1978, 61, 2720.
24. [24]
  (24) Islam, S. D. M.; Konishi, T.; Fujitsuka, M.; Ito, O.; Nakamura,Y.; Usui, Y. Photochem. Photobiol. 2000, 71 (6), 675.doi: 10.1562/0031-8655(2000)071<0675:PROMVU>2.0.CO;2
25. [25]
  (25) Keller, V.; Bernhardt, P.; Garin, F. J. Catal. 2003, 215 (1), 129.doi: 10.1016/S0021-9517(03)00002-2
26. [26]
  (26) Zhang,W.; Hong, J.; Zheng, J.; Huang, Z. Y.; Zhou, J. R.; Xu,R. J. Am. Chem. Soc. 2011, 133 (51), 20680. doi: 10.1021/ja208555h
27. [27]
  (27) Zheng, Z. K.; Huang, B. B.; Qin, X. Y.; Zhang, X. Y.; Dai, Y.;Whangbo, M. H. J. Mater. Chem. 2011, 21 (25), 9079.doi: 10.1039/c1jm10983a
28. [28]
  (28) Pelet, S.; Grätzel, M.; Moser, J. E. J. Phys. Chem. B 2003, 107,3215.
29. [29]
  (29) Dürr, H.; Boβmann, S.; Beuerlein, A. J. Photochem. Photobiol. A: Chem. 1993, 73, 233. doi: 10.1016/1010-6030(93)90010-I
1. [1]
  Shitao Fu , Jianming Zhang , Cancan Cao , Zhihui Wang , Chaoran Qin , Jian Zhang , Hui Xiong . Study on the Stability of Purple Cabbage Pigment. University Chemistry, 2024, 39(4): 367-372. doi: 10.3866/PKU.DXHX202401059
2. [2]
  Haitao Wang , Lianglang Yu , Jizhou Jiang , Arramel , Jing Zou . S-Doping of the N-Sites of g-C₃N₄ to Enhance Photocatalytic H₂ Evolution Activity. Acta Physico-Chimica Sinica, 2024, 40(5): 2305047-0. doi: 10.3866/PKU.WHXB202305047
3. [3]
  Wang Wang , Yucheng Liu , Shengli Chen . Use of NiFe Layered Double Hydroxide as Electrocatalyst in Oxygen Evolution Reaction: Catalytic Mechanisms, Electrode Design, and Durability. Acta Physico-Chimica Sinica, 2024, 40(2): 2303059-0. doi: 10.3866/PKU.WHXB202303059
4. [4]
  Jiawei Hu , Kai Xia , Ao Yang , Zhihao Zhang , Wen Xiao , Chao Liu , Qinfang Zhang . Interfacial Engineering of Ultrathin 2D/2D NiPS₃/C₃N₅ Heterojunctions for Boosting Photocatalytic H₂ Evolution. Acta Physico-Chimica Sinica, 2024, 40(5): 2305043-0. doi: 10.3866/PKU.WHXB202305043
5. [5]
  Chenye An , Sikandaier Abiduweili , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . Hierarchical S-scheme Heterojunction of Red Phosphorus Nanoparticles Embedded Flower-like CeO₂ Triggering Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-0. doi: 10.3866/PKU.WHXB202405019
6. [6]
  Jiajie Cai , Chang Cheng , Bowen Liu , Jianjun Zhang , Chuanjia Jiang , Bei Cheng . CdS/DBTSO-BDTO S-scheme photocatalyst for H₂ production and its charge transfer dynamics. Acta Physico-Chimica Sinica, 2025, 41(8): 100084-0. doi: 10.1016/j.actphy.2025.100084
7. [7]
  Shuang Cao , Bo Zhong , Chuanbiao Bie , Bei Cheng , Feiyan Xu . Insights into Photocatalytic Mechanism of H₂ Production Integrated with Organic Transformation over WO₃/Zn_0.5Cd_0.5S S-Scheme Heterojunction. Acta Physico-Chimica Sinica, 2024, 40(5): 2307016-0. doi: 10.3866/PKU.WHXB202307016
8. [8]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . Construction of 4-Amino-1H-imidazole-5-carbonitrile Modified Carbon Nitride-Based Donor-Acceptor Photocatalyst for Efficient Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-0. doi: 10.3866/PKU.WHXB202406026
9. [9]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Liu Fei . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 2408004-0. doi: 10.3866/PKU.WHXB202408004
10. [10]
  Sumiya Akter Dristy , Md Ahasan Habib , Shusen Lin , Mehedi Hasan Joni , Rutuja Mandavkar , Young-Uk Chung , Md Najibullah , Jihoon Lee . Exploring Zn doped NiBP microspheres as efficient and stable electrocatalyst for industrial-scale water splitting. Acta Physico-Chimica Sinica, 2025, 41(7): 100079-0. doi: 10.1016/j.actphy.2025.100079
11. [11]
  Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049
12. [12]
  Mingxuan Qi , Lanyu Jin , Honghe Yao , Zipeng Xu , Teng Cheng , Qi Chen , Cheng Zhu , Yang Bai . Recent progress on electrical failure and stability of perovskite solar cells under reverse bias. Acta Physico-Chimica Sinica, 2025, 41(8): 100088-0. doi: 10.1016/j.actphy.2025.100088
13. [13]
  Peipei Sun , Jinyuan Zhang , Yanhua Song , Zhao Mo , Zhigang Chen , Hui Xu . Built-in Electric Fields Enhancing Photocarrier Separation and H₂ Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2311001-0. doi: 10.3866/PKU.WHXB202311001
14. [14]
  Fanpeng Meng , Fei Zhao , Jingkai Lin , Jinsheng Zhao , Huayang Zhang , Shaobin Wang . Optimizing interfacial electric fields in carbon nitride nanosheet/spherical conjugated polymer S-scheme heterojunction for hydrogen evolution. Acta Physico-Chimica Sinica, 2025, 41(8): 100095-0. doi: 10.1016/j.actphy.2025.100095
15. [15]
  Chengyan Ge , Jiawei Hu , Xingyu Liu , Yuxi Song , Chao Liu , Zhigang Zou . Self-integrated black NiO clusters with ZnIn₂S₄ microspheres for photothermal-assisted hydrogen evolution by S-scheme electron transfer mechanism. Acta Physico-Chimica Sinica, 2026, 42(1): 100154-. doi: 10.1016/j.actphy.2025.100154
16. [16]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-0. doi: 10.1016/j.actphy.2025.100067
17. [17]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Construction of ZnCoP/CdLa₂S₄ Schottky Heterojunctions for Enhancing Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-0. doi: 10.3866/PKU.WHXB202404030
18. [18]
  Chengxiao Zhao , Zhaolin Li , Dongfang Wu , Xiaofei Yang . SBA-15 templated covalent triazine frameworks for boosted photocatalytic hydrogen production. Acta Physico-Chimica Sinica, 2026, 42(1): 100149-. doi: 10.1016/j.actphy.2025.100149
19. [19]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Corrosion inhibition of nickel-cobalt-phosphide in water by coating TiO₂ layer. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 365-384. doi: 10.11862/CJIC.20240063
20. [20]
  Yihan Xue , Xue Han , Jie Zhang , Xiaoru Wen . NCQDs修饰FeOOH基复合材料的制备及其电容脱盐性能. Acta Physico-Chimica Sinica, 2025, 41(7): 100072-0. doi: 10.1016/j.actphy.2025.100072

Get Citation

PDF

XML

Metrics

PDF Downloads(699)
Abstract views(1796)
HTML views(29)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142