Citation: WANG Xue-Bao, LI Jin-Qing, LUO Yun-Jun. Effect of Drying Methods on the Structure and Thermal Decomposition Behavior of Ammonium Perchlorate/Graphene Composites[J]. Acta Physico-Chimica Sinica, ;2013, 29(10): 2079-2086. doi: 10.3866/PKU.WHXB201305021 shu

Effect of Drying Methods on the Structure and Thermal Decomposition Behavior of Ammonium Perchlorate/Graphene Composites

1.
1 School of Material Science & Engineering, Beijing Institute of Technology, Beijing 100081, P. R. China;
2 cademy of Ordnance Science, Beijing 100089, P. R. China

Received Date: 4 March 2013
Available Online: 2 May 2013
Fund Project: 北京理工大学基础研究基金(20110942019)资助项目 (20110942019)

Graphene hydrogels were prepared by the sol-gel method, and then used to prepare ammonium perchlorate (AP)/graphene composites by the incorporation of AP. The composites were dried naturally in air, freeze-dried, or dried with supercritical CO₂. Scanning electron microscopy (SEM), elemental analyses (EA), and X-ray diffraction (XRD) were used to characterize the structure of the AP/graphene composites dried using different methods. Furthermore, the thermal decomposition behavior of the AP/graphene composites was investigated by differential scanning calorimetry (DSC) and thermogravimetric analysis/infrared spectroscopy (TG-FTIR). Drying method had an obvious influence on the morphology of the AP/graphene composites; only the AP/graphene composites dried with supercritical CO₂ showed similar three-dimensional networks and porous structure to graphene aerogels. Elemental analyses revealed that the AP contents in the AP/graphene composites prepared by drying naturally, freeze-drying, and supercritical CO₂ drying were 89.97%, 92.41%, and 94.40%, respectively. XRD results showed that AP was dispersed homogeneously on the nanoscale in the AP/graphene composites dried with supercritical CO₂ and the average particle diameter of AP was about 69 nm. DSC and TG-FTIR analyses indicated that graphene could promote the thermal decomposition of AP, particularly for the sample dried with supercritical CO₂. Independent of drying method, the low-temperature decomposition of the as-prepared AP/graphene composites was not observed and the high-temperature decomposition was accelerated. Compared to the other two drying methods, graphene in the AP/graphene composites dried with supercritical CO₂ showed most obvious promoting effects. The high-temperature decomposition temperature of the AP/graphene composites dried with supercritical CO₂ decreased by 83.7 ℃ compared with that of pure AP, and the total heat release reached 2110 J·g^-1. Moreover, graphene also took part in the oxidation reactions with oxidizing products, which was confirmed by the generation of CO₂.
- Drying methods,
- Graphene,
- Ammonium perchlorate,
- Sol-gel method,
- Thermal decomposition
1. [1]
  
  (1) Zhou, L. M.; Liu, H. Y.; Li, F. S. Acta Phys. -Chim. Sin. 2006,22 (5), 627. [周龙梅, 刘宏英, 李凤生. 物理化学学报, 2006,22 (5), 627.] doi: 10.3866/PKU.WHXB20060521
2. [2]
  (2) Liu, H. B.; Jiao, Q. Z.; Zhao, Y.; Li, H. S.; Sun, C. B.; Li, X. F.;Wu, H. Y. Mater. Lett. 2010, 64, 1698. doi: 10.1016/j.matlet.2010.04.061
3. [3]
  (3) Liu, L. L.; Li, F. S.; Tan, L. H.; Min, L.; Yi, Y. Propellants Explos. Pyrotech. 2004, 29, 34.
4. [4]
  (4) Kapoor, I. P. S.; Srivastava, P.; Singh, G. Propellants Explos. Pyrotech. 2009, 34, 351. doi: 10.1002/prep.v34:4
5. [5]
  (5) Luo, X. L.; Han, Y. F.; Yang, D. S.; Chen, Y. S. Acta Phys. -Chim. Sin. 2012, 28 (2), 297. [罗小林,韩银凤, 杨德锁,陈亚芍. 物理化学学报, 2012, 28 (2), 297.] doi: 10.3866/PKU.WHXB201112012
6. [6]
  (6) Chandru, R. A.; Patra, S.; Oommen, C.; Munichandraiah, N.;Raghunandan, B. N. J. Mater. Chem. 2012, 22, 6536. doi: 10.1039/c2jm16169a
7. [7]
  (7) Li, N.; Cao, M. H.;Wu, Q. Y.; Hu, C. W. CrystEngComm 2012,14, 428. doi: 10.1039/c1ce05858d
8. [8]
  (8) Chaturvedi, S.; Dave, P. N. J. Exp. Nanosci. 2012, 7 (2), 205.doi: 10.1080/17458080.2010.517571
9. [9]
  (9) Han, X.; Sun, Y. L.; Wang, T. F.; Lin, Z. K.; Li, S. F.; Zhao, F.Q.; Liu, Z. R.; Yi, J. H.; Ren, X. E. J. Therm. Anal. Calorim.2008, 91, 551. doi: 10.1007/s10973-007-8290-6
10. [10]
  (10) Reshmi, S.; Catherine, K. B.; Nair, C. P. R. Int. J. Nanotechnol.2011, 8 (10-12), 979.
11. [11]
  (11) Compton, O. C.; Nguyen, S. T. Small 2010, 6, 711. doi: 10.1002/smll.v6:6
12. [12]
  (12) Geim, A. K.; Novoselov, K. S. Nat. Mater. 2007, 6, 183. doi: 10.1038/nmat1849
13. [13]
  (13) Stoller, M. D.; Park, S. J.; Zhu, Y. W.; An, J. H.; Ruoff, R. S.Nano Lett. 2008, 8 (10), 3498. doi: 10.1021/nl802558y
14. [14]
  (14) Du, X.; Skachko, I.; Barker, A.; Andrei, E. Y. Nat. Nanotechnol.2008, 3 (8), 491. doi: 10.1038/nnano.2008.199
15. [15]
  (15) Lee, C.; Wei, X. D.; Kysar, J. W.; Hone, J. Science 2008, 321,385. doi: 10.1126/science.1157996
16. [16]
  (16) Balandin, A. A.; Ghosh, S.; Bao, W. Z.; Calizo, I.;Teweldebrhan, D.; Miao, F.; Lau, C. N. Nano Lett. 2008, 8 (3),902. doi: 10.1021/nl0731872
17. [17]
  (17) Zhang, X. T.; Sui, Z. Y.; Xu, B.; Yue, S. F.; Luo, Y. J.; Zhan, W.C.; Liu, B. J. Mater. Chem. 2011, 21, 6494. doi: 10.1039/c1jm10239g
18. [18]
  (18) Xu, Y. X.; Sheng, K. X.; Li, C.; Shi, G. Q. ACS Nano 2010, 4 (7), 4324. doi: 10.1021/nn101187z
19. [19]
  (19) Chen, W. F.; Yan, L. F. Nanoscale 2011, 3, 3132. doi: 10.1039/c1nr10355e
20. [20]
  (20) Hummers, W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80,1339. doi: 10.1021/ja01539a017
21. [21]
  (21) Boldyrev, V. V. Thermochim. Acta 2006, 443, 1. doi: 10.1016/j.tca.2005.11.038
22. [22]
  (22) Fan, X. Z.; Li, J. Z.; Fu, X. L.; Wang, H. Acta Chim. Sin. 2009,67 (1), 39. [樊学忠,李吉祯, 付小龙, 王晗. 化学学报,2009, 67 (1), 39.]
23. [23]
  (23) Li, N.; Geng, Z. F.; Cao, M. H.; Ren, L.; Zhao, X. Y.; Liu, B.;Tian, Y.; Hu, C. W. Carbon 2013, 54, 124. doi: 10.1016/j.carbon.2012.11.009
24. [24]
  (24) Lu, M.; Lü, C. X. Journal of Nanjing University of Science and Technology 2002, 26, 72. [陆明, 吕春绪. 南京理工大学学报, 2002, 26, 72.]
25. [25]
  (25) Cooper, P. W. Explosives Engineering;Wiley-VCH:Albuquerque NM, 1996; pp 24-26.
1. [1]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
2. [2]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
3. [3]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
4. [4]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
5. [5]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
6. [6]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
7. [7]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
8. [8]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
9. [9]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
10. [10]
  Yang Lv , Yingping Jia , Yanhua Li , Hexiang Zhong , Xinping Wang . Integrating the Ideological Elements with the “Chemical Reaction Heat” Teaching. University Chemistry, 2024, 39(11): 44-51. doi: 10.12461/PKU.DXHX202402059
11. [11]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
12. [12]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
13. [13]
  Rui Gao , Ying Zhou , Yifan Hu , Siyuan Chen , Shouhong Xu , Qianfu Luo , Wenqing Zhang . Design, Synthesis and Performance Experiment of Novel Photoswitchable Hybrid Tetraarylethenes. University Chemistry, 2024, 39(5): 125-133. doi: 10.3866/PKU.DXHX202310050
14. [14]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
15. [15]
  Zhao Lu , Hu Lv , Qinzhuang Liu , Zhongliao Wang . Modulating NH₂ Lewis Basicity in CTF-NH₂ through Donor-Acceptor Groups for Optimizing Photocatalytic Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(12): 2405005-. doi: 10.3866/PKU.WHXB202405005
16. [16]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
17. [17]
  Tingbo Wang , Yao Luo , Bingyan Hu , Ruiyuan Liu , Jing Miao , Huizhe Lu . Quantitative Computational Study on the Claisen Rearrangement Reaction of Allyl Phenyl Ethers: An Introduction to a Computational Chemistry Experiment. University Chemistry, 2024, 39(11): 278-285. doi: 10.12461/PKU.DXHX202403082
18. [18]
  Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
19. [19]
  Xinhao Yan , Guoliang Hu , Ruixi Chen , Hongyu Liu , Qizhi Yao , Jiao Li , Lingling Li . Polyethylene Glycol-Ammonium Sulfate-Nitroso R Salt System for the Separation of Cobalt (II). University Chemistry, 2024, 39(6): 287-294. doi: 10.3866/PKU.DXHX202310073
20. [20]
  Jihua Deng , Xinshi Wu , Dichang Zhong . Exploration of Green Teaching and Ideological and Political Education in Chemical Experiment of “Preparation of Ammonium Ferrous Sulfate”. University Chemistry, 2024, 39(10): 325-329. doi: 10.12461/PKU.DXHX202405046

Get Citation

PDF

XML

Metrics

PDF Downloads(859)
Abstract views(1141)
HTML views(48)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142