Citation: WU Hong-Ying, WANG Huan-Wen. Synthesis and Characterization of NiCo₂O₄ Nanoflower/Activated Carbon Fiber Composite and Its Supercapacitor Properties[J]. Acta Physico-Chimica Sinica, ;2013, 29(07): 1501-1506. doi: 10.3866/PKU.WHXB201304241 shu

Synthesis and Characterization of NiCo₂O₄ Nanoflower/Activated Carbon Fiber Composite and Its Supercapacitor Properties

1.
College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, P. R. China

Received Date: 24 December 2012
Available Online: 24 April 2013
Fund Project: 国家自然科学基金(20963009, 21163017) (20963009, 21163017)甘肃省自然科学基金(0803RJA005)资助项目 (0803RJA005)

In the present work, NiCo₂O₄ nanowires grown directly on carbon fibers self-organize into a nanoflower morphology. The materials are prepared by hydrothermal treatment and subsequent low-temperature annealing. Field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM) results reveal a hierarchical three-dimensional mesoporous structure, which facilitates ion transport and electronic conduction for fast redox reactions. As a result, the electrode achieves a respectable specific capacitance of 1626 F·g^-1 at 1 A·g^-1 and high rate capability (65% retention at 10 A·g^-1), so it shows promise for application in supercapacitors.
- NiCo₂O₄,
- Nanoflower,
- Hydrothermal treatment,
- Supercapacitor,
- Electrode material
1. [1]
  
  (1) Chen, Y. L.; Hu, Z. A.; Chang, Y. Q.;Wang, H.W.; Zhang, Z. Y.;Yang, Y. Y.;Wu, H. Y. J. Phys. Chem. C 2011, 115, 2563. doi: 10.1021/jp109597n
2. [2]
  (2) Wang, H.W.; Hu, Z. A.; Chang, Y. Q.; Chen, Y. L.;Wu, H. Y.;Zhang, Z. Y.; Yang, Y. Y. J. Mater. Chem. 2011, 21, 10504. doi: 10.1039/c1jm10758e
3. [3]
  (3) Guan, C.; Li, X.;Wang, Z.; Cao, X.; Soci, C.; Zhang, H.; Fan,H. J. Adv. Mater. 2012, 24, 4186. doi: 10.1002/adma.201104295
4. [4]
  (4) Wang, H.; Casalongue, H. S.; Liang, Y.; Dai, H. J. Am. Chem. Soc. 2010, 132, 7472. doi: 10.1021/ja102267j
5. [5]
  (5) Jiang, H.; Ma, J.; Li, C. Chem. Commun. 2012, 48, 4465. doi: 10.1039/c2cc31418e
6. [6]
  (6) Wu, Z. S.;Wang, D.W.; Ren,W.; Zhao, J.; Zhou, G.; Li, F.;Cheng, H. M. Adv. Funct. Mater. 2010, 20, 3595. doi: 10.1002/adfm.v20:20
7. [7]
  (7) Bi, R. R.;Wu, X. L.; Cao, F. F.; Jiang, L. Y.; Guo, Y. G.;Wan,L. J. J. Phys. Chem. C 2010, 114, 2448. doi: 10.1021/jp9116563
8. [8]
  (8) Wang, H.;Wang, Y.;Wang, X. Electrochem. Commun. 2012, 18,92. doi: 10.1016/j.elecom.2012.02.023
9. [9]
  (9) Wang, H.W.; Hu, Z. A.; Chang, Y. Q.; Chen, Y. L.; Zhang, Z. Y.;Yang, Y. Y.;Wu, H. Y. Mater. Chem. Phys. 2011, 130, 672. doi: 10.1016/j.matchemphys.2011.07.043
10. [10]
  (10) Gujar, T. P.; Shinde, V. R.; Lokhande, C. D.; Han, S. H.J. Power Sources 2006, 161, 1479. doi: 10.1016/j.jpowsour.2006.05.036
11. [11]
  (11) Yuan, D. S.; Zeng, J. H.; Kristian, N.;Wang, Y.;Wang, X.Electrochem. Commun. 2009, 11, 313. doi: 10.1016/j.elecom.2008.11.041
12. [12]
  (12) Patel, M. N.;Wang, X.; Slanac, D. A.; Ferrer, D. A.; Dai, S.;Johnston, K. P.; Stevenson, K. J. J. Mater. Chem. 2012, 22,3160. doi: 10.1039/c1jm14513d
13. [13]
  (13) Chen, Y. M.; Cai, J. H.; Huang, Y. S.; Lee, K. Y.; Tsai, D. S.;Tiong, K. K. Nanotechnology 2011, 22, 355708. doi: 10.1088/0957-4484/22/35/355708
14. [14]
  (14) Zhang, L. L.; Zhao, X. S. Chem. Soc. Rev. 2009, 38, 2520. doi: 10.1039/b813846j
15. [15]
  (15) Lang, X. Y.; Hirata, A.; Fujita, T.; Chen, M.W. Nat. Nanotechnol. 2011, 6, 232. doi: 10.1038/nnano.2011.13
16. [16]
  (16) Li, Q.;Wang, Z. L.; Li, G. R.; Guo, R. L.; Ding, X. Y.; Tong, X.Nano Lett. 2012, 12, 3803. doi: 10.1021/nl301748m
17. [17]
  (17) Wei, T. Y.; Chen, C. H.; Chien, H. C.; Lu, S. Y.; Hu, C. C. Adv. Mater. 2010, 22, 347. doi: 10.1002/adma.v22:3
18. [18]
  (18) Gupta, V.; Gupta, S.; Miura, N. J. Power Sources 2010, 195,3757. doi: 10.1016/j.jpowsour.2009.12.059
19. [19]
  (19) Wang, H. L.; Gao, Q. M.; Jiang, L. Small 2011, 7, 2454.
20. [20]
  (20) Zhang, G. Q.;Wu, H. B.; Hoster, H. E.; Chan-Park, M. B.; Lou,X.W. Energy Environ. Sci. 2012, 5, 9453. doi: 10.1039/c2ee22572g
21. [21]
  (21) Yuan, C.; Li, J. H.; Zhang, L.; Shen, X. L.; Lou, X.W. Adv. Funct. Mater. 2012, 22, 4592. doi: 10.1002/adfm.v22.21
22. [22]
  (22) Xing,W.; Qiao, S. Z.;Wu, X. Z.; Gao, X. L.; Zhou, J.; Zhuo, S.P.; Hartono, S. B.; Hulicova-Jurcakova, D. J. Power Sources2011, 196, 4123. doi: 10.1016/j.jpowsour.2010.12.003
23. [23]
  (23) Grdeń, M.; Alsabet, M.; Jerkiewicz, G. ACS Appl. Mater. Interfaces 2012, 4, 3012. doi: 10.1021/am300380m
24. [24]
  (24) Xia, X.; Tu, J.; Zhang, Y.;Wang, X.; Gu, C.; Zhao, X. B.; Fan,H. J. ACS Nano 2012, 6, 5531. doi: 10.1021/nn301454q
25. [25]
  (25) Wang, X.; Han, X.; Lim, M.; Singh, N.; Gan, C. L.; Jan, M.;Lee, P. S. J. Phys. Chem. C 2012, 116, 12448. doi: 10.1021/jp3028353
26. [26]
  (26) Chien, H. C.; Cheng,W. Y.;Wang, Y. H.; Lu, S. Y. Adv. Funct. Mater. 2012, 22, 5038. doi: 10.1002/adfm.v22.23
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Characterization of NiCo2O4 Nanoflower/Activated Carbon Fiber Composite and Its Supercapacitor Properties

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Synthesis and Characterization of NiCo₂O₄ Nanoflower/Activated Carbon Fiber Composite and Its Supercapacitor Properties