Citation: NING Hui, HOU Min-Qiang, YANG De-Zhong, KANG Xin-Chen, HAN Bu-Xing. Ionic Association in Binary Ionic Liquids by Conductivity[J]. Acta Physico-Chimica Sinica, ;2013, 29(10): 2107-2113. doi: 10.3866/PKU.WHXB201304172 shu

Ionic Association in Binary Ionic Liquids by Conductivity

1.
Institute of Chemistry, Chinese Academy of Sciences, CAS Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Beijing National Laboratory for Molecular Sciences, Beijing 100190, P. R. China

Received Date: 15 February 2013
Available Online: 17 April 2013
Fund Project: 国家自然科学基金(20903109, 21073207)资助项目 (20903109, 21073207)

In this study, the conductivity of 13 ionic liquids (ILs) and 25 related binary mixtures were determined at temperatures ranging from 293.15-323.15 K. The conductivity data of the pure ILs and their mixtures were fitted using the Vogel-Tammann-Fulcher (VTF) equation. The ionic association in the ILs and IL mixtures was discussed using the parameters of the VTF equation. It was demonstrated that at the same temperature, the ILs with short side chain cations, low charge density anions, and weak hydrogen bonding force between cations and anions usually exhibited high conductivity. Anions had a more obvious effect on conductivity than cations. The ionic association in the mixtures was affected not only by the species but also by the composition of the mixture.
- Ionic liquid,
- Binary mixture,
- Conductivity,
- Ionic association,
- VTF equation
1. [1]
  
  (1) ng, Y. Y.; Liu, M.; Jia, S. Y.; Feng, J. P.; Song, C. S.; Guo, X.W. Acta Phys. -Chim. Sin. 2012, 28, 686. [公艳艳, 刘民, 贾松岩,冯建萍, 宋春山,郭新闻. 物理化学学报, 2012, 28, 686.]doi: 10.3866/PKU.WHXB201112292
2. [2]
  (2) Yuan, X.; Lou, S. J.; Kou, Y. Acta Phys. -Chim. Sin. 2010, 26,908. [苑晓,娄舒洁, 寇元. 物理化学学报, 2010, 26,908.] doi: 10.3866/PKU.WHXB20100433
3. [3]
  (3) Chen, Y.; Han, J.; Wang, T.; Mu, T. C. Energy & Fuels 2011, 25,5810. doi: 10.1021/ef201519g
4. [4]
  (4) Zhao, X. Y.; Cao, Y. R.; Cao, G. R.; Xiao, R. J. Acta Phys. -Chim. Sin. 2012, 28, 1411. [赵学艳, 曹宇容, 曹桂荣,肖瑞杰. 物理化学学报, 2012, 28, 1411.] doi: 10.3866/PKU.WHXB201203262
5. [5]
  (5) Zhong, H. X.; Zhao, C. B.; Luo, H.; Zhang, L. Z. Acta Phys. -Chim. Sin. 2012, 28, 2641. [仲皓想,赵春宝,骆浩,张灵志. 物理化学学报, 2012, 28, 2641.] doi: 10.3866/PKU.WHXB201207181
6. [6]
  (6) Dong, K.; Song, Y. T.; Liu, X. M.; Cheng, W. G.; Yao, X. Q.;Zhang, S. J. J. Phys. Chem. B 2012, 116, 1007. doi: 10.1021/jp205435u
7. [7]
  (7) Xu, W. G.; Li, L.; Ma, X. X.; Wei, J.; Duan, W. B.; Guan, W.;Yang, J. Z. J. Chem. Eng. Data 2012, 57, 2177. doi: 10.1021/je3000348
8. [8]
  (8) Zhang, Q. G.; Wei, Y.; Sun, S. S.; Wang, C.; Yang, M.; Liu, Q.S.; Gao, Y. A. J. Chem. Eng. Data 2012, 57, 2185. doi: 10.1021/je300153f
9. [9]
  (9) Wang, D.; Tian, G. C. Acta Phys. -Chim. Sin. 2012, 28, 2558.[王丁, 田国才.物理化学学报, 2012, 28, 2558.] doi: 10.3866/PKU.WHXB201208271
10. [10]
  (10) Ren, S. H.; Hou, Y. C.; Wu, W. Z.; Liu, Q. Y.; Xiao, Y. F.; Chen,X. T. J. Phys. Chem. B 2010, 114, 2175. doi: 10.1021/jp9108859
11. [11]
  (11) Zhang, L. Q.; Li, H. R. Acta Phys. -Chim. Sin. 2010, 26, 2877.[张力群,李浩然. 物理化学学报, 2010, 26, 2877.] doi: 10.3866/PKU.WHXB20101123
12. [12]
  (12) Zhai, C. P.; Liu, X. J.; Zhao, Y.; Wang, J. J. Acta Phys. -Chim. Sin. 2009, 25, 1185. [翟翠萍, 刘学军,赵扬,王键吉.物理化学学报, 2009, 25, 1185.] doi: 10.3866/PKU.WHXB20090628
13. [13]
  (13) Zhang, Q. G.; Wang, N. N.; Yu, Z. W. J. Phys. Chem. B 2010,114, 4747. doi: 10.1021/jp1009498
14. [14]
  (14) Niedermeyer, H.; Hallett, J. P.; Villar-Garcia, I. J.; Hunt, P. A.;Welton, T. Chem. Soc. Rev. 2012, 41, 7780. doi: 10.1039/c2cs35177c
15. [15]
  (15) Castiglione, F.; Raos, G.; Battista Appetecchi, G.; Montanino,M.; Passerini, S.; Moreno, M.; Famulari, A.; Mele, A. Phys. Chem. Chem. Phys. 2010, 12, 1784. doi: 10.1039/b921816e
16. [16]
  (16) Fletcher, K. A.; Baker, S. N.; Baker, G. A.; Pandey, S. New J. Chem. 2003, 27, 1706. doi: 10.1039/b305965k
17. [17]
  (17) Ma, L. L.; Liu, Y. F.; Yuan, J.; Wu, Y. H. Chemical Journal of Chinese Universities 2006, 27, 2182. [马亮亮,刘逸枫,袁俊,吴益华. 高等学校化学学报, 2006, 27, 2182.]
18. [18]
  (18) Annat, G.; Forsyth, M.; MacFarlane, D. R. J. Phys. Chem. B2012, 116, 8251. doi: 10.1021/jp3012602
19. [19]
  (19) Widegren, J. A.; Saurer, E. M.; Marsh, K. N.; Magee, J. W.J. Chem. Thermodyn. 2005, 37, 569. doi: 10.1016/j.jct.2005.04.009
20. [20]
  (20) Zech, O.; Stoppa, A.; Buchner, R.; Kunz, W. J. Chem. Eng. Data2010, 55, 1774. doi: 10.1021/je900793r
21. [21]
  (21) Tokuda, H.; Hayamizu, K.; Ishii, K.; Abu Bin Hasan Susan, M.;Watanabe, M. J. Phys. Chem. B 2004, 108, 16593. doi: 10.1021/jp047480r
22. [22]
  (22) Zhang, J. M.; Yang, C. H.; Hou, Z. S.; Han, B. X.; Jiang, T.; Li,X. H.; Zhao, G. Y.; Li, Y. F.; Liu, Z. M.; Zhao, D. B.; Kou, Y.New J. Chem. 2003, 27, 333. doi: 10.1039/b206526f
23. [23]
  (23) Burrell, G. L.; Burgar, I. M.; ng, Q.; Dunlop, N. F.;Separovic, F. J. Phys. Chem. B 2010, 114, 11436.
24. [24]
  (24) Tokuda, H.; Hayamizu, K.; Ishii, K.; Susan, M.; Watanabe, M.J. Phys. Chem. B 2005, 109, 6103. doi: 10.1021/jp044626d
25. [25]
  (25) Tokuda, H.; Ishii, K.; Susan, M.; Tsuzuki, S.; Hayamizu, K.;Watanabe, M. J. Phys. Chem. B 2006, 110, 2833. doi: 10.1021/jp053396f
26. [26]
  (26) Hagiwara, R.; Matsumoto, K.; Nakamori, Y.; Tsuda, T.; Ito, Y.;Matsumoto, H.; Momota, K. J. Electrochem. Soc. 2003, 150,D195.
27. [27]
  (27) Yoshida, Y.; Baba, O.; Saito, G. J. Phys. Chem. B 2007, 111,4742. doi: 10.1021/jp067055t
28. [28]
  (28) Leys, J.; Rajesh, R. N.; Menon, P. C.; Glorieux, C.; Longuemart,S.; Nockemann, P.; Pellens, M.; Binnemans, K. J. Chem. Phys.2010, 133, 034503. doi: 10.1063/1.3455892
29. [29]
  (29) Bandres, I.; Montano, D. F.; Gascon, I.; Cea, P.; Lafuente, C.Electrochim. Acta 2010, 55, 2252. doi: 10.1016/j.electacta.2009.11.073
30. [30]
  (30) Liu, Q. S.; Yan, P. F.; Yang, M.; Tan, Z. C.; Li, C. P.; Welz-Biermann, U. Acta Phys. -Chim. Sin. 2011, 27, 2762. [刘青山,颜佩芳, 杨淼, 谭志诚, 李长平, Welz-Biermann, U. 物理化学学报, 2011, 27, 2762.] doi: 10.3866/PKU.WHXB20112762
31. [31]
  (31) Noda, A.; Hayamizu, K.; Watanabe, M. J. Phys. Chem. B 2001,105, 4603. doi: 10.1021/jp004132q
32. [32]
  (32) Leys, J.;Wubbenhorst, M.; Menon, C. P.; Rajesh, R.; Thoen, J.;Glorieux, C.; Nockemann, P.; Thijs, B.; Binnemans, K.;Longuemart, S. J. Chem. Phys. 2008, 128, 64509. doi: 10.1063/1.2827462
33. [33]
  (33) Every, H.; Bishop, A. G.; Forsyth, M.; MacFarlane, D. R.Electrochim. Acta 2000, 45, 1279. doi: 10.1016/S0013-4686(99)00332-1
34. [34]
  (34) Stoppa, A.; Buchner, R.; Hefter, G. J. Mol. Liq. 2010, 153, 46.
35. [35]
  (35) Ning, H.; Hou, M. Q.; Mei, Q. Q.; Liu, Y. H.; Yang, D. Z.; Han,B. X. Science China Chemistry 2012, 55, 1509. [宁汇,侯民强,梅清清, 刘元会,杨德重, 韩布兴.中国科学:化学, 2012,55, 1509.] doi: 10.1007/s11426-012-4655-1
1. [1]
  Jiayu Tang , Jichuan Pang , Shaohua Xiao , Xinhua Xu , Meifen Wu . Improvement for Measuring Transference Numbers of Ions by Moving-Boundary Method. University Chemistry, 2024, 39(5): 193-200. doi: 10.3866/PKU.DXHX202311021
2. [2]
  Fangyan Zhang , Yuhan Li , Bowen He , Meng Lin , Ying Ma . Determination of Sodium Carbonate Content: A Conductometric Titration Approach. University Chemistry, 2026, 41(3): 373-380. doi: 10.12461/PKU.DXHX202505023
3. [3]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
4. [4]
  Yameen Ahmed , Xiangxiang Feng , Yuanji Gao , Yang Ding , Caoyu Long , Mustafa Haider , Hengyue Li , Zhuan Li , Shicheng Huang , Makhsud I. Saidaminov , Junliang Yang . Interface Modification by Ionic Liquid for Efficient and Stable FAPbI₃ Perovskite Solar Cells. Acta Physico-Chimica Sinica, 2024, 40(6): 2303057-0. doi: 10.3866/PKU.WHXB202303057
5. [5]
  Yibo Wang , Ruiyuan Xu , Binye Cao , Wanmei Li . Unlocking the Secrets of Battery Aging: Understanding the Life Cycle of Batteries. University Chemistry, 2026, 41(3): 330-335. doi: 10.12461/PKU.DXHX202503119
6. [6]
  Ru SONG , Biao WANG , Chunling LU , Bingbing NIU , Dongchao QIU . Electrochemical properties of stable and highly active PrBa_0.5Sr_0.5Fe_1.6Ni_0.4O_5+δ cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 639-649. doi: 10.11862/CJIC.20240397
7. [7]
  Qiang Zhang , Yuanbiao Huang , Rong Cao . Imidazolium-Based Materials for CO₂ Electroreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306040-0. doi: 10.3866/PKU.WHXB202306040
8. [8]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
9. [9]
  Wan Li , Xiaohang Qiu , Xiuyun Wang , Mei Shi , Xiuqiong Zeng , Yanping Ren , Faqiong Zhao , Min Hu , Yiru Wang , Juanjuan Song , Yongxian Fan , Dongcheng Liu , Wenwei Zhang , Weihong Li , Yong Fan , Jianrong Zhang , Shuyong Zhang . Specifications of Laboratory Water and Suggestions on the Use of Conductivity Meter. University Chemistry, 2026, 41(3): 77-86. doi: 10.12461/PKU.DXHX202507036
10. [10]
  Qiaorong RU . Synthesis and characterization of tripyridine functionalized polyionic liquid luminescent materials. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 111-119. doi: 10.11862/CJIC.20250121
11. [11]
  Yang Chen , Xiuying Wang , Nengqin Jia . Ideological and Political Design, Blended Teaching Practice of Physical Chemistry Experiment: Pb-Sn Binary Metal Phase Diagram. University Chemistry, 2025, 40(3): 223-229. doi: 10.12461/PKU.DXHX202405184
12. [12]
  Qijia BAI , Xiang GAO , Yihang SHEN , Jiaqi LI , Yang CHEN , Cuie ZHAO . Mixed-size MXene for the application of high-performance transparent zinc-ion hybrid supercapacitors. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 703-712. doi: 10.11862/CJIC.20250331
13. [13]
  Yingran Liang , Fei Wang , Jiabao Sun , Hongtao Zheng , Zhenli Zhu . Construction and Application of a New Experimental Device for Determination of Alkaline Metal Elements by Plasma Atomic Emission Spectrometry Based on Solution Cathode Glow Discharge: An Alternative Approach for Fundamental Teaching Experiments in Emission Spectroscopy. University Chemistry, 2024, 39(5): 380-387. doi: 10.3866/PKU.DXHX202312024
14. [14]
  Zhiming Feng , Lili Wu , Chengming Wang . Doubly Oxidized Carbene. University Chemistry, 2025, 40(9): 326-331. doi: 10.12461/PKU.DXHX202411008
15. [15]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5−xMn_0.5V_1.5−xZr_x (PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-0. doi: 10.3866/PKU.WHXB202407023
16. [16]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
17. [17]
  Tianhao GE , Sirong LU , Zhiyin XIAO , Wei ZHONG . Synthesis of porphyrin-based ionic polymeric materials for catalytic application in CO₂ conversion. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 722-736. doi: 10.11862/CJIC.20250312
18. [18]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-0. doi: 10.3866/PKU.WHXB202408012
19. [19]
  Yufan ZHAO , Jinglin YOU , Shixiang WANG , Guopeng LIU , Xiang XIA , Yingfang XIE , Meiqin SHENG , Feiyan XU , Kai TANG , Liming LU . Raman spectroscopic quantitative study of the melt microstructure in binary Li₂O-GeO₂ functional crystals. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1533-1544. doi: 10.11862/CJIC.20250063
20. [20]
  Zhenhuan Wang , Weifei Wei , Ruijie Ma , Dou Luo , Zhanxiang Chen , Jun Zhang , Liyang Yu , Gang Li , Zhenghui Luo . 苯并[a]苯嗪受体的核心氰基化实现高效(19.04%)绿色溶剂加工的二元有机太阳能电池. Acta Physico-Chimica Sinica, 2026, 42(2): 100182-0. doi: 10.1016/j.actphy.2025.100182

Get Citation

PDF

XML

Metrics

PDF Downloads(747)
Abstract views(1388)
HTML views(12)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142