Citation: LONG Mei, CONG Ye, LI Xuan-Ke, CUI Zheng-Wei, DONG Zhi-Jun, YUAN Guan-Ming. Hydrothermal Synthesis and Photocatalytic Activity of Partially Reduced Graphene Oxide/TiO₂ Composite[J]. Acta Physico-Chimica Sinica, ;2013, 29(06): 1344-1350. doi: 10.3866/PKU.WHXB201303263 shu

Hydrothermal Synthesis and Photocatalytic Activity of Partially Reduced Graphene Oxide/TiO₂ Composite

1.
Hubei Province Key Laboratory of Coal Conversion and New Carbon Materials, Wuhan University of Science and Technology, Wuhan, Hubei 430081, P. R. China

Received Date: 9 January 2013
Available Online: 26 March 2013
Fund Project: 国家自然科学基金(20803054, 50972110)资助项目 (20803054, 50972110)

Partially reduced graphene oxide/titanium dioxide (R /TiO₂) composite was synthesized using tetrabutyl titanate and graphite oxide by a hydrothermal method. Photocatalytic activity of the material was evaluated by the degradation of methylene blue solution under visible light and UV light. The results suggest that the crystal phase and dispersion of titanium oxide in the composite can be controlled by varying the reaction temperature and amount of graphite oxide. Graphene oxide was partially reduced in the hydrothermal reaction process. Photocatalytic activities of partially reduced graphene oxide/titanium dioxide composites under both visible and UV light irradiation were higher than those of pure TiO₂. Partially reduced graphene oxide may act as a support and electron acceptor, and can also extend and enhance the band edge absorption of TiO₂ into the visible light region, hence effectively enhancing the adsorbability and photocatalytic activity of TiO₂.
- Hydrothermal,
- Partially reduced graphene oxide,
- Titanium dioxide,
- Photocatalysis,
- Support
1. [1]
  
  (1) Geim, A. K. Science 2009, 324, 1530. doi: 10.1126/science.1158877
2. [2]
  (2) Allen, M. J.; Tung, V. C.; Kaner, R. B. Chem. Rev. 2010, 110,132. doi: 10.1021/cr900070d
3. [3]
  (3) Zhang, H. B.; Zheng,W. G.; Yan, Q.; Yang, Y.;Wang, J.W.; Lu,Z. H.; Ji, G. Y.; Yu, Z. Z. Polymer 2010, 51, 1191. doi: 10.1016/j.polymer.2010.01.027
4. [4]
  (4) Wan, C.; Peng, T. J.; Sun, H. J.; Huang, Q. Chin. J. Inorg. Chem. 2012, 28 (5), 915. [万臣, 彭同江, 孙红娟, 黄桥.无机化学学报, 2012, 28 (5), 915.]
5. [5]
  (5) Chen, D.; Feng, H. B.; Li, J. H. Chem. Rev. 2012, 112, 6027.doi: 10.1021/cr300115g
6. [6]
  (6) Zhang, X. Y.; Sun, M. X.; Sun, Y. J.; Li, J.; Song, P.; Sun, T.;Cui, X. L. Acta Phys. -Chim. Sin. 2011, 27, 2831. [张晓艳,孙明轩, 孙钰珺, 李靖, 宋鹏, 孙通, 崔晓莉. 物理化学学报, 2011, 27, 2831.] doi: 10.3866/PKU.WHXB20112831
7. [7]
  (7) Zhang, X.; Yang, R.;Wang, C.; Heng, C. L. Acta Phys. -Chim. Sin. 2012, 28, 1520. [张晓, 杨蓉, 王琛, 衡成林. 物理化学学报, 2012, 28, 1520.] doi: 10.3866/PKU.WHXB201203131
8. [8]
  (8) Xu, Z. X.; Du, Y. J.; Jiao, Y. P.; Feng,W. Journal of Anhui University (Natural Science Edition) 2012, 36 (5), 73.[许志献, 杜燕军, 焦延鹏, 冯伟. 安徽大学学报(自然科学版), 2012, 36( 5), 73.]
9. [9]
  (9) Fan,W. Q.; Lai, Q. H.; Zhang, Q. H.;Wang, Y. J. Phys. Chem. C 2011, 115, 10694. doi: 10.1021/jp2008804
10. [10]
  (10) Cong, Y.; Zhang, J. L.; Chen, F.; Anpo, M. J. Phys. Chem. C2007, 111, 6976. doi: 10.1021/jp0685030
11. [11]
  (11) Zhang, X.; Liu, Q. Appl. Surf. Sci. 2008, 254, 4780.doi: 10.1016/j.apsusc.2008.01.094
12. [12]
  (12) Xing, M. Y.; Fang,W. Z.; Nasir, M.; Ma, Y. F.; Zhang, J. L.;Anpo, M. Journal of Catalysis 2013, 297, 236. doi: 10.1016/j.jcat.2012.10.014
13. [13]
  (13) Zhang, X. Y.; Li, H. P.; Cui, X. L. Chin. J. Inorg. Chem. 2009,25, 1903. [张晓艳, 李浩鹏, 崔晓莉. 无机化学学报, 2009,25, 1903.]
14. [14]
  (14) Cong, Y.; Li, X. K.; Qin, Y.; Dong, Z. J.; Yuan, G. M.; Cui, Z.W.; Lai, X. J. Appl. Catal. B 2011, 107, 128. doi: 10.1016/j.apcatb.2011.07.005
15. [15]
  (15) Rincón, M. E.; Trujillo-Camacho, M. E.; Cuentas-Galle s, A.K. Catal. Today 2005, 107-108, 606.
16. [16]
  (16) Soldano, C.; Mahmood, A.; Dujardin, E. Carbon 2010, 48,2127. doi: 10.1016/j.carbon.2010.01.058
17. [17]
  (17) Cong, Y.; Qin, Y.; Li, X. K.; Dong, Z. J.; Yuan, G. M.; Cui, Z.W. Acta Phys. -Chim. Sin. 2011, 27, 1509. [丛野, 秦云,李轩科, 董志军, 袁观明, 崔正威. 物理化学学报, 2011, 27,1509.] doi: 10.3866/PKU.WHXB201203272
18. [18]
  (18) Xiang, Q. J.; Yu, J. G.; Jaroniec, M. Chem. Soc. Rev. 2012, 41,782.
19. [19]
  (19) Jiang, G. D.; Lin, Z. F.; Chen, C.; Zhu, L. H.; Chang, Q.;Wang,N.;Wei,W.; Tang, H. Q. Carbon 2011, 49, 2693. doi: 10.1016/j.carbon.2011.02.059
20. [20]
  (20) Min, Y. L.; Zhang, K.; Zhao,W.; Zheng, F. C.; Chen, Y. C.;Zhang, Y. G. Chemical Engineering Journal 2012, 193-194,203.
21. [21]
  (21) Hummers,W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80,1339. doi: 10.1021/ja01539a017
22. [22]
  (22) Liu, J.; Bai, H.;Wang, Y.; Liu, Z.; Zhang, X.; Sun, D. D. Adv. Funct. Mater. 2010, 20, 4175. doi: 10.1002/adfm.201001391
23. [23]
  (23) Nethravathi, C.; Rajamathi, M. Carbon 2008, 46, 1994.doi: 10.1016/j.carbon.2008.08.013
24. [24]
  (24) Zhou, K. F.; Zhu, Y. H.; Yang, X. L.; Jiang, X.; Li, C. Z. New J. Chem. 2011, 35, 353. doi: 10.1039/c0nj00623h
25. [25]
  (25) Zhang, J. L.; Yang, H. J.; Shen, G. X.; Cheng, P.; Zhang, J. Y.;Guo, S.W. Chem. Commun. 2010, 46, 1112. doi: 10.1039/b917705a
26. [26]
  (26) Wang,W. G.; Yu, J. G.; Xiang, Q. J.; Cheng, B. Appl. Catal. B: Environ. 2012, 119-120, 109.
27. [27]
  (27) Zhang, L.W.; Fu, H. B.; Zhu, Y. F. Adv. Funct. Mater. 2008, 18,2180. doi: 10.1002/adfm.v18:15
28. [28]
  (28) Ma, L. J.; Guo, L. J. Acta Chim. Sin. 2006, 24 (9), 863. [马利静, 郭烈锦. 化学学报, 2006, 24 (9), 863.]
29. [29]
  (29) Zhou, Y.; Bao, Q. L.; Tang, L. A. L.; Zhong, Y. L.; Loh, K. P.Chem. Mater. 2009, 21, 2950. doi: 10.1021/cm9006603
30. [30]
  (30) Yang, Y. H.; Sun, H. J.; Peng, T. J. Chin. J. Inorg. Chem. 2010,26 (11), 2083. [杨勇辉, 孙红娟, 彭同江. 无机化学学报,2010, 26 (11), 2083.
31. [31]
  (31) Zhang, X. Y.; Sun, Y. J.; Cui, X. L.; Jiang, Z. Y. Int. J. hydrog. Energy 2012, 37, 811. doi: 10.1016/j.ijhydene.2011.04.053
32. [32]
  (32) Lei, Y.; Zhang, L. D.; Fan, J. C. Chem. Phys. Lett. 2001, 338,231. doi: 10.1016/S0009-2614(01)00263-9
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Hydrothermal Synthesis and Photocatalytic Activity of Partially Reduced Graphene Oxide/TiO2 Composite

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通讯作者: 陈斌, bchen63@163.com

Hydrothermal Synthesis and Photocatalytic Activity of Partially Reduced Graphene Oxide/TiO₂ Composite