Citation: GUO Li-Mei, KUANG Yuan-Jiang, YANG Xiao-Dan, YU Yan-Long, YAO Jiang-Hong, CAO Ya-An. Investigation on Photocatalytic Reduction of CO₂into CH₄ Using SrB₂O₄/SrCO₃Composite Catalyst[J]. Acta Physico-Chimica Sinica, ;2013, 29(07): 1558-1565. doi: 10.3866/PKU.WHXB201304161 shu

Investigation on Photocatalytic Reduction of CO₂into CH₄ Using SrB₂O₄/SrCO₃Composite Catalyst

1.
1 Key Laboratory of Weak-Light Nonlinear Photonics, Ministry of Education, TEDA Applied Physics School and School of Physics, Nankai University, Tianjin 300457, P. R. China;
2 Maintenance Training Center, Zhenjiang Watercraft College, Zhenjiang 212000, Jiangsu Province, P. R. China

Received Date: 15 February 2013
Available Online: 16 April 2013
Fund Project: 国家自然科学基金(51072082, 21173121)资助项目 (51072082, 21173121)

An SrB₂O₄/SrCO₃composite catalyst is synthesized by the simple sol-gel method. Reduction of carbon dioxide into methane in the presence of water is used to evaluate the photocatalytic activity of the composite catalyst. SrB₂O₄/SrCO₃exhibits better photocatalytic performance than TiO₂(P25) and SrB₂O₄ under irradiation with UV light. The crystalline structure, crystallite size, and the BET surface areas of the resultant photocatalysts are studied via the techniques of X-ray diffraction (XRD), transmission electron microscopy (TEM), and nitrogen adsorption-desorption isotherms. The energy levels of the SrB₂O₄/SrCO₃ photocatalyst are determined from characterization with UV-Vis diffuse reflectance absorption spectra, X-ray photoelectron spectroscopy (XPS), and photoluminescence (PL) measurements. The heterojunction formed at the SrB₂O₄/SrCO₃interface efficiently promotes photogenerated carrier separation and increases the use of photogenerated carriers in photocatalytic reactions at the solid/liquid interface, resulting in high photocatalytic activity under UV light.
- SrB₂O₄/SrCO₃composite catalyst,
- Photocatalytic reduction of CO₂,
- CH₄,
- Photocatalytic activity
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Investigation on Photocatalytic Reduction of CO₂into CH₄ Using SrB₂O₄/SrCO₃Composite Catalyst