Citation: HE Peng, GAO Xiang-Dong, WU Li-Bin, JIANG Zheng-Wu, WANG Cai-Lu, LI Xiao-Min. Porous ZnO Sheets Transformed from Zinc Sulfate Hydroxide Hydrate and Their Photoluminescence Performance[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201302045 shu

Porous ZnO Sheets Transformed from Zinc Sulfate Hydroxide Hydrate and Their Photoluminescence Performance

HE Peng ^1,2 ,
GAO Xiang-Dong ^1, ,
WU Li-Bin ³ ,
JIANG Zheng-Wu ⁴ ,
WANG Cai-Lu ^1,2 ,
LI Xiao-Min ¹

1.
1 State Key Laboratory of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, P. R. China;
2 University of Chinese Academy of Sciences, Beijing 100049, P. R. China;
3 Shanghai Research Institute of Petrochemical Technology, Shanghai 200137, P. R. China;
4 Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, Tongji University, Shanghai 201804, P. R. China

Received Date: 7 November 2012
Available Online: 4 February 2013
Fund Project: 国家重点基础研究发展规划(973) (2009CB623304, 2011CB013805) (973) (2009CB623304, 2011CB013805)国家自然科学基金(51072214, 51002174)资助项目 (51072214, 51002174)

Highly crystalline, porous ZnO sheets were prepared from chemically-deposited zinc sulfate hydroxide hydrate (ZSH) sheets by sintering at 1000 ℃. The formation mechanism of ZSH in Zn²⁺- hexamethyltetramine (HMT) precursor system, the transformation process of ZSH to ZnO, and the crystalline, microstructural and optical properties of the ZnO sheets were investigated. The porous ZnO sheets possessed a well-defined hexa nal shape with controllable size (10-50 μm) and thickness (200-500 nm), high crystallinity, and strong ultraviolet photoluminescence without detectable defectrelated visible emission. Submicron-sized pores (100-500 nm) and poly nal or irregular ZnO particles resulting from the limited mass transport during high temperature sintering were observed in the ZnO sheets. Analysis of the formation mechanism indicated that the high affinity of SO₄^2- for Zn²⁺ was responsible for the formation of ZSH in the Zn²⁺-HMT precursor system, and the thermolysis of ZSH affected the morphology and microstructure of the ZnO sheets. This work reveals a facile route to porous ZnO nanostructures with od crystallinity and optical properties, which make them suitable for application in catalysis, and photo and/or electrical devices.
- ZnO,
- Porous sheet,
- Zinc sulfate hydroxide hydrate,
- Photoluminescence
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