Citation: LI Jin-Bing, JIANG Zhi-Quan, HUANG Wei-Xin. Adsorption and Decomposition of NO₂ on Ag/Pt(110) Bimetallic Surface[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201301241 shu

Adsorption and Decomposition of NO₂ on Ag/Pt(110) Bimetallic Surface

1.
1 Yanshan Branch of SINOPEC Beijing Research Institute of Chemical Industry, SINOPEC, Beijing 102500, China;
2 Hefei National Laboratory for Physical Sciences at the Microscale, Chinese Academy of Sciences, Key Laboratory of Materials for Energy Conversion and Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, Anhui, China

Received Date: 28 November 2012
Available Online: 24 January 2013
Fund Project: 国家自然科学基金(11079033)资助项目 (11079033)

The adsorption and decomposition of NO₂ on Ag/Pt(110) bimetallic surfaces have been investigated by Auger electron spectroscopy (AES) and thermal desorption spectroscopy (TDS). At room temperature, NO₂ under es dissociative chemisorption on Ag/Pt(110) bimetallic surfaces, forming chemisorbed NO(ads) and O(ads). Upon heating, NO(ads) under es both desorption from the surface and further decomposition. At 500 K, NO₂ chemisorbs dissociatively on Ag/Pt(110) bimetallic surfaces, forming O(ads). Electron transfer occurs from Pt to Ag, therefore, the presence of Ag on Pt(110) surface weakens the binding energy of O(ads) with the surface and decreases the temperature required for the recombinative desorption of O(ads) from the surface. We observed the formation of a Ag/Pt(110) alloy structure that exhibits catalytic activity towards NO₂ decomposition similar to that of Pt(110)-(1×2) but with a binding energy towards O(ads) much lower than that of Pt(110)-(1×2). Such a Ag/Pt(110) alloy structure may be active in catalyzing the direct decomposition of NO_x at relatively low temperatures.
- Ag/Pt(110) bimetallic surface,
- NO₂,
- Chemisorption,
- Decomposition,
- Promotion effect
1. [1]
  
  (1) Garin, F. Appl. Catal. A 2001, 222 (1-2), 183. doi: 10.1016/S0926-860X(01)00827-4
2. [2]
  (2) Zhdanov, V. P.; Kasemo, B. Surf. Sci. Rep. 1997, 29 (2), 31.doi: 10.1016/S0167-5729(97)00009-5
3. [3]
  (3) Permana, H.; Ng, K. Y. S.; Peden, C. H. F.; Schmieg, S. J.;Lambert, D. K.; Belton, D. N. J. Catal. 1996, 164 (1), 194.doi: 10.1006/jcat.1996.0375
4. [4]
  (4) Nakamura, I.; Fujitani, T.; Hamada, H. Surf. Sci. 2002, 514 (1-3), 409. doi: 10.1016/S0039-6028(02)01660-6
5. [5]
  (5) Brown,W. A.; King, D. A. J. Phys. Chem. B 2000, 104 (12),2578. doi: 10.1021/jp9930907
6. [6]
  (6) Ge, Q.; Neurock, M. J. Am. Chem. Soc. 2004, 126 (5), 1551.doi: 10.1021/ja036575o
7. [7]
  (7) Bartram, M. E.;Windham, R. G.; Koel, B. E. Langmuir 1988, 4 (2), 240. doi: 10.1021/la00080a001
8. [8]
  (8) Bartram, M. E.;Windham, R. G.; Koel, B. E. Surf. Sci. 1987,184 (1-2), 57. doi: 10.1016/S0039-6028(87)80272-8
9. [9]
  (9) Huang,W. X.; White, J. M. Surf. Sci. 2003, 529, 455. doi: 10.1016/S0039-6028(03)00332-7
10. [10]
  (10) Schwalke, U.; Niehus, H.; Comsa, G. Surf. Sci. 1985, 152-153,596.
11. [11]
  (11) Parker, D. H.; Bartram, M. E.; Koel, B. E. Surf. Sci. 1989, 217 (3), 489. doi: 10.1016/0039-6028(89)90443-3
12. [12]
  (12) Devarajan, S. P.; Hinojosa, J. A.;Weaver, J. F. Surf. Sci. 2008,602 (19), 3116. doi: 10.1016/j.susc.2008.08.008
13. [13]
  (13) Huang,W. X.; Jiang, Z. Q.; Jiao, J.; Tan, D. L.; Zhai, R. S.; Bao,X. H. Surf. Sci. 2002, 506 (3), L287.
14. [14]
  (14) Jiang, Z. Q.; Huang,W. X.; Tan, D. L.; Zhai, R. S.; Bao, X. H.Surf. Sci. 2006, 600 (21), 4860. doi: 10.1016/j.susc.2006.08.007
15. [15]
  (15) Li, J. B.; Huang,W. X.; Jiang, Z. Q.; Bao, X. H. Chin. J. Catal.2006, 27 (1), 65. [李金兵, 黄伟新, 姜志全, 包信和. 催化学报, 2006, 27 (1), 65.]
16. [16]
  (16) Sasaki, M.; Hamada, H.; Kintaichi, Y.; Ito, T. Catal. Lett. 1992,15 (3), 297. doi: 10.1007/BF00765274
17. [17]
  (17) Iwamoto, M.; Zengyo, T.; Hernandez, A. M.; Araki, H. Appl.Catal. B 1998, 17 (3), 259. doi: 10.1016/S0926-3373(98)00018-6
18. [18]
  (18) Iwamoto, M.; Yahiro, H. Catal. Today 1994, 22 (1), 5.doi: 10.1016/0920-5861(94)80089-8
19. [19]
  (19) Amirnazmi, A.; Benson, J. E.; Boudart, M. J. Catal. 1973, 30 (1), 55. doi: 10.1016/0021-9517(73)90051-1
20. [20]
  (20) Iwamoto, M.; Yahiro, H.; Shundo, S.; Yoshihiro, Y.; Mizuno, N.Appl. Catal. 1991, 69 (2), L15.
21. [21]
  (21) Hamada, H.; Kintaichi, Y.; Sasaki, M.; Ito, T. Chem. Lett. 1990,19 (7), 1069.
22. [22]
  (22) Wu, R. J.; Chou, T. Y.; Yeh, C. T. Appl. Catal. B 1995, 6 (2),105. doi: 10.1016/0926-3373(95)00005-4
23. [23]
  (23) Huang,W. X.; Jiang, Z. Q.; Tan, D. L.; Zhai, R. S.; Bao, X. H.Surf. Sci. 2001, 478 (1-2), L345.
24. [24]
  (24) Huang,W. X.; Jiang, Z. Q.; Dong, F.; Bao, X. H. Surf. Sci. 2002,514 (1-3), 420. doi: 10.1016/S0039-6028(02)01662-X
25. [25]
  (25) Li, J. B.; Jiang, Z. Q.; Huang,W. X. Chin. J. Chem. Phys. 2011,24 (6), 735. doi: 10.1088/1674-0068/24/06/735-740
26. [26]
  (26) rte, R. J.; Gland, J. L. Surf. Sci. 1981, 102 (2-3), 348.doi: 10.1016/0039-6028(81)90034-0
27. [27]
  (27) Wilf, M.; Dawson, P. T. Surf. Sci. 1977, 65 (2), 399.doi: 10.1016/0039-6028(77)90456-3
28. [28]
  (28) Imbihl, R.; Sander, M.; Ertl, G. Surf. Sci. 1988, 204 (1-2), L701.
29. [29]
  (29) Rodriguez, J. A.; Kuhn, M. J. Phys. Chem. 1994, 98 (44),11251. doi: 10.1021/j100095a004
30. [30]
  (30) Härtel, T.; Strüber, U.; Küppers, J. Thin Solid Films 1993, 229 (2), 163. doi: 10.1016/0040-6090(93)90359-W
1. [1]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, doi: 10.3866/PKU.DXHX202311102
2. [2]
  Tao Wang , Qin Dong , Cunpu Li , Zidong Wei . Sulfur Cathode Electrocatalysis in Lithium-Sulfur Batteries: A Comprehensive Understanding. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202303061
3. [3]
  Ruizhi Duan , Xiaomei Wang , Panwang Zhou , Yang Liu , Can Li . The role of hydroxyl species in the alkaline hydrogen evolution reaction over transition metal surfaces. Acta Physico-Chimica Sinica, doi: 10.1016/j.actphy.2025.100111
4. [4]
  Shijie Ren , Mingze Gao , Rui-Ting Gao , Lei Wang . Bimetallic Oxyhydroxide Cocatalyst Derived from CoFe MOF for Stable Solar Water Splitting. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202307040
5. [5]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240201
6. [6]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, doi: 10.3866/PKU.DXHX202309005
7. [7]
  Xiaofei Liu , He Wang , Li Tao , Weimin Ren , Xiaobing Lu , Wenzhen Zhang . Electrocarboxylation of Benzylic Phosphates and Phosphinates with Carbon Dioxide. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202307008
8. [8]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240014
9. [9]
  Bizhu Shao , Huijun Dong , Yunnan Gong , Jianhua Mei , Fengshi Cai , Jinbiao Liu , Dichang Zhong , Tongbu Lu . Metal-Organic Framework-Derived Nickel Nanoparticles for Efficient CO₂ Electroreduction in Wide Potential Windows. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202305026
10. [10]
  Yan Kong , Wei Wei , Lekai Xu , Chen Chen . Electrochemical Synthesis of Organonitrogen Compounds from N-integrated CO₂ Reduction Reaction. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202307049
11. [11]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240067
12. [12]
  Hui-Ying Chen , Hao-Lin Zhu , Pei-Qin Liao , Xiao-Ming Chen . Integration of Ru(Ⅱ)-Bipyridyl and Zinc(Ⅱ)-Porphyrin Moieties in a Metal-Organic Framework for Efficient Overall CO₂ Photoreduction. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202306046
13. [13]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230346
14. [14]
  Yu Dai , Xueting Sun , Haoyu Wu , Naizhu Li , Guoe Cheng , Xiaojin Zhang , Fan Xia . Determination of the Michaelis Constant for Gold Nanozyme-Catalyzed Decomposition of Hydrogen Peroxide. University Chemistry, doi: 10.12461/PKU.DXHX202407052
15. [15]
  Huasen Lu , Shixu Song , Qisen Jia , Guangbo Liu , Luhua Jiang . Advances in Cu₂O-based Photocathodes for Photoelectrochemical Water Splitting. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202304035
16. [16]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240149
17. [17]
  Qiang Zhang , Yuanbiao Huang , Rong Cao . Imidazolium-Based Materials for CO₂ Electroreduction. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202306040
18. [18]
  Yanhui Guo , Li Wei , Zhonglin Wen , Chaorong Qi , Huanfeng Jiang . Recent Progress on Conversion of Carbon Dioxide into Carbamates. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202307004
19. [19]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202406029
20. [20]
  Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240398

Get Citation

PDF

XML

Metrics

PDF Downloads(667)
Abstract views(1045)
HTML views(30)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Adsorption and Decomposition of NO2 on Ag/Pt(110) Bimetallic Surface

Metrics

通讯作者: 陈斌, bchen63@163.com

Adsorption and Decomposition of NO₂ on Ag/Pt(110) Bimetallic Surface