Citation: WANG Sen-Lin, WANG Li-Pin, ZHANG Zhen-Hong. Preparation and Oxygen Evolution Reaction Performance of Ni/NiCo₂O₄ Electrode[J]. Acta Physico-Chimica Sinica, ;2013, 29(05): 981-988. doi: 10.3866/PKU.WHXB201303071 shu

Preparation and Oxygen Evolution Reaction Performance of Ni/NiCo₂O₄ Electrode

1.
Department of Applied Chemistry, College of Materials Science and Engineering, Huaqiao University, Xiamen 361021, P. R. China

Received Date: 30 November 2012
Available Online: 7 March 2013

Spinel-type NiCo₂O₄ powders were prepared by a sol-gel method, and Ni/NiCo₂O₄ electrode was prepared through composite sol method combined with sintering. The composition and structure of Ni/ NiCo₂O₄ were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and energydispersive X-ray spectroscopy (EDS). Electrocatalytic properties of the Ni/NiCo₂O₄ electrode in the oxygen evolution reaction (OER) were studied in 5 mol·L^-1 KOH solution, using cyclic voltammertry (CV), linear sweep voltammetry (LSV), electrochemical impedance spectroscopy (EIS), chronoamperometry, and extended duration constant potential electrolysis. The Ni/NiCo₂O₄ electrode exhibited a lower OER overpotential, higher specific surface area, and better stability than a porous Ni electrode. The specific surface area of the Ni/NiCo₂O₄ electrode was 28.69 times greater than that of the porous Ni electrode, and its apparent activation energies decrease 166.78 and 162.15 kJ·mol^-1 at different overpotentials, respectively.
- Sol-gel,
- NiCo₂O₄,
- Porous nickel,
- Oxygen evolution reaction,
- Electrocatalysis
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Oxygen Evolution Reaction Performance of Ni/NiCo2O4 Electrode

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通讯作者: 陈斌, bchen63@163.com

Preparation and Oxygen Evolution Reaction Performance of Ni/NiCo₂O₄ Electrode