Citation: FENG Xing-Xing, XIE Jing, HU Geng-Shen, JIA Ai-Ping, XIE Guan-Qun, LUO Meng-Fei. Preparation of Pentaethylenehexamine-Functionalized Mesocellular Silica Foams and Their Application for CO₂ Adsorption[J]. Acta Physico-Chimica Sinica, ;2013, 29(06): 1266-1272. doi: 10.3866/PKU.WHXB201304091 shu

Preparation of Pentaethylenehexamine-Functionalized Mesocellular Silica Foams and Their Application for CO₂ Adsorption

1.
Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China

Received Date: 27 December 2012
Available Online: 9 April 2013
Fund Project: 国家自然科学基金(21203167)资助项目 (21203167)

Mesocellular silica foam (MCF) was prepared using P123 (EO₂₀-PO₇₀-EO₂₀) as template and then functionalized with pentaethylenehexamine (PEHA) for CO₂ adsorption. The samples were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), nitrogen adsorptiondesorption isotherms, Fourier transform infrared (FTIR) spectroscopy and thermal gravimetric analysis (TGA). These results indicated that after modification with PEHA, the structure of the support itself was undamaged. The highest CO₂ adsorption capacity of MCF-PEHA was obtained at 75℃. With increasing PEHA loading, the CO₂ adsorption capacity increases and approached the highest adsorption capacity (3.55 mmol·g^-1) with a 70% (w) PEHA loading. Moisture improved the CO₂ adsorption performance of the adsorbents. Repeated adsorption-desorption cycling indicated that the sorbents maintained stable CO₂ adsorption capacity after 4 cycles, indicating potential for regeneration of the adsorbents.
- Mesostructure cellar foam,
- Pentaethylenehexamine,
- Adsorption,
- CO₂
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Pentaethylenehexamine-Functionalized Mesocellular Silica Foams and Their Application for CO2 Adsorption

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通讯作者: 陈斌, bchen63@163.com

Preparation of Pentaethylenehexamine-Functionalized Mesocellular Silica Foams and Their Application for CO₂ Adsorption