Citation: HE Peng, GAO Xiang-Dong, WU Li-Bin, JIANG Zheng-Wu, WANG Cai-Lu, LI Xiao-Min. Porous ZnO Sheets Transformed from Zinc Sulfate Hydroxide Hydrate and Their Photoluminescence Performance[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201302045 shu

Porous ZnO Sheets Transformed from Zinc Sulfate Hydroxide Hydrate and Their Photoluminescence Performance

HE Peng ^1,2 ,
GAO Xiang-Dong ^1, ,
WU Li-Bin ³ ,
JIANG Zheng-Wu ⁴ ,
WANG Cai-Lu ^1,2 ,
LI Xiao-Min ¹

1.
1 State Key Laboratory of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, P. R. China;
2 University of Chinese Academy of Sciences, Beijing 100049, P. R. China;
3 Shanghai Research Institute of Petrochemical Technology, Shanghai 200137, P. R. China;
4 Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, Tongji University, Shanghai 201804, P. R. China

Received Date: 7 November 2012
Available Online: 4 February 2013
Fund Project: 国家重点基础研究发展规划(973) (2009CB623304, 2011CB013805) (973) (2009CB623304, 2011CB013805)国家自然科学基金(51072214, 51002174)资助项目 (51072214, 51002174)

Highly crystalline, porous ZnO sheets were prepared from chemically-deposited zinc sulfate hydroxide hydrate (ZSH) sheets by sintering at 1000 ℃. The formation mechanism of ZSH in Zn²⁺- hexamethyltetramine (HMT) precursor system, the transformation process of ZSH to ZnO, and the crystalline, microstructural and optical properties of the ZnO sheets were investigated. The porous ZnO sheets possessed a well-defined hexa nal shape with controllable size (10-50 μm) and thickness (200-500 nm), high crystallinity, and strong ultraviolet photoluminescence without detectable defectrelated visible emission. Submicron-sized pores (100-500 nm) and poly nal or irregular ZnO particles resulting from the limited mass transport during high temperature sintering were observed in the ZnO sheets. Analysis of the formation mechanism indicated that the high affinity of SO₄^2- for Zn²⁺ was responsible for the formation of ZSH in the Zn²⁺-HMT precursor system, and the thermolysis of ZSH affected the morphology and microstructure of the ZnO sheets. This work reveals a facile route to porous ZnO nanostructures with od crystallinity and optical properties, which make them suitable for application in catalysis, and photo and/or electrical devices.
- ZnO,
- Porous sheet,
- Zinc sulfate hydroxide hydrate,
- Photoluminescence
1. [1]
  
  (1) Wang, Z. L. Mat. Sci. Eng. R 2009, 64, 33. doi: 10.1016/j.mser.2009.02.001
2. [2]
  (2) Yoshida, T.; Terada, K.; Schlettwein, D.; Oekermann, T.;Sugiura, T.; Minoura, H. Adv. Mater. 2000, 12, 1214.
3. [3]
  (3) Li, S.; Li, Z.W.; Tay, Y. Y.; Armellin, J.; Gao,W. Cryst. GrowthDes. 2008, 8, 1623. doi: 10.1021/cg701056q
4. [4]
  (4) Liu, Z.;Wen, X. D.;Wu, X. L.; Gao, Y. J.; Chen, H. T.; Zhu, J.;Chu, P. K. J. Am. Chem. Soc. 2009, 131, 9405. doi: 10.1021/ja9039136
5. [5]
  (5) Shen, J. B.; Zhuang, H. Z.;Wang, D. X.; Xue, C. S.; Liu, H.Cryst. Growth Des. 2009, 9, 2187. doi: 10.1021/cg800847d
6. [6]
  (6) Zhang, J.;Wang, S. R.; Xu, M. J.;Wang, Y.; Zhu, B. L.; Zhang,S. M.; Huang,W. P.;Wu, S. H. Cryst. Growth Des. 2009, 9,3532. doi: 10.1021/cg900269a
7. [7]
  (7) Chivukula, V.; Ciplys, D.; Shur, M.; Dutta, P. Appl. Phys. Lett.2010, 96, 233512. doi: 10.1063/1.3447932
8. [8]
  (8) Park, H. Y.; , H. Y.; Kalme, S.; Mane, R. S.; Han, S. H.;Yoon, M. Y. Anal. Chem. 2009, 81, 4280. doi: 10.1021/ac900632n
9. [9]
  (9) Zhang, Q. F.; Chou, T. R.; Russo, B.; Jenekhe, S. A.; Cao, G. Z.Angew. Chem. Int. Edit. 2008, 47, 2402.
10. [10]
  (10) Wang, Q.; Geng, B. Y.;Wang, S. Z. Environ. Sci.Technol. 2009,43, 8968. doi: 10.1021/es902568h
11. [11]
  (11) Yang, M.; Sun, K.; Kotov, N. A. J. Am. Chem. Soc. 2010, 132,1860. doi: 10.1021/ja906868h
12. [12]
  (12) Jung, S.; Cho,W.; Lee, H. J.; Oh, M. Angew. Chem. Int. Edit.2009, 48, 1459. doi: 10.1002/anie.v48:8
13. [13]
  (13) Shan, C. X.; Liu, Z.; Zhang, Z. Z.; Shen, D. Z.; Hark, S. K.J. Phys. Chem. B 2006, 110, 11176. doi: 10.1021/jp0600514
14. [14]
  (14) Wu, J. H.; Varghese, B.; Zhou, X. D.; Teo, S. Y.; Sow, C. H.;Ang, S. G.; Xu, G. Q. Chem. Mater. 2010, 22, 1533. doi: 10.1021/cm902490g
15. [15]
  (15) Qian, H. S.; Yu, S. H.; ng, J. Y.; Luo, L. B.;Wen, L. L. Cryst.Growth Des. 2005, 5, 935. doi: 10.1021/cg049666l
16. [16]
  (16) Kong, Q. S.;Wu, X. L.; Guo, Y. G.;Wang, Y. Q.; Xia, Y. Z.; Yu,J.; Liu, H. H.; Duan, X. F. Acta Phys. -Chim. Sin. 2008, 24,2179. [孔庆山, 吴兴隆, 郭玉国, 王乙潜, 夏延致, 于建,刘海华, 段晓峰. 物理化学学报, 2008, 24, 2179.] doi: 10.3866/PKU.WHXB20081206
17. [17]
  (17) Zhou, X. F.; Hu, Z. L.; Fan, Y. Q.; Chen, S.; Ding,W. P.; Xu, N.P. J. Phys. Chem. C 2008, 112, 11722. doi: 10.1021/jp802619j
18. [18]
  (18) Gao, X. D.; Li, X. M.; Gao,W.; Qiu, J. J.; Gan, X. Y.;Wang, C.L.; Leng, X. Crystengcomm 2011, 13, 4741. doi: 10.1039/c1ce05125c
19. [19]
  (19) Gao, X. D.; Li, X. M.; Yu,W. D.; Peng, F.; Zhang, C. Y.Materials Research Bulletin 2006, 41, 608. doi: 10.1016/j.materresbull.2005.09.001
20. [20]
  (20) Vayssieres, L. Adv. Mater. 2003, 15, 464. doi: 10.1002/adma.200390108
21. [21]
  (21) Tagawa, H.; Saijo, H. Thermochimica Acta 1985, 91, 67. doi: 10.1016/0040-6031(85)85202-3
22. [22]
  (22) Gao, X. D.; Gao,W.; Yan, X. D.; Zhuge, F.W.; Bian, J. M.; Li,X. M. Funct. Mater. Lett. 2009, 2, 27. doi: 10.1142/S1793604709000508
23. [23]
  (23) Qiu, Y. C.; Chen,W.; Yang, S. H. J. Mater. Chem. 2010, 20,1001. doi: 10.1039/b917305f
24. [24]
  (24) Hsueh, T. J.; Hsu, C. L. Sens. Actuator B-Chem. 2008, 131, 572.doi: 10.1016/j.snb.2007.12.045
25. [25]
  (25) Gao, M. D.; Li, M. M.; Yu,W. D. J. Phys. Chem. B 2005, 109,1155. doi: 10.1021/jp046267s
26. [26]
  (26) Wang, D. L.; Ruan, Y. F.; Zhang, L. C.; Yang, H. B. ActaPhys. -Chim. Sin. 2010, 26, 3369. [王丹丽, 阮永丰, 张灵翠,杨红波. 物理化学学报, 2010, 26, 3369.] doi: 10.3866/PKU.WHXB201210082
27. [27]
  (27) Zhao, J. L.; Li, X. M.; Bian, J. M.; Yu,W. D.; Zhang, C. Y. ThinSolid Films 2006, 515, 1763. doi: 10.1016/j.tsf.2006.06.032
28. [28]
  (28) Kim, D.; Shimomura, T.;Wakaiki, S.; Terashita, T.; Nakayama,M. Physica B 2006, 376, 741. doi: 10.1016/j.physb.2005.12.185
29. [29]
  (29) Al-Salman, H. S.; Abdullah, M. J. J. Alloy. Compd. 2013, 547,132. doi: 10.1016/j.jallcom.2012.08.119
30. [30]
  (30) Gu, Y. F.; Li, X. M.; Yu,W. D.; Gao, X. D.; Zhao, J. L.; Yang, C.J. Cryst. Growth 2007, 305, 36. doi: 10.1016/j.jcrysgro.2007.03.050
31. [31]
  (31) Li, C.; Fang, G. J.; Fu, Q.; Su, F. H.; Li, G. H.;Wu, X. G.; Zhao,X. Z. J. Cryst. Growth 2006, 292, 19. doi: 10.1016/j.jcrysgro.2006.03.061
32. [32]
  (32) Zhang, X. H.; Yan, X. Q.; Zhao, J.; Qin, Z.; Zhang, Y. Mater.Lett. 2009, 63, 444. doi: 10.1016/j.matlet.2008.11.006
33. [33]
  (33) Yoo, Y. Z.; Jin, Z.W.; Chikyow, T.; Fukumura, T.; Kawasaki,M.; Koinuma, H. Appl. Phys. Lett. 2002, 81, 3798. doi: 10.1063/1.1521577
34. [34]
  (34) Yousefi, R.; Kamaluddin, B. Solid State Sci. 2010, 12, 252. doi: 10.1016/j.solidstatesciences.2009.11.002
1. [1]
  Xiaxue Chen , Yuxuan Yang , Ruolin Yang , Yizhu Wang , Hongyun Liu . Adjustable Polychromatic Fluorescence: Investigating the Photoluminescent Properties of Copper Nanoclusters. University Chemistry, doi: 10.3866/PKU.DXHX202308019
2. [2]
  Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm³⁺-doped Ba_0.85Ca_0.15Ti_0.90Zr_0.10O₃ lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230388
3. [3]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, doi: 10.3866/PKU.DXHX202310107
4. [4]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, doi: 10.3866/PKU.DXHX202312019
5. [5]
  Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, doi: 10.3866/PKU.DXHX202403028
6. [6]
  Jianjun Liu , Xue Yang , Chi Zhang , Xueyu Zhao , Zhiwei Zhang , Yongmei Chen , Qinghong Xu , Shao Jin . Preparation and Fluorescence Characterization of CdTe Semiconductor Quantum Dots. University Chemistry, doi: 10.3866/PKU.DXHX202311031
7. [7]
  Jie Ren , Hao Zong , Yaqun Han , Tianyi Liu , Shufen Zhang , Qiang Xu , Suli Wu . Visual identification of silver ornament by the structural color based on Mie scattering of ZnO spheres. Chinese Chemical Letters, doi: 10.1016/j.cclet.2023.109350
8. [8]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202406020
9. [9]
  Yanyang Li , Zongpei Zhang , Kai Li , Shuangquan Zang . Ideological and Political Design for the Comprehensive Experiment of the Synthesis and Aggregation-Induced Emission (AIE) Performance Study of Salicylaldehyde Schiff-Base. University Chemistry, doi: 10.3866/PKU.DXHX202307020
10. [10]
  Xiuzheng Deng , Yi Ke , Jiawen Ding , Yingtang Zhou , Hui Huang , Qian Liang , Zhenhui Kang . Construction of ZnO@CDs@Co₃O₄ sandwich heterostructure with multi-interfacial electron-transfer toward enhanced photocatalytic CO₂ reduction. Chinese Chemical Letters, doi: 10.1016/j.cclet.2023.109064
11. [11]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202406027
12. [12]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230441
13. [13]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230404
14. [14]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, doi: 10.3866/PKU.DXHX202310093
15. [15]
  Qin Li , Kexin Yang , Qinglin Yang , Xiangjin Zhu , Xiaole Han , Tao Huang . Illuminating Chlorophyll: Innovative Chemistry Popularization Experiment. University Chemistry, doi: 10.3866/PKU.DXHX202309059
16. [16]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230403
17. [17]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202309043
18. [18]
  Yangrui Xu , Yewei Ren , Xinlin Liu , Hongping Li , Ziyang Lu . 具有高传质和亲和表面的NH₂-UIO-66基疏水多孔液体用于增强CO₂光还原. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202403032
19. [19]
  Yang YANG , Pengcheng LI , Zhan SHU , Nengrong TU , Zonghua WANG . Plasmon-enhanced upconversion luminescence and application of molecular detection. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230440
20. [20]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, doi: 10.3866/PKU.DXHX202312017

Get Citation

PDF

XML

Metrics

PDF Downloads(770)
Abstract views(866)
HTML views(13)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142