Citation: WANG Hai, XU Xue-Qing, SHI Ji-Fu, XU Gang. Application of Ionic Liquids with Carboxyl and Aromatic Ring Conjugated Anions in Dye-Sensitized Solar Cells[J]. Acta Physico-Chimica Sinica, ;2013, 29(03): 525-532. doi: 10.3866/PKU.WHXB201301091 shu

Application of Ionic Liquids with Carboxyl and Aromatic Ring Conjugated Anions in Dye-Sensitized Solar Cells

WANG Hai ^1,2,3 ,
XU Xue-Qing ^1,2 ,
SHI Ji-Fu ^1,2 ,
XU Gang ^1,2

1.
1 Guangzhou Institute of Energy Conversion 510640, P. R. China;
2 Key Laboratory of Renewable Energy and Gas Hydrate, Chinese Academy of Science, Guangzhou 510640, P. R. China;
3 University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received Date: 25 October 2012
Available Online: 9 January 2013
Fund Project: 国家自然科学基金(21103194, 21273241) (21103194, 21273241) 广州市珠江科技新星专项(2012061) (2012061)中国科学院广州能源研究所所长创新基金(y007r71001)资助项目 (y007r71001)

A method of utilizing p-π conjugation effects for obtaining low-viscosity ionic liquids is presented. p-π conjugation effectively disperses anionic charge and reduces Coulombic interactions. Ionic liquids prepared in this study were 1-ethyl-3-methylimidazolium benzoate (EMIB) and 1-ethyl-3- methylimidazolium isonicotinate (EMIIN). They have carboxyl and aromatic ring p-π conjugated anions, and achieve low viscosities of 42 and 27 mPa·s, respectively. EMIB and EMIIN were employed as electrolytes, which were used to construct dye-sensitized solar cells (DSCs). After optimizing the composition, the ionic conductivity and triiodide ionic diffusion constant for the EMIB-based electrolyte were 1.43 mS·cm-1 and 1.45 × 10^-7 cm²·s^-1, respectively. For the EMIIN-based electrolyte, the ionic conductivity and triiodide ionic diffusion constant were 1.63 mS·cm^-1 and 2.01×10^-7 cm²·s^-1, respectively. These were higher than the corresponding values for the EMIB-based electrolyte because of EMIIN's lower viscosity. DSCs based on these two electrolytes attained satisfactory energy conversion efficiencies of 2.85% and 4.30% for EMIB and EMIIN, respectively, under an illumination intensity of 300 W·m^-2.
- Ionic liquid,
- Viscosity,
- Electrolyte,
- Conductivity,
- Dye-sensitized solar cell
1. [1]
  
  (1) O'Regan, B.; Grätzel, M. Nature 1991, 353, 737. doi: 10.1038/353737a0
2. [2]
  (2) Kong, F. T.; Dai, S. Y. Progress in Chemistry 2006, 18, 1409.[孔凡太, 戴松元. 化学进展, 2006, 18, 1409.]
3. [3]
  (3) Shi, J.; Peng, S.; Pei, J.; Liang, Y.; Cheng, F.; Chen, J. ACSAppl. Mater. Interfaces 2009, 1, 944. doi: 10.1021/am9000375
4. [4]
  (4) Wang, M.; Pan, X.; Fang, X.; Guo, L.; Liu,W.; Zhang, C.;Huang, Y.; Hu, L.; Dai, S. Adv. Mater. 2010, 22, 5526. doi: 10.1002/adma.v22.48
5. [5]
  (5) Yu, Q.;Wang, Y.; Yi, Z.; Zu, N.; Zhang, J.; Zhang, M.;Wang, P.ACS Nano 2010, 4, 6032. doi: 10.1021/nn101384e
6. [6]
  (6) Grätzel, M. J. Photochem. Photobiol. A 2004, 164, 3. doi: 10.1016/j.jphotochem.2004.02.023
7. [7]
  (7) Pan, X.; Dai, S. Y.;Wang, K. J.; Shi, C.W.; Guo, L. ActaPhys. -Chim. Sin. 2005, 21, 697. [潘旭, 戴松元, 王孔嘉,史成武, 郭力. 物理化学学报, 2005, 21, 697.] doi: 10.3866/PKU.WHXB20050624
8. [8]
  (8) Bai, Y.; Cao, Y.; Zhang, J.;Wang, M.; Li, R.;Wang, P.;Zakeeruddin, S. M.; Grätzel, M. Nat. Mater. 2008, 7, 626. doi: 10.1038/nmat2224
9. [9]
  (9) Papageorgiou, N.; Athanassov, Y.; Armand, M.; Bonhote, P.;Pettersson, H.; Azam, A.; Grätzel, M. J. Electrochem. Soc.1996, 143, 3099. doi: 10.1149/1.1837171
10. [10]
  (10) Shi, C.W.; Ge, Q.; Qiu, Z. G.; Li, B.; Han, S. K. ActaPhys. -Chim. Sin. 2007, 23, 1473. [史成武, 葛茜, 邱治国,李兵, 韩士奎. 物理化学学报, 2007, 23, 1473.] doi: 10.3866/PKU.WHXB20070932
11. [11]
  (11) Wang, P.; Zakeeruddin, S. M.; Comte, P.; Exnar, I.; Grätzel, M.J. Am. Chem. Soc. 2003, 125, 1166. doi: 10.1021/ja029294+
12. [12]
  (12) Zakeeruddin, S. M.; Moser, J. E.; Grätzel, M. J. Phys. Chem. B2003, 107, 13280. doi: 10.1021/jp0355399
13. [13]
  (13) Kuang, D.;Wang, P.; Ito, S.; Zakeeruddin, S. M.; Grätzel, M.J. Am. Chem. Soc. 2006, 128, 7732. doi: 10.1021/ja061714y
14. [14]
  (14) Wachter, P.; Schreiner, C.; Zistler, M.; Gerhard, D.;Wasserscheid, P.; res, H. J. Microchim. Acta 2008, 160, 125.doi: 10.1007/s00604-007-0803-2
15. [15]
  (15) Fredin, K.; rlov, M.; Pettersson, H.; Hagfeldt, A.; Kloo, L.;Boschloo, G. J. Phys. Chem. C 2007, 111, 13261. doi: 10.1021/jp072514r
16. [16]
  (16) Zhou, Z. B.; Matsumoto, H.; Tatsumi, K. Chem. Eur. J. 2004,10, 6581.
17. [17]
  (17) Fukumoto, K.; Yoshizawa, M.; Ohno, H. J. Am. Chem. Soc.2005, 127, 2398. doi: 10.1021/ja043451i
18. [18]
  (18) Shi, J. F.;Wang, L.; Liang, Y. L.; Peng, S. J.; Cheng, F. Y.;Chen, J. J. Phys. Chem. C 2010, 114, 6814. doi: 10.1021/jp100029r
19. [19]
  (19) Shi, J. F.;Wan, Q. C.; Xu, G.; Xu, X. Q.; Fan, Y. ActaPhys. -Chim. Sin. 2011, 27, 2360. [史继富, 万青翠, 徐刚,徐雪青, 樊晔. 物理化学学报, 2011, 27, 2360.] doi: 10.3866/PKU.WHXB20111023
20. [20]
  (20) Bonhote, P.; Dias, A. P.; Armand, M.; Papageorgiou, N.;Kalyanasundaram, K.; Grätzel, M. Inorg. Chem. 1996, 35,1168. doi: 10.1021/ic951325x
21. [21]
  (21) Kawano, R.;Watanabe, M. Chem. Commun. 2003, 330.
22. [22]
  (22) Wu, J.; Hao, S.; Lan, Z.; Lin, J.; Huang, M.; Huang, Y.; Li, P.;Yin, S.; Sato, T. J. Am. Chem. Soc. 2008, 130, 11568. doi: 10.1021/ja802158q
23. [23]
  (23) Jerman, I.; Jovanovski, V.; Vuk, A. Š.; Hocevar, S. B.; Gaberšcek,M.; Jesih, A.; Orel, B. Electrochim. Acta 2008, 53, 2281. doi: 10.1016/j.electacta.2007.09.043
24. [24]
  (24) Wang, P.; Zakeeruddin, S. M.; Humphry-Baker, R.; Grätzel, M.Chem. Mater. 2004, 16, 2694. doi: 10.1021/cm049916l
25. [25]
  (25) Shi, J. F.; Fan, Y.; Xu, X. Q.; Xu, G.; Chen, L. H. ActaPhys. -Chim. Sin. 2012, 28, 857. [史继富, 樊晔, 徐雪青,徐刚, 陈丽华. 物理化学学报, 2012, 28, 857.] doi: 10.3866/PKU.WHXB201202204
26. [26]
  (26) Fabregat-Santia , F.; Bisquert, J.; Palomares, E.; Otero, L.;Kuang, D.; Zakeeruddin, S. M.; Grätzel, M. J. Phys. Chem. C2007, 111, 6550. doi: 10.1021/jp066178a
27. [27]
  (27) Hara, K.; Dan-oh, Y.; Kasada, C.; Ohga, Y.; Shinpo, A.; Suga,S.; Sayama, K.; Arakawa, H. Langmuir 2004, 20, 4205. doi: 10.1021/la0357615
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