Citation: MENG Xiu-Xia, NG Xun, YANG Nai-Tao, TAN Xiao-Yao, MA Zi-Feng. Preparation and Properties of Direct-Methane Solid Oxide Fuel Cell Based on a Graded Cu-CeO₂-Ni-YSZ Composite Anode[J]. Acta Physico-Chimica Sinica, ;2013, 29(08): 1719-1726. doi: 10.3866/PKU.WHXB201305151 shu

Preparation and Properties of Direct-Methane Solid Oxide Fuel Cell Based on a Graded Cu-CeO₂-Ni-YSZ Composite Anode

1.
1 School of Chemical Engineering, Shandong University of Technology, Zibo 255049, Shandong Province, P. R. China;
2 Chemical Engineering Department, Shanghai JiaoTong University, Shanghai 200240, P. R. China

Received Date: 6 February 2013
Available Online: 15 May 2013
Fund Project: 国家自然科学基金(21076118, 21173147) (21076118, 21173147)山东省优秀中青年科学家科研奖励基金(2010BSB01011)资助项目 (2010BSB01011)

A graded anode-supported solid oxide fuel cell (SOFC) with the structure porous Ni-yttria stabilized zirconia (Ni-YSZ)|microporous Ni-YSZ|YSZ|La_0.8Sr_0.2MnO₃ (LSM) was fabricated by a trilayer co-pressing-sintering method, and coating with an LSM cathode. Cu-CeO₂ was impregnated into the porous Ni-YSZ layer using nitrate/glycol precursors to act as an anti-carbon catalyst to fabricate a graded Cu-CeO₂-NiO-YSZ composite anode. The current-voltage (I-V), current-power (I-P), and long-term stability of the SOFC were tested using CH₄ or H₂ as fuels and air as an oxidant. The results show that the co-pressing-sintering layers possess a gradient pore structure with defect-free combination. The power density of SOFC supported by a graded Ni-YSZ anode is 284 mW·cm^-2, operated at 850℃ using H₂ as a fuel, but decreases to 143 mW·cm^-2 when the fuel is changed to CH₄. In contrast, the cell supported by a Cu-CeO₂-Ni-YSZ anode show the reverse behavior, increasing from 176 to 196 mW·cm^-2 when the fuel is changed from H₂ to CH₄ at 850℃. Under a 250 mA·cm^-2 load using CH₄ as the fuel, the output of the cell with a graded Ni-YSZ anode fluctuats and the cell is blocked after 10 h. At this point, carbon particles or fibers are observed in the anode layer by scanning electron microscopy (SEM). Conversely, the cell with a Cu-CeO₂-Ni-YSZ anode shows stable power output for 50 h or longer, and no carbon deposition was observed inside the anode.
- Solid oxide fuel cell,
- Cu-CeO₂,
- Anti-carbonization,
- Graded composite anode,
- Tri-layer co-pressing-sintering
1. [1]
  
  (1) Lawlor, V.; Griessera, S.; Buchingerd, G.; Olabi, A. G.;Cordiner, S.; Meissner, D. J. Power Sources 2009, 193, 387.doi: 10.1016/j.jpowsour.2009.02.085
2. [2]
  (2) Suzuki, T.; Yamaguchi, T.; Fujishiro, Y.; Awano, M.J. Electrochem. Soc. 2006, 153, A925.
3. [3]
  (3) Lee, T. J.; Kendall, K. J. Power Sources 2008, 181, 195. doi: 10.1016/j.jpowsour.2008.03.019
4. [4]
  (4) rte, R. J.; Vohs, J. M. Current Opinion in Colloid & Interface Science 2009, 14, 236. doi: 10.1016/j.cocis.2009.04.006
5. [5]
  (5) Zhan, Z. L.; Barnett, S. A. Science 2005, 308, 844. doi: 10.1126/science.1109213
6. [6]
  (6) Kurokawa, H.; Sholklapper, T. Z.; Jacobson, C. P.; Jonghe, L. C.D.; Visco, S. J. Electrochem. Solid-State 2007, 10, B135.
7. [7]
  (7) Resini, C.; Delgado, M. C. H.; Presto, S.; Alemany, L. J.; Riani,P.; Marazza, R.; Ramis, G.; Busca, G. Int. J. Hydrog. Energy2008, 33, 3728. doi: 10.1016/j.ijhydene.2008.04.044
8. [8]
  (8) Huang, B.;Wang, S. R.; Liu, R. Z.;Wen, T. L. J. Power Sources2007, 167, 288. doi: 10.1016/j.jpowsour.2007.02.075
9. [9]
  (9) Lee, S. I.; Ahn, K.; Vohs, J. M.; rte, R. J. Electrochem. Solid-State Lett. 2005, 8, A48.
10. [10]
  (10) Lei, Z.; Zhu, Q. S.; Han, M. F. Acta Phys. -Chim. Sin. 2010, 26 (3), 583. [雷泽, 朱庆山, 韩敏芳. 物理化学学报, 2010, 26 (3), 583.] doi: 10.3866/PKU.WHXB20100323
11. [11]
  (11) Jiang, S. P. Mater Sci Eng. A 2006, 418, 199. doi: 10.1016/j.msea.2005.11.052
12. [12]
  (12) Ye, X. F.; Zhou, J.;Wang, S. R.; Zeng, F. R.;Wen, T. L.; Zhan,Z. L. Int. J. Hydrog. Energy 2012, 37, 505.
13. [13]
  (13) Zhou, X.; Zhen, J.; Liu, L.; Li, X.; Zhang, N.; Sun, K. J. Power Sources 2012, 201, 128. doi: 10.1016/j.jpowsour.2011.10.129
14. [14]
  (14) Tao, S.W.; Irvine, J. T. S. J. Electrochem. Soc. 2004, 151, A252.
15. [15]
  (15) Fu, Q. X.; Tietz, F.; Stover, D. J. Electrochem. Soc. 2006, 153,D74.
16. [16]
  (16) Haag, J. M.; Madsen, B. D.; Barnett, S. A. Electrochem. Solid-State Lett. 2008, 11, B51.
17. [17]
  (17) Kim, G.; Corre, G.; Irvine, J. T. S.; Vohs, J. M.; rte, R. J.Electrochem. Solid-State Lett. 2008, 11, B16.
18. [18]
  (18) Ye, X. F.;Wang, S. R.; Hu, Q.; Chen, J. Y.;Wen, T. L.;Wen, Z.Y. Solid State Ionics 2009, 180, 276. doi: 10.1016/j.ssi.2008.11.010
19. [19]
  (19) Ye, X.;Wang, S. R.; Hu, Q.;Wang, Z. R.;Wen, T. L.,Wen, Z. Y.Electrochem. Commun. 2009, 11, 823. doi: 10.1016/j.elecom.2009.02.003
20. [20]
  (20) Ye, X. F.; Huang, B.;Wang, S. R.;Wang, Z. R.; Xiong, L.;Wen,T. L. J. Power Sources 2007, 164, 203. doi: 10.1016/j.jpowsour.2006.10.056
21. [21]
  (21) Zhao, F.; Virkar, A. V. J. Power Sources 2005, 141, 79. doi: 10.1016/j.jpowsour.2004.08.057
22. [22]
  (22) Zong,W. Z.; Zhu, Y. F. Acta Phys. -Chim. Sin. 2010, 26 (4),827. [宗卫正, 朱永法. 物理化学学报, 2010, 26 (4), 827.]doi: 10.3866/PKU.WHXB20100443
23. [23]
  (23) Li, Q.; Zhao,H.; Jiang, R.; Guo, L. F. Acta Phys. -Chim. Sin.2012, 28 (9), 2065. [李强, 赵辉, 江瑞, 郭力帆. 物理化学学报, 2012, 28 (9), 2065.] doi: 10.3866/PKU.WHXB201206272
24. [24]
  (24) Yang, N. T.; Tan, X.; Meng, X. X.; Yin, Y.; Ma, Z. F. ECS Transaction 2009, 25 (2), 811.
25. [25]
  (25) Lin, Y.; Zhan, Z.; Liu, J.; Barnett, S. A. Solid State Ionics 2005,176, 1827. doi: 10.1016/j.ssi.2005.05.008
26. [26]
  (26) Liu, J.; Barnett, S. A. Solid State Ionics 2003, 158, 11. doi: 10.1016/S0167-2738(02)00769-5
27. [27]
  (27) Kishimoto, H.; Yamaji, K.; Horita, T.; Xiong, Y. P.; Sakai, N.;Brito, M. E.; Yokokawa, H. Electrochem. Soc. 2006, 153 (6),982. doi: 10.1149/1.2186790
28. [28]
  (28) Pillaia, M.; Lin, Y.; Zhu, H.; Kee, R. J.; Barnett, S. A. J. Power Sources 2010, 195, 271. doi: 10.1016/j.jpowsour.2009.05.032
29. [29]
  (29) Lin, Y.; Zhan, Z.; Barnett, S. A. J. Power Sources 2006, 158,1313. doi: 10.1016/j.jpowsour.2005.09.060
30. [30]
  (30) Fisher, J. C.; Chuang, S. S. C. Catal. Commun. 2009, 10, 772.doi: 10.1016/j.catcom.2008.11.035
31. [31]
  (31) Sariboga, V.; Oksuzomer, F. Applied Energy 2012, 93, 707. doi: 10.1016/j.apenergy.2012.01.003
1. [1]
  Xingmin Chen , Yunyun Wu , Yao Tang , Peishen Li , Shuai Gao , Qiang Wang , Wen Liu , Sihui Zhan . Construction of Z-scheme Cu-CeO₂/BiOBr heterojunction for enhanced photocatalytic degradation of sulfathiazole. Chinese Chemical Letters, 2024, 35(7): 109245-. doi: 10.1016/j.cclet.2023.109245
2. [2]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
3. [3]
  Ru SONG , Biao WANG , Chunling LU , Bingbing NIU , Dongchao QIU . Electrochemical properties of stable and highly active PrBa_0.5Sr_0.5Fe_1.6Ni_0.4O_5+δ cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 639-649. doi: 10.11862/CJIC.20240397
4. [4]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069
5. [5]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . 氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化. Acta Physico-Chimica Sinica, 2025, 41(1): 2309037-. doi: 10.3866/PKU.WHXB202309037
6. [6]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
7. [7]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
8. [8]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
9. [9]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
10. [10]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
11. [11]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
12. [12]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
13. [13]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
14. [14]
  Fangfang WANG , Jiaqi CHEN , Weiyin SUN . CuBi@Cu-MOF composite catalysts for electrocatalytic CO₂ reduction to HCOOH. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 97-104. doi: 10.11862/CJIC.20240350
15. [15]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
16. [16]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
17. [17]
  Zhiyuan TONG , Ziyuan LI , Ke ZHANG . Three-dimensional porous collector based on Cu-Li_6.4La₃Zr_1.4Ta_0.6O₁₂ composite layer for the construction of stable lithium metal anode. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 499-508. doi: 10.11862/CJIC.20240238
18. [18]
  Bowen Yang , Rui Wang , Benjian Xin , Lili Liu , Zhiqiang Niu . C-SnO₂/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100015-. doi: 10.3866/PKU.WHXB202310024
19. [19]
  Yongpo Zhang , Xinfeng Li , Yafei Song , Mengyao Sun , Congcong Yin , Chunyan Gao , Jinzhong Zhao . Synthesis of Chlorine-Bridged Binuclear Cu(I) Complexes Based on Conjugation-Driven Cu(II) Oxidized Secondary Amines. University Chemistry, 2024, 39(5): 44-51. doi: 10.3866/PKU.DXHX202309092
20. [20]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019

Get Citation

PDF

XML

Metrics

PDF Downloads(725)
Abstract views(1009)
HTML views(52)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Properties of Direct-Methane Solid Oxide Fuel Cell Based on a Graded Cu-CeO2-Ni-YSZ Composite Anode

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Properties of Direct-Methane Solid Oxide Fuel Cell Based on a Graded Cu-CeO₂-Ni-YSZ Composite Anode