Citation: WANG Yan-Jun, JIA Li-Hui, WANG Bing-Wu. Synthesis, Structure and Magnetic Properties of Iron(II) Sulfate Containing Hydrazine[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201302212 shu

Synthesis, Structure and Magnetic Properties of Iron(II) Sulfate Containing Hydrazine

1.
1 Key Laboratory for Green Chemical Process of Ministry of Education, School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan 430074, P. R. China;
2 Beijing National Laboratory of Molecular Science, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received Date: 10 January 2013
Available Online: 21 February 2013
Fund Project: 国家自然科学基金(21101123, 21071008)资助项目 (21101123, 21071008)

A novel transition metal iron(II) sulfate containing hydrazine (N₂H₄) ligand: [Fe(N₂H₅)₂(SO₄)₂]_n(1), is prepared by a hydrothermal method. Single-crystal X-ray diffraction reveals that 1 consists of onedimensional (1D) sulfate-bridged homometallic chains with protonated hydrazine molecules as terminal ligands. Hydrogen bonds between protonated hydrazine and sulfate ions connect the chains into a threedimensional (3D) extended framework. Magnetic measurements indicate that 1 exhibits the antiferromagnetic ordering behavior at low temperature.
- Hydrazine,
- Sulfate group,
- Ferrous ion,
- Antiferromagnetic interaction,
- Magnetic ordering
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