Citation: CAI Hong-Min, REN Su-Zhen, WANG Meng, JIA Cui-Ying. Preparation and Properties of Monodisperse SnO₂ Hollow Micro/Nano Spheres[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201302051 shu

Preparation and Properties of Monodisperse SnO₂ Hollow Micro/Nano Spheres

1.
1 College of Chemistry, Dalian University of Technology, Dalian, 116024, Liaoning Province, P. R. China;
2 The experiment center of Chemistry, Dalian University of Technology, Dalian, 116024, Liaoning Province, P. R. China

Received Date: 26 November 2012
Available Online: 5 February 2013
Fund Project: 国家自然科学基金(21176043)资助项目 (21176043)

Templating is one of the most important methods for preparation of inorganic hollow micro/ nano spheres. We prepared monodisperse polystyrene (PS) microspheres having a diameter of 620 nm by the emulsion polymerization of styrene. Sulfonated polystyrene (PSS) microspheres were used as a template, through electrostatic adsorption of anions and cations, for modification with Sn²⁺ from SnSO₄ precursor. The core-shell composite structures thereby produced through Sn²⁺ hydrolysis in an ethanolwater medium were calcined at high temperature to remove PSS and to obtain SnO₂ hollow micro/nano spheres. We investigated the effects of precursor concentration, amount of surfactant, reaction time, and templates choice. Scanning electron microscopy (SEM), X-ray diffraction (XRD), infrared (IR) spectroscopy, thermogravimetric analysis (TGA), H₂ temperature programmed reduction (H₂-TPR), Brunauer-Emmett-Teller (BET) measurement, and other technical probes were used to detect the structure and properties of the prepared SnO₂ hollow micro/nano spheres, and compared them with those of solid SnO₂. BET and H₂-TPR showed that the hollow SnO₂ micro/nano spheres had improved specific surface area, surface oxygen vacancies, and oxidation activity. We inferred the growth mechanism of the core-shell structure from IR spectroscopy and XRD pattern and optimized the simple and reasonable synthesis procedure to obtain SnO₂ hollow micro/nano spheres which had smooth surface, compact structure, and well controlled cladding thickness.
- SnO₂,
- Hollow micro/nano sphere,
- Core-shell structure,
- Template method,
- Hydrolysis
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Preparation and Properties of Monodisperse SnO₂ Hollow Micro/Nano Spheres