Citation: XU Jing, ZHU Yong-Fa. Elimination of Bisphenol A from Water via Graphene Oxide Adsorption[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201301211 shu

Elimination of Bisphenol A from Water via Graphene Oxide Adsorption

XU Jing ¹ ,
ZHU Yong-Fa ^1,2,

1.
1 Department of Chemistry, Tsinghua University, Beijing 100084, P.R. China;
2 Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Nanjing University of Information Science and Technology, Nanjing 210044, P.R. China

Received Date: 31 October 2012
Available Online: 21 January 2013
Fund Project: 国家重点基础研究发展计划(973) (2013CB632403) (973) (2013CB632403) 国家高技术研究发展计划(863) (2012AA062701) (863) (2012AA062701) 科技部创新方法工作专项(2009IM030500) (2009IM030500)江苏省大气环境监测与污染控制高技术研究重点实验室开放基金(AEMPC201103)资助项目 (AEMPC201103)

The elimination of bisphenol A (BPA) from aqueous solution by adsorption on graphene oxide ( ) was investigated. The maximum adsorption capacity (q_m) of for BPA estimated from the Langmuir isotherm was 87.80 mg·g^-1 at 25℃. The required contact time to reach adsorption equilibrium was about 30 min, which was much shorter than that of activated carbon. The adsorption kinetics and isotherm data fitted well with the pseudo-second-order kinetic model and the Langmuir isotherm, respectively. Neutral pH and low solution temperature were favorable for adsorption, whereas the presence of NaCl in the solution was unfavorable. The had od recyclability and could be reused several times with a slight decline in adsorption ability. Both hydrogen bonding and π-π interaction were thought to be responsible for the adsorption of BPA on . The excellent adsorption capacity and high adsorption rate of result from its sheet-like structure and the abundant oxygen-containing groups on its surface. Although q_m of for BPA is lower than that of graphene, has the benefits of large scale production, a hydrophilic surface with plenty of oxygen-containing groups, and od dispersion in water. Therefore, can be regarded as a od potential adsorbent for water treatment.
- Adsorption,
- Graphene oxide,
- Bisphenol A,
- Endocrine-disrupting chemicals,
- Water treatment
1. [1]
  
  (1) Snyder, S. A.;Westerhoff, P.; Yoon, Y.; Sedlak, D. L. Environ.Sci. Technol. 2003, 20, 449.
2. [2]
  (2) Chang, H. S.; Choo, K. H.; Lee, B.; Choi, S. J. J. Hazard.Mater. 2009, 172, 1. doi: 10.1016/j.jhazmat.2009.06.135
3. [3]
  (3) Kang, J. H.; Kondo, F.; Katayama, Y. Toxicology 2006, 226, 79.doi: 10.1016/j.tox.2006.06.009
4. [4]
  (4) Staples, C. A.; Dorn, P. B.; Klecka, G. M.; O'Block, S. T.;Harris, L. R. Chemosphere 1998, 36, 2149. doi: 10.1016/S0045-6535(97)10133-3
5. [5]
  (5) Staples, C. A.; Dorn, P. B.; Klecka, G. M.; O'Block, S. T.;Branson, D. R.; Harris, L. R. Chemosphere 2000, 40, 521. doi: 10.1016/S0045-6535(99)00288-X
6. [6]
  (6) Belfroid, A.; van Velzen, M.; van der Horst, B.; Vethaak, D.Chemosphere 2002, 49, 97. doi: 10.1016/S0045-6535(02)00157-1
7. [7]
  (7) Pan, B.; Lin, D. H.; Mashayekhi, H.; Xing, B. S. Environ. Sci.Technol. 2009, 43, 5480.
8. [8]
  (8) Liu, G. F.; Ma, J.; Li, X. C.; Qin, Q. D. J. Hazard. Mater. 2009,164, 1275. doi: 10.1016/j.jhazmat.2008.09.038
9. [9]
  (9) Dong, Y.;Wu, D. Y.; Chen, X. C.; Lin, Y. J. Colloid InterfaceSci. 2010, 348, 585. doi: 10.1016/j.jcis.2010.04.074
10. [10]
  (10) Kim, Y. H.; Lee, B.; Choo, K. H.; Choi, S. J. MicroporousMesoporous Mat. 2011, 138, 184. doi: 10.1016/j.micromeso.2010.09.007
11. [11]
  (11) El-Naas, M. H.; Al-Muhtaseb, S. A.; Makhlouf, S. J. Hazard.Mater. 2009, 164, 720. doi: 10.1016/j.jhazmat.2008.08.059
12. [12]
  (12) Wang, R.; Ren, D.; Xia, S.; Zhang, Y.; Zhao, J. J. Hazard.Mater. 2009, 169, 926. doi: 10.1016/j.jhazmat.2009.04.036
13. [13]
  (13) Bautista-Toledo, I.; Ferro-Garcia, M. A.; Rivera-Utrilla, J.;Moreno-Castilla, C.; Vegas Fernandez, F. J. Environ. Sci.Technol. 2005, 39, 6246. doi: 10.1021/es0481169
14. [14]
  (14) Pan, B.; Xing, B. S. J. Agric. Food Chem. 2010, 58, 8338. doi: 10.1021/jf101346e
15. [15]
  (15) Kuo, C. Y. Desalination 2009, 249, 976. doi: 10.1016/j.desal.2009.06.058
16. [16]
  (16) Xu, J.;Wang, L.; Zhu, Y. F. Langmuir 2012, 28, 8418. doi: 10.1021/la301476p
17. [17]
  (17) Yuan,W. H.; Li, B. Q.; Li, L. Acta Phys. -Chim. Sin. 2011, 27,2244. [袁文辉, 李保庆, 李莉. 物理化学学报, 2011, 27,2244.] doi: 10.3866/PKU.WHXB20110838
18. [18]
  (18) Nakanishi, A.; Tamai, M.; Kawasaki, N.; Nakamura, T.; Tanada,S. J. Colloid Interface Sci. 2002, 252, 393. doi: 10.1006/jcis.2002.8387
19. [19]
  (19) Asada, T.; Oikawa, K.; Kawata, K.; Ishihara, S.; Iyobe, T.;Yamada, A. J. Health Sci. 2004, 50, 588. doi: 10.1248/jhs.50.588
20. [20]
  (20) Furhacker, M.; Scharf, S.;Weber, H. Chemosphere 2000, 41,751. doi: 10.1016/S0045-6535(99)00466-X
21. [21]
  (21) Dikin, D. A.; Stankovich, S.; Zimney, E. J.; Piner, R. D.;Dommett, G. H. B.; Evmenenko, G.; Nguyen, S. T.; Ruoff, R. S.Nature 2007, 448, 457. doi: 10.1038/nature06016
22. [22]
  (22) Dreyer, D. R.; Park, S.; Bielawski, C.W.; Ruoff, R. S. Chem.Soc. Rev. 2010, 39, 228. doi: 10.1039/b917103g
23. [23]
  (23) Yang, S. T.; Chang, Y. L.;Wang, H. F.; Liu, G. B.; Chen, S.;Wang, Y.W.; Liu, Y. F.; Cao, A. N. J. Colloid Interface Sci.2010, 351, 122. doi: 10.1016/j.jcis.2010.07.042
24. [24]
  (24) Zhang, K.; Dwivedi, V.; Chi, C. Y.;Wu, J. S. J. Hazard. Mater.2010, 182, 162. doi: 10.1016/j.jhazmat.2010.06.010
25. [25]
  (25) Nana, Z.; Haixia, Q.; Youmiao, S.;Wei,W.; Jianping, G.Carbon 2011, 49, 827. doi: 10.1016/j.carbon.2010.10.024
26. [26]
  (26) Fan, L.; Luo, C.; Li, X.; Lu, F.; Qiu, H.; Sun, M. J. Hazard.Mater. 2012, 215-216, 272.
27. [27]
  (27) Zhang,W.; Zhou, C.; Zhou,W.; Lei, A.; Zhang, Q.;Wan, Q.;Zou, B. Bull. Environ. Contam. Toxicol. 2011, 87, 86. doi: 10.1007/s00128-011-0304-1
28. [28]
  (28) Gao, Y.; Li, Y.; Zhang, L.; Huang, H.; Hu, J.; Shah, S. M.; Su,X. J. Colloid Interface Sci. 2012, 368, 540. doi: 10.1016/j.jcis.2011.11.015
29. [29]
  (29) Hummers,W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80,1339. doi: 10.1021/ja01539a017
30. [30]
  (30) Hu, Y. J.; Jin, J.; Zhang, H.;Wu, P.; Cai, C. X. ActaPhys. -Chim. Sin. 2010, 26, 2073. [胡耀娟, 金娟, 张卉,吴萍, 蔡称心. 物理化学学报, 2010, 26, 2073.] doi: 10.3866/PKU.WHXB20100812
31. [31]
  (31) Sing, K. S.W.; Everett, D. H.; Haul, R. A.W.; Moscou, L.;Pierotti, R. A.; Rouquerol, J.; Siemieniewska, T. Pure Appl.Chem. 1985, 57, 603. doi: 10.1351/pac198557040603
32. [32]
  (32) Everett, D. H. Basic Principles of Colloid Science; The RoyalSociety of Chemistry: London, 1988.
33. [33]
  (33) Fan, X. B.; Peng,W. C.; Li, Y.; Li, X. Y.;Wang, S. L.; Zhang, G.L.; Zhang, F. B. Adv. Mater. 2008, 20, 4490. doi: 10.1002/adma.v20:23
34. [34]
  (34) Ho, Y. S.; McKay, G. Water Res. 2000, 34, 735. doi: 10.1016/S0043-1354(99)00232-8
35. [35]
  (35) Blanchard, G.; Maunaye, M.; Martin, G. Water Res. 1984, 18,1501. doi: 10.1016/0043-1354(84)90124-6
36. [36]
  (36) Zhao, G. X.; Li, J. X.;Wang, X. K. Chem. Eng. J. 2011, 173,185. doi: 10.1016/j.cej.2011.07.072
37. [37]
  (37) Langmuir, I. J. Am. Chem. Soc. 1916, 38, 2221. doi: 10.1021/ja02268a002
38. [38]
  (38) Freundlich, H. J. Phys. Electrochem. 1906, 57, 385.
39. [39]
  (39) Hameed, B. H. J. Hazard. Mater. 2008, 154, 204. doi: 10.1016/j.jhazmat.2007.10.010
40. [40]
  (40) Radovic, L. R.; Moreno-Castilla, C.; Rivera-Utrilla, J. CarbonMaterials as Adsorbents in Aqueous Solutions. In Chemistryand Physics of Carbon; Radovic, L. R. Ed.; Marcel Dekker:New York, 2001; Vol. 27, pp 227-405.
41. [41]
  (41) Ersoz, A.; Denizli, A.; Sener, I.; Atilir, A.; Diltemiz, S.; Say, R.Sep. Purif. Technol. 2004, 38, 173. doi: 10.1016/j.seppur.2003.11.004
42. [42]
  (42) Chandra, V.; Park, J.; Chun, Y.; Lee, J.W.; Hwang, I. C.; Kim,K. S. ACS Nano 2010, 4, 3979. doi: 10.1021/nn1008897
43. [43]
  (43) Coughlin, R.W.; Ezra, F. S. Environ. Sci. Technol. 1968, 2, 291.doi: 10.1021/es60016a002
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