Citation: HE Peng, GAO Xiang-Dong, WU Li-Bin, JIANG Zheng-Wu, WANG Cai-Lu, LI Xiao-Min. Porous ZnO Sheets Transformed from Zinc Sulfate Hydroxide Hydrate and Their Photoluminescence Performance[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201302045 shu

Porous ZnO Sheets Transformed from Zinc Sulfate Hydroxide Hydrate and Their Photoluminescence Performance

HE Peng ^1,2 ,
GAO Xiang-Dong ^1, ,
WU Li-Bin ³ ,
JIANG Zheng-Wu ⁴ ,
WANG Cai-Lu ^1,2 ,
LI Xiao-Min ¹

1.
1 State Key Laboratory of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, P. R. China;
2 University of Chinese Academy of Sciences, Beijing 100049, P. R. China;
3 Shanghai Research Institute of Petrochemical Technology, Shanghai 200137, P. R. China;
4 Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, Tongji University, Shanghai 201804, P. R. China

Received Date: 7 November 2012
Available Online: 4 February 2013
Fund Project: 国家重点基础研究发展规划(973) (2009CB623304, 2011CB013805) (973) (2009CB623304, 2011CB013805)国家自然科学基金(51072214, 51002174)资助项目 (51072214, 51002174)

Highly crystalline, porous ZnO sheets were prepared from chemically-deposited zinc sulfate hydroxide hydrate (ZSH) sheets by sintering at 1000 ℃. The formation mechanism of ZSH in Zn²⁺- hexamethyltetramine (HMT) precursor system, the transformation process of ZSH to ZnO, and the crystalline, microstructural and optical properties of the ZnO sheets were investigated. The porous ZnO sheets possessed a well-defined hexa nal shape with controllable size (10-50 μm) and thickness (200-500 nm), high crystallinity, and strong ultraviolet photoluminescence without detectable defectrelated visible emission. Submicron-sized pores (100-500 nm) and poly nal or irregular ZnO particles resulting from the limited mass transport during high temperature sintering were observed in the ZnO sheets. Analysis of the formation mechanism indicated that the high affinity of SO₄^2- for Zn²⁺ was responsible for the formation of ZSH in the Zn²⁺-HMT precursor system, and the thermolysis of ZSH affected the morphology and microstructure of the ZnO sheets. This work reveals a facile route to porous ZnO nanostructures with od crystallinity and optical properties, which make them suitable for application in catalysis, and photo and/or electrical devices.
- ZnO,
- Porous sheet,
- Zinc sulfate hydroxide hydrate,
- Photoluminescence
1. [1]
  
  (1) Wang, Z. L. Mat. Sci. Eng. R 2009, 64, 33. doi: 10.1016/j.mser.2009.02.001
2. [2]
  (2) Yoshida, T.; Terada, K.; Schlettwein, D.; Oekermann, T.;Sugiura, T.; Minoura, H. Adv. Mater. 2000, 12, 1214.
3. [3]
  (3) Li, S.; Li, Z.W.; Tay, Y. Y.; Armellin, J.; Gao,W. Cryst. GrowthDes. 2008, 8, 1623. doi: 10.1021/cg701056q
4. [4]
  (4) Liu, Z.;Wen, X. D.;Wu, X. L.; Gao, Y. J.; Chen, H. T.; Zhu, J.;Chu, P. K. J. Am. Chem. Soc. 2009, 131, 9405. doi: 10.1021/ja9039136
5. [5]
  (5) Shen, J. B.; Zhuang, H. Z.;Wang, D. X.; Xue, C. S.; Liu, H.Cryst. Growth Des. 2009, 9, 2187. doi: 10.1021/cg800847d
6. [6]
  (6) Zhang, J.;Wang, S. R.; Xu, M. J.;Wang, Y.; Zhu, B. L.; Zhang,S. M.; Huang,W. P.;Wu, S. H. Cryst. Growth Des. 2009, 9,3532. doi: 10.1021/cg900269a
7. [7]
  (7) Chivukula, V.; Ciplys, D.; Shur, M.; Dutta, P. Appl. Phys. Lett.2010, 96, 233512. doi: 10.1063/1.3447932
8. [8]
  (8) Park, H. Y.; , H. Y.; Kalme, S.; Mane, R. S.; Han, S. H.;Yoon, M. Y. Anal. Chem. 2009, 81, 4280. doi: 10.1021/ac900632n
9. [9]
  (9) Zhang, Q. F.; Chou, T. R.; Russo, B.; Jenekhe, S. A.; Cao, G. Z.Angew. Chem. Int. Edit. 2008, 47, 2402.
10. [10]
  (10) Wang, Q.; Geng, B. Y.;Wang, S. Z. Environ. Sci.Technol. 2009,43, 8968. doi: 10.1021/es902568h
11. [11]
  (11) Yang, M.; Sun, K.; Kotov, N. A. J. Am. Chem. Soc. 2010, 132,1860. doi: 10.1021/ja906868h
12. [12]
  (12) Jung, S.; Cho,W.; Lee, H. J.; Oh, M. Angew. Chem. Int. Edit.2009, 48, 1459. doi: 10.1002/anie.v48:8
13. [13]
  (13) Shan, C. X.; Liu, Z.; Zhang, Z. Z.; Shen, D. Z.; Hark, S. K.J. Phys. Chem. B 2006, 110, 11176. doi: 10.1021/jp0600514
14. [14]
  (14) Wu, J. H.; Varghese, B.; Zhou, X. D.; Teo, S. Y.; Sow, C. H.;Ang, S. G.; Xu, G. Q. Chem. Mater. 2010, 22, 1533. doi: 10.1021/cm902490g
15. [15]
  (15) Qian, H. S.; Yu, S. H.; ng, J. Y.; Luo, L. B.;Wen, L. L. Cryst.Growth Des. 2005, 5, 935. doi: 10.1021/cg049666l
16. [16]
  (16) Kong, Q. S.;Wu, X. L.; Guo, Y. G.;Wang, Y. Q.; Xia, Y. Z.; Yu,J.; Liu, H. H.; Duan, X. F. Acta Phys. -Chim. Sin. 2008, 24,2179. [孔庆山, 吴兴隆, 郭玉国, 王乙潜, 夏延致, 于建,刘海华, 段晓峰. 物理化学学报, 2008, 24, 2179.] doi: 10.3866/PKU.WHXB20081206
17. [17]
  (17) Zhou, X. F.; Hu, Z. L.; Fan, Y. Q.; Chen, S.; Ding,W. P.; Xu, N.P. J. Phys. Chem. C 2008, 112, 11722. doi: 10.1021/jp802619j
18. [18]
  (18) Gao, X. D.; Li, X. M.; Gao,W.; Qiu, J. J.; Gan, X. Y.;Wang, C.L.; Leng, X. Crystengcomm 2011, 13, 4741. doi: 10.1039/c1ce05125c
19. [19]
  (19) Gao, X. D.; Li, X. M.; Yu,W. D.; Peng, F.; Zhang, C. Y.Materials Research Bulletin 2006, 41, 608. doi: 10.1016/j.materresbull.2005.09.001
20. [20]
  (20) Vayssieres, L. Adv. Mater. 2003, 15, 464. doi: 10.1002/adma.200390108
21. [21]
  (21) Tagawa, H.; Saijo, H. Thermochimica Acta 1985, 91, 67. doi: 10.1016/0040-6031(85)85202-3
22. [22]
  (22) Gao, X. D.; Gao,W.; Yan, X. D.; Zhuge, F.W.; Bian, J. M.; Li,X. M. Funct. Mater. Lett. 2009, 2, 27. doi: 10.1142/S1793604709000508
23. [23]
  (23) Qiu, Y. C.; Chen,W.; Yang, S. H. J. Mater. Chem. 2010, 20,1001. doi: 10.1039/b917305f
24. [24]
  (24) Hsueh, T. J.; Hsu, C. L. Sens. Actuator B-Chem. 2008, 131, 572.doi: 10.1016/j.snb.2007.12.045
25. [25]
  (25) Gao, M. D.; Li, M. M.; Yu,W. D. J. Phys. Chem. B 2005, 109,1155. doi: 10.1021/jp046267s
26. [26]
  (26) Wang, D. L.; Ruan, Y. F.; Zhang, L. C.; Yang, H. B. ActaPhys. -Chim. Sin. 2010, 26, 3369. [王丹丽, 阮永丰, 张灵翠,杨红波. 物理化学学报, 2010, 26, 3369.] doi: 10.3866/PKU.WHXB201210082
27. [27]
  (27) Zhao, J. L.; Li, X. M.; Bian, J. M.; Yu,W. D.; Zhang, C. Y. ThinSolid Films 2006, 515, 1763. doi: 10.1016/j.tsf.2006.06.032
28. [28]
  (28) Kim, D.; Shimomura, T.;Wakaiki, S.; Terashita, T.; Nakayama,M. Physica B 2006, 376, 741. doi: 10.1016/j.physb.2005.12.185
29. [29]
  (29) Al-Salman, H. S.; Abdullah, M. J. J. Alloy. Compd. 2013, 547,132. doi: 10.1016/j.jallcom.2012.08.119
30. [30]
  (30) Gu, Y. F.; Li, X. M.; Yu,W. D.; Gao, X. D.; Zhao, J. L.; Yang, C.J. Cryst. Growth 2007, 305, 36. doi: 10.1016/j.jcrysgro.2007.03.050
31. [31]
  (31) Li, C.; Fang, G. J.; Fu, Q.; Su, F. H.; Li, G. H.;Wu, X. G.; Zhao,X. Z. J. Cryst. Growth 2006, 292, 19. doi: 10.1016/j.jcrysgro.2006.03.061
32. [32]
  (32) Zhang, X. H.; Yan, X. Q.; Zhao, J.; Qin, Z.; Zhang, Y. Mater.Lett. 2009, 63, 444. doi: 10.1016/j.matlet.2008.11.006
33. [33]
  (33) Yoo, Y. Z.; Jin, Z.W.; Chikyow, T.; Fukumura, T.; Kawasaki,M.; Koinuma, H. Appl. Phys. Lett. 2002, 81, 3798. doi: 10.1063/1.1521577
34. [34]
  (34) Yousefi, R.; Kamaluddin, B. Solid State Sci. 2010, 12, 252. doi: 10.1016/j.solidstatesciences.2009.11.002
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