Citation: MA Jing-Yuan, ZOU Yang, JIANG Zheng, HUANG Yu-Ying. Effect of the Ratio between Ionic Liquids [BMIM]Br and [BMIM][BF₄] on the Charge Transfer of Br^-[J]. Acta Physico-Chimica Sinica, ;2013, 29(08): 1618-1622. doi: 10.3866/PKU.WHXB201305272 shu

Effect of the Ratio between Ionic Liquids [BMIM]Br and [BMIM][BF₄] on the Charge Transfer of Br^-

1.
Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, P. R. China

Received Date: 25 March 2013
Available Online: 27 May 2013
Fund Project: 国家自然科学基金(11079007, 11005148, 10705046) (11079007, 11005148, 10705046)中国科学院知识创新工程重大交叉项目(KJCX2-YW-N43)资助 (KJCX2-YW-N43)

We analyzed the change of hydrogen bonding between Br^- and imidazolium cations when the ionic liquid 1-butyl-3-methylimidazolium bromide ([BMIM]Br) was gradually mixed with 1-butyl-3- methylimidazolium tetrafluoroborate ([BMIM] [BF₄]) using X-ray absorption fine structure (XAFS) and ultraviolet absorption spectroscopies. As the content of [BMIM][BF₄] increased, the intensity of the K-edge main peak of Br reduced in X-ray absorption near edge structure (XANES) spectra, and the absorption edge moved 0.9 eV to lower energy. Meanwhile, the radial structure given by extended X-ray absorption fine structure (EXAFS) indicated that the distribution number reduced and average hydrogen bond length increased. UV spectra showed a clear blue shift and peaks decreased in intensity as the content of [BMIM][BF₄] increased. All of these results indicate that more negative charge was transferred to Br^- as the content of [BMIM][BF₄] increased. The data obtained from quantum chemical calculations also support this conclusion.
- Ionic liquid,
- Charge transfer,
- X-ray absorption fine structure spectroscopy,
- Absorption edge,
- UV spectroscopy
1. [1]
  
  (1) Jain, N.; Kumar, A.; Chauhan, S.; Chauhan, S. M. S. Tetrahedron 2005, 61, 1015. doi: 10.1016/j.tet.2004.10.070
2. [2]
  (2) Buzzeo, M. C.; Evans, R. G.; Comppton, R. G. ChemPhysChem2004, 5, 1106.
3. [3]
  (3) Hardacre, C.; Holbrey, J. D.; McMath, E. J.; Bowron, D. T.;Soper, A. K. J. Chem. Phys. 2003, 118, 273. doi: 10.1063/1.1523917
4. [4]
  (4) Behera, K.; Om, H.; Pandey, S. J. Phys. Chem. B 2009, 113,786. doi: 10.1021/jp8089787
5. [5]
  (5) Zhang, Y. F.; Gan, L.; Chi, R. A.; Zhang, M. Lishizhen Medicine and Materia Medica Research 2010, 21, 1975. [张越非,甘琳, 池汝安, 张美. 时珍国医国药, 2010, 21, 1975.]
6. [6]
  (6) Liang, L.; Xuan, A. G.;Wu, Y. X.;Wang, Y. Y.; Cheng, S.Journal of Wuhan University of Technology 2009, 31, 63.[梁蕾, 宣爱国, 吴元欣, 王艳艳, 程思. 武汉理工大学学报, 2009, 31, 63.]
7. [7]
  (7) Wilkes, J. S.; Levisky, J. A.;Wilson, R. A.; Hussey, C. L. Inorg. Chem. 1982, 21, 1263. doi: 10.1021/ic00133a078
8. [8]
  (8) N , H. L.; LeCompte, K.; Hargens, L.; McEwen, A. B.Thermochim. Acta 2000, 357, 97.
9. [9]
  (9) Liu, G.; Shao, J. Chinese Journal of Inorganic Chemistry, 2011,27, 731. [刘阁, 邵杰. 无机化学学报, 2011, 27, 731.]
10. [10]
  (10) Su, Z.; Ye, S. H.;Wang, Y. L. Chinese Journal of Inorganic Chemistry 2010, 26, 693. [粟智, 叶世海, 王永龙. 无机化学学报, 2010, 26, 693.]
11. [11]
  (11) Wu, F. Y.; Zhang, X.; Jiang, Y. B. Chemical Journal of Chinese Universities 2003, 24, 1990. [吴芳英, 张煊, 江云宝. 高等学校化学学报, 2003, 24, 1990.]
12. [12]
  (12) Liu, Y. D.; Zhang, Y.;Wu, G. Z.; Hu, J. J. Am. Chem. Soc. 2006,128, 7456. doi: 10.1021/ja062685u
13. [13]
  (13) Chen, S. M.;Wu, G. Z.; Sha, M. L.; Huang, S. R. J. Am. Chem. Soc. 2007, 129, 2416. doi: 10.1021/ja067972c
14. [14]
  (14) Sha, M. L.;Wu, G. Z.; Liu, Y. S.; Tang, Z. F.; Fang, H. P.J. Phys. Chem. C 2009, 113, 4618. doi: 10.1021/jp810980v
15. [15]
  (15) Zou, Y.; Xu, H. J.;Wu, G. Z.; Jiang, Z.; Chen, S. M.; Huang, Y.Y.; Huang,W.;Wei, X. J. J. Phys. Chem. B 2009, 113, 2066.doi: 10.1021/jp809788u
16. [16]
  (16) He, Y. X.; Fu, H. Y.; Li, C.; Ji, X.; Ge, X.W.; Zou, Y.; Jiang, Z.;Xu, H. J.;Wu, G. Z. Chin. Sci. Bull. doi: 10.1007/s11434-013-5845-8
17. [17]
  (17) Li, C.; Guo, X. J.; He, Y. X.; Jiang, Z.;Wang, Y. X.; Chen, S.M.; Fu, H. Y.; Zou, Y.; Dai, S.;Wu, G. Z.; Xu, H. J. RSC Advances 2013, 3, 9618.
18. [18]
  (18) Ma, J. Y.; Zou, Y.; Jiang, Z.; Huang,W.; Li, J.;Wu, G. Z.;Huang, Y. Y.; Xu, H. J. Phys. Chem. Chem. Phys. 2013, 15,11904. doi: 10.1039/c3cp51743h
19. [19]
  (19) Heng, L.; Zhou, Y. N.; Jiang, Z.; Gu, S. Q.;Wei, X. J.; Huang,Y. Y.; Zou, Y.; Xu, H. J. J. Synchrotron Rad. 2012, 19, 969.doi: 10.1107/S0909049512038873
20. [20]
  (20) Newville, M. J. Synchrotron Rad. 2001, 8, 322. doi: 10.1107/S0909049500016964
21. [21]
  (21) Richtmyer, F. K.; Barnes, S.W.; Ramberg, E. Phys. Rev. 1934,46, 843. doi: 10.1103/PhysRev.46.843
22. [22]
  (22) Lee, P. A.; Citrin, P. H.; Eisenberger, P.; Kancaid, B. M. Rev. Mod. Phys. 1981, 53, 769. doi: 10.1103/RevModPhys.53.769
23. [23]
  (23) Nagel, D. J.; Baun,W. L. X-ray spectroscopy; Azaroff, L. V. Ed.McGraw-Hill: New York, 1974; p 445.
24. [24]
  (24) Waychunas, G. A.; Apted, M. J.; Brown, G. E., Jr. Physics and Chemistry of Minerals 1983, 10, 1. doi: 10.1007/BF01204319
25. [25]
  (25) Zhang, J. P.; Jin, L.; Zhang, H. X. Acta Phys. -Chim. Sin. 2011,27, 1089. [张建坡, 金丽, 张红星. 物理化学学报, 2011, 27,1089]. doi: 10.3866/PKU.WHXB20110505
26. [26]
  (26) Feng, C. G.; Xiong, Y. D.; Liu, X. Spectroscopy and Spectral Analysis 2010, 30, 1441. [冯长根, 熊宇迪, 刘霞. 光谱学与光谱分析, 2010, 30, 1441.]
27. [27]
  (27) Frisch, M. J.; Trucks, G.W.; Schlegel, H. B.; et al. Gaussian 03,Revision B.02; Gaussian Inc.: Pittsburgh, PA, 2003.
28. [28]
  (28) Zhang, S. J.; Lü, X. M.; et al. Ionic Liquids: from Basic Research to Industrial Applications; Science Press: Beijing,2006; pp 36-53. [张锁江, 吕兴梅, 等. 离子液体——从基础研究到工业应用. 北京: 科学出版社, 2006: 36-53.]
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of the Ratio between Ionic Liquids [BMIM]Br and [BMIM][BF4] on the Charge Transfer of Br-

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通讯作者: 陈斌, bchen63@163.com

Effect of the Ratio between Ionic Liquids [BMIM]Br and [BMIM][BF₄] on the Charge Transfer of Br^-