Citation: CHEN Hong-Li, DING Jian, WANG Yi-Meng. Synthesis of Hierarchical M -Containing Silicalite-1 Zeolites with High Hydrothermal Stability[J]. Acta Physico-Chimica Sinica, ;2013, 29(05): 1035-1040. doi: 10.3866/PKU.WHXB201302223 shu

Synthesis of Hierarchical M -Containing Silicalite-1 Zeolites with High Hydrothermal Stability

1.
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, P. R. China

Received Date: 15 November 2012
Available Online: 22 February 2013
Fund Project: 国家自然科学基金(20890124) (20890124)国家科技支撑计划(2012BAE05B02)资助 (2012BAE05B02)

Hierarchical M /silicalite-1 composites were synthesized via hydrothermal treatment of M -supported porous silica using tetrapropylammonium hydroxide (TPAOH) as a template. M species were introduced into porous silica via solid-state grinding and subsequent calcination. X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDX), and transmission electron microscopy (TEM) results indicated that M was uniformly distributed in the zeolite crystals. The hydrothermal stability of M / silicalite-1 before and after acid washing was detected by treatment at 800℃ in 100% steam for 10 h. The introduction of M increased the hydrothermal stability of M /silicalite-1 samples. Furthermore, acid washing could remove M impurities, increasing the relative crystallinity of samples compared with that of calcined M /silicalite-1 and introducing mesopore into zeolite simultaneously. N₂ adsorption-desorption measurements indicated that mesopores were generated in the zeolite crystals by the removal of M species. The improved hydrothermal stability and the generation of mesopores in these M /silicalite-1 samples play important roles in preserving zeolite structure, enhancing coke tolerance, slowing deactivation, and extending catalyst life during high-temperature reaction.
- M ,
- Zeolite,
- Hydrothermal stability,
- Hierarchical porosity
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沈阳化工大学材料科学与工程学院沈阳 110142