Citation: CHEN Yong-Dong, WANG Lei, GUAN Xiao-Xu, LIU Yong-Bing, NG Mao-Chu, CHEN Yao-Qiang. Catalytic Oxidation of Soluble Organic Fraction in Diesel Exhausts Using Composite Oxides (CeO₂)_x(La-Al₂O₃)_1-x[J]. Acta Physico-Chimica Sinica, ;2013, 29(05): 1048-1054. doi: 10.3866/PKU.WHXB201303051 shu

Catalytic Oxidation of Soluble Organic Fraction in Diesel Exhausts Using Composite Oxides (CeO₂)_x(La-Al₂O₃)_1-x

1.
1 State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu 610500, P. R. China;
2 Southwest Research & Design Institute of Chemical Industry, Chengdu 610225, P. R. China;
3 Key Laboratory of Green Chemistry & Technology of Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, P. R. China

Received Date: 6 December 2012
Available Online: 5 March 2013
Fund Project: 国家自然科学基金(21173153) (21173153) 四川省教育厅一般项目(12ZB163) (12ZB163) 绿色催化四川省高校重点实验室开放课题基金(LYY1101) (LYY1101) 四川省科技创新苗子工程项目(2012ZZ072) (2012ZZ072)西南石油大学校级科技基金(2012XJZ037)资助 (2012XJZ037)

A series of catalytic composite oxides (CeO₂)_x(La-Al₂O₃)_1-x (with mass fractions x=0.00, 0.25, 0.50, 0.75, 1.00) was prepared using a co-precipitation method. Thermogravimetric-differential thermal analysis (TG-DTA) was used to determine the performances of these composite oxides in the catalytic oxidation of the soluble organic fraction (SOF) of diesel exhaust. The results show that the catalyst with the highest activity, i.e., x=0.75, enabled the SOF to light-off at 125℃ and completely converted the SOF at 355℃. The catalysts were characterized using low-temperature N2 absorption-desorption, oxygen-storage capacity (OSC) measurements, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and H₂ temperature-programmed reduction(H₂-TPR). The results indicate that co-doping appropriate amounts of La and Al into the catalyst increases the specific surface area of the cerium oxide and the proportion of Ce³⁺ in the catalyst. This may improve the catalyst's adsorption abilities at low temperature and its OSC, enhancing its activity in SOF oxidation. These (CeO₂)_0.75(La-Al₂O₃)_0.25 composite oxides are promising catalysts for diesel oxidation.
- Cerium,
- Aluminum,
- Composite oxide,
- Soluble organic fraction,
- Catalytic oxidation
1. [1]
  
  (1) Nejar, N.; Makkee, M.; Illán-Gómez, M. J. Appl. Catal. B 2007,75, 11. doi: 10.1016/j.apcatb.2007.03.009
2. [2]
  (2) Zhao, Z.; Zhang, G. Z.; Liu, J.; Liang, P.; Xu, J.; Duan, A. J.;Jiang, G. Y.; Xu, C. M. Chin. J. Catal. 2008, 29, 303. [赵震,张桂臻, 刘坚, 梁鹏, 许洁, 段爱军, 姜桂元, 徐春明. 催化学报, 2008, 29, 303.]
3. [3]
  (3) Johnson, T. V. SAE Int. J. Fuels Lubr. 2009, 2, 1.
4. [4]
  (4) Yang, Z. Z.; Chen, Y. D.; Zhao, M.; Zhou, J. F.; ng, M. C.;Chen, Y. Q. Chin. J. Catal. 2012, 33, 819. [杨铮铮, 陈永东,赵明, 周菊发, 龚茂初, 陈耀强. 催化学报, 2012, 33, 819.]
5. [5]
  (5) Zhou, J. F.; Zhao, M.; Peng, N.; Yang, Z. Z.; ng, M. C.;Chen, Y. Q. Acta Phys. -Chim. Sin. 2012, 28, 1448. [周菊发,赵明, 彭娜, 杨铮铮, 龚茂初, 陈耀强. 物理化学学报,2012, 28, 1448.] doi: 10.3866/PKU.WHXB201204011
6. [6]
  (6) Durán, A.; Carmona, M.; Monteagudo, J. M. Chemosphere2004, 56, 209. doi: 10.1016/j.chemosphere.2004.03.008
7. [7]
  (7) Maricq, M. M. Aerosol Science 2007, 1079, 38.
8. [8]
  (8) Farrauto, R. J.; Voss, K. E. Appl. Catal. B 1996, 10, 29. doi: 10.1016/0926-3373(96)00022-7
9. [9]
  (9) Ozaki, T.; Masui, T.; Machida, K.; Adachi, G.; Sakata, T.; Mori,H. Chem. Mater. 2000, 12, 643. doi: 10.1021/cm9903374
10. [10]
  (10) Thammachart, M.; Meeyoo, V.; Risksomboon, T.; Osuwan, S.Catal. Today 2001, 68, 53. doi: 10.1016/S0920-5861(01)00322-4
11. [11]
  (11) Voss, K. E.; Yavuz, B. O.; Farrauto, R. J.; Galligan, M. P.Oxidation Catalyst with Bulk Ceria, a Second Bulk MetalOxide, and Platinum. U. S. Pat. 5491120, 1996.
12. [12]
  (12) Voss, K. E.; Yavuz, B. O.; Farrauto, R. J.; Galligan, M. P.Oxidation Catalyst and Method of Use. U. S. Pat. 6255249,2001.
13. [13]
  (13) Turko, G. A.; Ivanova, A. S.; Plyasova, L. M.; Litvak, G. S.;Ro v, V. A. Kinet. Catal. 2005, 46, 932.
14. [14]
  (14) Lv, J. D.;Wang, L.; Lei, D.; Guo, H. X.; Kumar, R. V. J. Alloy.Compd. 2009, 467, 376. doi: 10.1016/j.jallcom.2007.12.103
15. [15]
  (15) Xiao, Y. H.; Yang, H. G.; Cai, G. H.; Zheng, Y.; Zheng, Y.;Wei,K. M. Acta Phys. -Chim. Sin. 2012, 28, 245. [肖益鸿, 杨黄根,蔡国辉, 郑勇, 郑瑛, 魏可镁. 物理化学学报, 2012, 28,245.] doi: 10.3866/PKU.WHXB201228245
16. [16]
  (16) Chen, Y. D.;Wang, L.; Tang, S. H.; Cao, H. Y.; ng, M. C.;Chen, Y. Q. Acta Phys. -Chim. Sin. 2012, 28, 1237. [陈永东,王磊, 唐水花, 曹红岩, 龚茂初, 陈耀强. 物理化学学报,2012, 28, 1237.] doi: 10.3866/PKU.WHXB201203141
17. [17]
  (17) Zhang, Z. L.; Zhang, Y. X.; Mu, Z. G.; Yu, P. F.; Ni, X. Z.;Wang, S. L.; Zheng, L. S. Appl. Catal. B 2007, 76, 335. doi: 10.1016/j.apcatb.2007.06.011
18. [18]
  (18) Wang, J.;Wen, J.; Shen, M. Q. J. Phys. Chem. C 2008, 112,5113.
19. [19]
  (19) Li, B.; Li, S. J.;Wang, Y. X.; Li, N.; Zhang,W. J.; Lin, B. X.Chin. J. Catal. 2010, 31, 528. [李斌, 李士杰, 王颖霞,李能, 张婉静, 林炳雄. 催化学报, 2010, 31, 528.] doi: 10.1016/S1872-2067(09)60067-X
20. [20]
  (20) Hori, C. E.; Permana, H.; Simon Ng, K. Y.; Brenner, A.; More,K.; Rahmoeller, K. M.; Belton, D. Appl. Catal. B 1998, 16, 105.doi: 10.1016/S0926-3373(97)00060-X
21. [21]
  (21) Leofanti, G.; Padovan, M.; Tozzola, G.; Venturelli, B. Catal.Today 1998, 41, 207. doi: 10.1016/S0920-5861(98)00050-9
22. [22]
  (22) Jen, H.W.; Graham, G.W.; Chun,W.; McCabe, R.W.; Cuif, J.P.; Deutsch, S. E.; Touret, O. Catal. Today 1999, 50, 309. doi: 10.1016/S0920-5861(98)00512-4
23. [23]
  (23) Civera, A.; Pavese, M.; Saracco, G.; Specchia, V. Catal. Today2003, 83, 199. doi: 10.1016/S0920-5861(03)00220-7
24. [24]
  (24) He, H.; Dai, H. X.;Wong, K.W.; Au, C. T. Appl. Catal. A 2003,251, 61. doi: 10.1016/S0926-860X(03)00309-0
25. [25]
  (25) Larachi, F.; Pierre, J.; Adnot, A.; Bernis, A. Applied SurfaceScience 2002, 195, 236. doi: 10.1016/S0169-4332(02)00559-7
26. [26]
  (26) Zhong, L. S.; Hu, J. S.; Cao, A. M.; Liu, Q.; Song,W. G.;Wan,L. J. Chem. Mater. 2007, 19, 1648. doi: 10.1021/cm062471b
27. [27]
  (27) Vidal, H.; Kašpar, J.; Pijolat, M.; Colonb, G.; Bernal, S.;Cordón, A.; Perrichon, V.; Fally, F. Appl. Catal. B 2000, 27, 49.doi: 10.1016/S0926-3373(00)00138-7
28. [28]
  (28) Shyu, J. Z.;Weber,W. H.; Gandhi, H. S. J. Phys. Chem. C 1988,92, 4964. doi: 10.1021/j100328a029
1. [1]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
2. [2]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
3. [3]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
4. [4]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
5. [5]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
6. [6]
  Shicheng Yan . Experimental Teaching Design for the Integration of Scientific Research and Teaching: A Case Study on Organic Electrooxidation. University Chemistry, 2024, 39(11): 350-358. doi: 10.12461/PKU.DXHX202408036
7. [7]
  Anqiu LIU , Long LIN , Dezhi ZHANG , Junyu LEI , Kefeng WANG , Wei ZHANG , Junpeng ZHUANG , Haijun HAO . Synthesis, structures, and catalytic activity of aluminum and zinc complexes chelated by 2-((2,6-dimethylphenyl)amino)ethanolate. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 791-798. doi: 10.11862/CJIC.20230424
8. [8]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
9. [9]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
10. [10]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
11. [11]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
12. [12]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
13. [13]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
14. [14]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
15. [15]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
16. [16]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
17. [17]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
18. [18]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117
19. [19]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
20. [20]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469

Get Citation

PDF

XML

Metrics

PDF Downloads(581)
Abstract views(976)
HTML views(5)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Catalytic Oxidation of Soluble Organic Fraction in Diesel Exhausts Using Composite Oxides (CeO2)x(La-Al2O3)1-x

Metrics

通讯作者: 陈斌, bchen63@163.com

Catalytic Oxidation of Soluble Organic Fraction in Diesel Exhausts Using Composite Oxides (CeO₂)_x(La-Al₂O₃)_1-x