Citation: QIAN Jia-Sheng, LIU Ming-Xian, GAN Li-Hua, LÜ Yao-Kang, CHEN Ling-Yan, YE Rui-Jie, CHEN Long-Wu. Synthesis and Electrochemical Performance of Microporous Carbon Using a Zinc(II)-Organic Coordination Polymer[J]. Acta Physico-Chimica Sinica, ;2013, 29(07): 1494-1500. doi: 10.3866/PKU.WHXB201304271 shu

Synthesis and Electrochemical Performance of Microporous Carbon Using a Zinc(II)-Organic Coordination Polymer

1.
Department of Chemistry, Tongji University, Shanghai 200092, P. R. China

Received Date: 17 January 2013
Available Online: 27 April 2013
Fund Project: 国家自然科学基金(21207099, 21273162) (21207099, 21273162) 上海市科学技术委员会(11nm0501000, 12ZR1451100) (11nm0501000, 12ZR1451100) 上海市教委重点学科建设项目(J50102) (J50102)中央高校基本科研业务费(2011KJ023)资助 (2011KJ023)

Microporous carbon was prepared using a novel procedure based on a zinc(II)-organic coordination polymer. The polymer was prepared through the coordination interaction of zinc ions with tartaric acid, and then it was introduced into the open networks of resorcinol/formaldehyde (R/F) resol using hydrogen-bonding interactions. The R/F resol and zinc-organic coordination compound system copolymerized to produce an R/F and zinc-organic coordination copolymer. The copolymer was then heat-treated at 950℃ to decompose and evaporate zinc to fabricate microporous carbon materials. The carbon materials possessed relatively regular large micropores, with a specific surface area of up to 1260 m²·g^-1 and a total pore volume of 0.63 cm³·g^-1. The resultant microporous carbon materials were used as supercapacitor electrodes, exhibiting an equivalent series resistance of 0.46 Ω, and ideal capacitive behavior with a rectangular shape in cyclic voltammograms. Galvanostatic charge/discharge measurements of the carbon materials gave a specific capacitance of 196 F·g^-1 at a current density of 1 A· g^-1 and 137 F·g^-1 at a large current density of 10 A·g^-1. A high retention of 98% was measured for the long-term cycling stability (~1000 cycles) of the mesoporous carbon. Overall, the microporous carbon materials exhibited very od electrochemical performance. This study highlights the potential of well-designed microporous carbon materials as electrodes for diverse supercapacitor applications.
- Microporous carbon,
- Synthesis,
- Electrochemical performance,
- Zinc(II)-organic coordination polymer,
- Hydrogen-bonding interaction,
- Electrode material
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