Citation: YANG Ting-Ting, XU Hui-Xia, WANG Hua, MIAO Yan-Qin, DU Xiao-Gang, JING Shu, XU Bing-She. Synthesis and Photoelectric Properties of a New Phosphorescent Host Material Based on Carbazole[J]. Acta Physico-Chimica Sinica, ;2013, 29(06): 1351-1356. doi: 10.3866/PKU.WHXB201303281 shu

Synthesis and Photoelectric Properties of a New Phosphorescent Host Material Based on Carbazole

YANG Ting-Ting ^1,2 ,
XU Hui-Xia ^1,2, ,
WANG Hua ^1,2 ,
MIAO Yan-Qin ^1,2 ,
DU Xiao-Gang ^1,2 ,
JING Shu ^1,2 ,
XU Bing-She ^1,2

1.
1 Key Laboratory of Interface Science and Engineering in Advanced Materials, Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, P. R. China;
2 Research Center of Advanced Materials Science and Technology, Taiyuan University of Technology, Taiyuan 030024, P. R. China

Received Date: 22 October 2012
Available Online: 28 March 2013
Fund Project: 教育部长江学者与创新团队发展项目(IRT0972) (IRT0972) 国家国际科技合作专项(2012DFR50460) (2012DFR50460) 国家自然科学基金(21071108, 60976018,21101111, 61274056, 61205179) (21071108, 60976018,21101111, 61274056, 61205179) 山西省自然科学基金(2010021023-2, 2011021022-2) (2010021023-2, 2011021022-2)山西省科技攻关项目(20120321019)资助 (20120321019)

A new phosphorescent host material based on 9-[6-(9H-carbazol-9-yl)hexyl]-9H-carbazole (hCP) was designed and synthesized and its structure and properties were characterized. These investigations indicated that hCP possessed a twisted rigid structure, with the two carbazole units in a non-coplanar conformation leading to a higher triplet energy level (3.01 eV). hCP also possessed a high glass transition temperature (93℃). Electroluminescent devices were fabricated by doping the hCP host with the green- phosphorescent fac-tris(2-phenylpyridine)iridium(III) (Ir(ppy)₃) as the light-emitting layer. Compared with devices employing the typical (4,4'-N,N'-dicarbazole)biphenyl) (CBP) as a host, the hCP host showed a 34.8% increase of current efficiency to 15.1 cd·A^-1.
- Carbazole,
- Phosphorescence organic light emitting device,
- Host material
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