Citation: CHEN Hong-Li, DING Jian, WANG Yi-Meng. Synthesis of Hierarchical M -Containing Silicalite-1 Zeolites with High Hydrothermal Stability[J]. Acta Physico-Chimica Sinica, ;2013, 29(05): 1035-1040. doi: 10.3866/PKU.WHXB201302223 shu

Synthesis of Hierarchical M -Containing Silicalite-1 Zeolites with High Hydrothermal Stability

1.
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, P. R. China

Received Date: 15 November 2012
Available Online: 22 February 2013
Fund Project: 国家自然科学基金(20890124) (20890124)国家科技支撑计划(2012BAE05B02)资助 (2012BAE05B02)

Hierarchical M /silicalite-1 composites were synthesized via hydrothermal treatment of M -supported porous silica using tetrapropylammonium hydroxide (TPAOH) as a template. M species were introduced into porous silica via solid-state grinding and subsequent calcination. X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDX), and transmission electron microscopy (TEM) results indicated that M was uniformly distributed in the zeolite crystals. The hydrothermal stability of M / silicalite-1 before and after acid washing was detected by treatment at 800℃ in 100% steam for 10 h. The introduction of M increased the hydrothermal stability of M /silicalite-1 samples. Furthermore, acid washing could remove M impurities, increasing the relative crystallinity of samples compared with that of calcined M /silicalite-1 and introducing mesopore into zeolite simultaneously. N₂ adsorption-desorption measurements indicated that mesopores were generated in the zeolite crystals by the removal of M species. The improved hydrothermal stability and the generation of mesopores in these M /silicalite-1 samples play important roles in preserving zeolite structure, enhancing coke tolerance, slowing deactivation, and extending catalyst life during high-temperature reaction.
- M ,
- Zeolite,
- Hydrothermal stability,
- Hierarchical porosity
1. [1]
  
  (1) Quann, R. J.; Green, L. A.; Tabak, S. A.; Krambeck, F. J.Industrial & Engineering Chemistry Research 1988, 27, 565.doi: 10.1021/ie00076a006
2. [2]
  (2) Yamamura, M.; Chaki, K.;Wakatsuki, T.; Okado, H.; Fujimoto,K. Zeolites 1994, 14, 643. doi: 10.1016/0144-2449(94)90121-X
3. [3]
  (3) Jiang, N.; Jin, H.; Jeong, E. Y.; Park, S. E. Journal ofNanoscience and Nanotechnology 2010, 10, 227. doi: 10.1166/jnn.2010.1513
4. [4]
  (4) Asencios, Y. J. O.; Bellido, J. D. A.; Assaf, E. M. AppliedCatalysis A: General 2011, 397, 138. doi: 10.1016/j.apcata.2011.02.023
5. [5]
  (5) Li, X. L.; Yue, B. H.;Wang, X. G.; Yan, Y. F.; Kong, L. H.; Lu,X. G.; Ding,W. Z. Acta Physico-Chimica Sinica 2009, 25, 762.[李雪玲, 岳宝华, 汪学广, 鄢于飞, 孔令华, 鲁雄刚, 丁伟中.物理化学学报, 2009, 25, 762.] doi: 10.3866/PKU.WHXB200904231
6. [6]
  (6) Huber, G.W.; Guymon, C. G.; Conrad, T. L.; Stephenson, B. C.;Bartholomew, C. H. Stud. Surf. Sci. Catal. 2001, 139, 423. doi: 10.1016/S0167-2991(01)80226-3
7. [7]
  (7) Chen, N. Y.; Mitchell, T. O.; Olson, D. H.; Pelrine, B. P. Ind.Eng. Chem., Prod. Res. Dev. 1977, 16, 247.
8. [8]
  (8) Finnerty, C. M.; Coe, N. J.; Cunningham, R. H.; Ormerod, R.M. Catal. Today 1998, 46, 137. doi: 10.1016/S0920-5861(98)00335-6
9. [9]
  (9) Beyne, A. O. E.; Froment, G. F. Chem. Eng. Sci. 1993, 48, 503.doi: 10.1016/0009-2509(93)80304-9
10. [10]
  (10) Beyne, A. O. E.; Froment, G. F. Chem. Eng. Sci. 1990, 45, 2089.doi: 10.1016/0009-2509(90)80081-O
11. [11]
  (11) Chen, D.; Rebo, H. P.; Moljord, K.; Holmen, A. Industrial &Engineering Chemistry Research 1997, 36, 3473. doi: 10.1021/ie9700223
12. [12]
  (12) Triantafyllopoulos, N. C.; Neophytides, S. G. J. Catal. 2003,217, 324.
13. [13]
  (13) Trimm, D. L. Catal. Today 1999, 49, 3. doi: 10.1016/S0920-5861(98)00401-5
14. [14]
  (14) Voskoboynikov, T. V.; Pelekh, A. Y.; Senetar, J. J. OCP Catalystwith Improved Steam Tolerance. US Patent 12/639, 577. X,2011-06-16.
15. [15]
  (15) Choi, M.; Na, K.; Kim, J.; Sakamoto, Y.; Terasaki, O.; Ryoo, R.Nature 2009, 461, 246.
16. [16]
  (16) Verboekend, D.; Groen, J. C.; Pérez-Ramírez, J. Adv. Funct.Mater. 2010, 20, 1441. doi: 10.1002/adfm.200902205
17. [17]
  (17) Chen, L.; Zhu, S. Y.;Wang, H. M.;Wang, Y. M. Solid StateSciences 2011, 13, 2024. doi: 10.1016/j.solidstatesciences.2011.08.033
18. [18]
  (18) Chen, L.; Zhu, S. Y.;Wang, Y. M.; He, M. Y. New J. Chem.2010, 34, 2328. doi: 10.1039/c0nj00316f
19. [19]
  (19) Itoh, H.; Hattori, T.; Suzuki, K.; Murakami, Y. J. Catal. 1983,79, 21. doi: 10.1016/0021-9517(83)90286-5
20. [20]
  (20) Hathaway, P. E.; Davis, M. E. J. Catal. 1989, 119, 497. doi: 10.1016/0021-9517(89)90177-2
21. [21]
  (21) Wieland,W. S.; Davis, R. J.; Garces, J. M. J. Catal. 1998, 173,490. doi: 10.1006/jcat.1997.1952
22. [22]
  (22) Hunger, M.; Schenk, U.;Weitkamp, J. J. Mol. Catal. A: Chem.1998, 134, 97. doi: 10.1016/S1381-1169(98)00026-0
23. [23]
  (23) Yue, B. H.; Kong, L. H.;Wang, X. G.; Lu, X. G.; Ding,W. Z.Chinese Jounal of Catalysis 2010, 31, 218. [岳宝华, 孔令华,汪学广, 鲁雄刚, 丁伟中. 催化学报, 2010, 31, 218.]
24. [24]
  (24) Mao, D. S.; Guo, Q. S.; Meng, T. Acta Physico-Chimica Sinica2010, 26, 2242. [毛东森, 郭强胜, 孟涛. 物理化学学报,2010, 26, 2242.] doi: 10.3866/PKU.WHXB20100814
25. [25]
  (25) Zhang, F.; Miao, C. X.; Yue, Y. H.; Hua,W. M.; Gao, Z. Chin. J.Chem. 2012, 30, 929. [张帆, 缪长喜, 乐英红, 华伟明,高滋. 中国化学, 2012, 30, 929.] doi: 10.1002/cjoc.201100379
26. [26]
  (26) Wang, Y. M.;Wu, Z. Y.; Zhu, J. H. J. Solid State Chem. 2004,177, 3815. doi: 10.1016/j.jssc.2004.07.013
1. [1]
  Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
2. [2]
  Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049
3. [3]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
4. [4]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
5. [5]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
6. [6]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
7. [7]
  Shitao Fu , Jianming Zhang , Cancan Cao , Zhihui Wang , Chaoran Qin , Jian Zhang , Hui Xiong . Study on the Stability of Purple Cabbage Pigment. University Chemistry, 2024, 39(4): 367-372. doi: 10.3866/PKU.DXHX202401059
8. [8]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
9. [9]
  Shicheng Yan . Experimental Teaching Design for the Integration of Scientific Research and Teaching: A Case Study on Organic Electrooxidation. University Chemistry, 2024, 39(11): 350-358. doi: 10.12461/PKU.DXHX202408036
10. [10]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
11. [11]
  Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029
12. [12]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
13. [13]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
14. [14]
  Ji-Quan Liu , Huilin Guo , Ying Yang , Xiaohui Guo . Calculation and Discussion of Electrode Potentials in Redox Reactions of Water. University Chemistry, 2024, 39(8): 351-358. doi: 10.3866/PKU.DXHX202401031
15. [15]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
16. [16]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
17. [17]
  Wenliang Wang , Weina Wang , Sufan Wang , Tian Sheng , Tao Zhou , Nan Wei . “Schrödinger Equation – Approximate Models – Core Concepts – Simple Applications”: Constructing a Logical Framework and Knowledge Graph of Atom and Molecule Structures. University Chemistry, 2024, 39(8): 338-343. doi: 10.3866/PKU.DXHX202312084
18. [18]
  Hongyun Liu , Jiarun Li , Xinyi Li , Zhe Liu , Jiaxuan Li , Cong Xiao . Course Ideological and Political Design of a Comprehensive Chemistry Experiment: Constructing a Visual Molecular Logic System Based on Intelligent Hydrogel Film Electrodes. University Chemistry, 2024, 39(2): 227-233. doi: 10.3866/PKU.DXHX202309070
19. [19]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
20. [20]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125

Get Citation

PDF

XML

Metrics

PDF Downloads(591)
Abstract views(977)
HTML views(34)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142