Citation: XU Gui-Yin, DING Bing, NIE Ping, LUO Hong-Jun, ZHANG Xiao-Gang. Preparation and Electrochemical Performance of Carbon Nanotubes/ Graphene Oxide/Sulfur Complex Cathode Material[J]. Acta Physico-Chimica Sinica, ;2013, 29(03): 546-552. doi: 10.3866/PKU.WHXB201301081 shu

Preparation and Electrochemical Performance of Carbon Nanotubes/ Graphene Oxide/Sulfur Complex Cathode Material

1.
College of Material Science & Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, P.R. China

Received Date: 8 October 2012
Available Online: 8 January 2013
Fund Project: 国家自然科学基金(21173120) (21173120) 江苏省自然科学基金重点专项(BK2011030) (BK2011030)南京航空航天大学研究生创新基地(实验室)开放基金(kfjj120209)资助 (实验室)开放基金(kfjj120209)

Three-dimensional (3D) hierarchical CNTs/ /S ternary composites were prepared by solution-based reaction-deposition, using graphene oxide ( ) and carbon nanotubes (CNTs) as precursors. Scanning electron microscopy (SEM) and transmission electron microscope (TEM) indicated a uniform S coating on CNTs/ which arose because of the large specific surface area. CNTs interspersed between the layers to form a 3D porous structure. Constant current charge-discharge tests showed that CNTs/ /S composites had a high discharge capacity and excellent cycling stability, and delivered a high initial discharge capacity of 904 mAh·g^-1 at 1C rate. After 50 cycles at the same rate, the reversible capacity remained at 578 mAh·g^-1.
- Lithium-sulfur battery,
- Graphene oxide,
- Carbon nanotube,
- Composite,
- Cycling performance
1. [1]
  
  (1) Bruce, P. G.; Freunberger, S. A.; Hardwick, L. J.; Tarascon, J.M. Nat. Mater. 2012, 11 (1), 19. doi: 10.1038/nmat3191
2. [2]
  (2) Yao, Z. D.;Wei,W.;Wang, J. L.; Yang, J.; Nuli, Y. N. ActaPhys. -Chim. Sin. 2011, 27 (5), 1005. [姚真东, 魏巍, 王久林, 杨军, 努丽燕娜. 物理化学学报, 2011, 27 (5), 1005.]doi: 10.3866/PKU.WHXB20110345
3. [3]
  (3) Xiao, L. F.; Cao, Y. L.; Xiao, J.; Schwenzer, B.; Engelhard, M.H.; Saraf, L. V.; Nie, Z. M.; Exarhos, G. J.; Liu, J. Adv. Mater.2012, 24 (9), 1176. doi: 10.1002/adma.201103392
4. [4]
  (4) Ai, X. P.; Cao, Y. L.; Yang, H. X. J. Electrochemistry 2012, 18 (3), 224. [艾新平, 曹余良, 杨汉西. 电化学, 2012, 18 (3),224.]
5. [5]
  (5) Ji, X. L.; Nazar, L. F. J. Mater. Chem. 2010, 20 (44), 9821. doi: 10.1039/b925751a
6. [6]
  (6) Aurbach, D.; Pollak, E.; Elazari, R.; Salitra, G.; Kelley, C. S.;Affinito, J. J. Electrochem. Soc. 2009, 156, A694. doi: 10.1149/1.3148721
7. [7]
  (7) Mikhaylik, Y. V.; Akridge, J. R. J. Electrochem. Soc. 2004, 151 (11), A1969. doi: 10.1149/1.1806394
8. [8]
  (8) Choi, N. S.; Chen, Z. H.; Freunberger, S. A.; Ji, X. L.; Sun, Y.K.; Amine, K.; Yushin, G.; Nazar, L. F.; Cho, J.; Bruce, P. G.Angew. Chem. Int. Edit. 2012, 51 (40), 9994. doi: 10.1002/anie.201201429
9. [9]
  (9) Wang,W. K.;Wang, A. B.; Cao, G. P.; Yang, Y. S. ActaPhys. -Chim. Sin. 2004, 20 (12), 1440. [王维坤, 王安邦, 曹高萍, 杨裕生. 物理化学学报, 2004, 20 (12), 1440.] doi: 10.3866/PKU.WHXB20041208
10. [10]
  (10) Wang, C.; Chen, J. J.; Shi, Y. N.; Zheng, M. S.; Dong, Q. F.Electrochim. Acta 2010, 55 (23), 7010. doi: 10.1016/j.electacta.2010.06.019
11. [11]
  (11) Elazari, R.; Salitra, G.; Garsuch, A.; Panchenko, A.; Aurbach, D.Adv. Mater. 2011, 23 (47), 5641. doi: 10.1002/adma.v23.47
12. [12]
  (12) Yin, L. C.;Wang, J. L.; Lin, F. J.; Yang, J.; Nuli, Y. N. EnergyEnviron. Sci. 2012, 5 (5), 6966. doi: 10.1039/c2ee03495f
13. [13]
  (13) Rao, M. M.; Li,W. S.; Cairns, E. J. Electrochem. Commun.2012, 17, 1. doi: 10.1016/j.elecom.2011.12.022
14. [14]
  (14) Ji, X. L.; Lee, K. T.; Nazar, L. F. Nat. Mater. 2009, 8 (6), 500.doi: 10.1038/nmat2460
15. [15]
  (15) Wang, J. L.; Yang, J.; Xie, J. Y.; Xu, N. X.; Li, Y. Electrochem.Commun. 2002, 4 (6), 499.
16. [16]
  (16) Ji, L.W.; Rao, M. M.; Aloni, S.;Wang, L.; Cairns, E. J.; Zhang,Y. G. Energy Environ. Sci. 2011, 4 (12), 5053. doi: 10.1039/clee02256c
17. [17]
  (17) Wang, D.W.; Zhou, G. M.; Li, F.;Wu, K. H.; Lu, G. Q.; Cheng,H. M.; Gentle, I. R. Phys. Chem. Chem. Phys. 2012, 14 (24),8703. doi: 10.1039/c2cp40808b
18. [18]
  (18) Ji, L.W.; Rao, M. M.; Zheng, H. M.; Zhang, L.; Li, Y. C.; Duan,W. H.; Guo, J. H.; Cairns, E. J.; Zhang, Y. G. J. Am. Chem. Soc.2011, 133 (46), 18522. doi: 10.1021/ja206955k
19. [19]
  (19) Buglione, L.; Pumera, M. Electrochem. Commun. 2012, 17, 45.doi: 10.1016/j.elecom.2012.01.018
20. [20]
  (20) Huang, Z. D.; Zhang, B.; Oh, S.W.; Zheng, Q. B.; Lin, X. Y.;Yousefi, N.; Kim, J. K. J. Mater. Chem. 2012, 22 (8), 3591.doi: 10.1039/c2jm15048d
21. [21]
  (21) Hummers,W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80,1339. doi: 10.1021/ja01539a017
22. [22]
  (22) Che, Q.; Zhang, F.; Zhang, X. G.; Lu, X. J.; Ding, B.; Zhu, J. J.Acta Phys. -Chim. Sin. 2012, 28 (4), 837. [车倩, 张方,张校刚, 卢向军, 丁兵, 朱佳佳. 物理化学学报, 2012, 28 (4),837.]doi: 10.3866/PKU.WHXB201202074
23. [23]
  (23) Zhang, L.; Ji, L.W.; Glans, P. A.; Zhang, Y. G.; Zhu, J. F.; Guo,J. H. Phys. Chem. Chem. Phys. 2012, 14 (39), 13670. doi: 10.1039/c2cp42866k
24. [24]
  (24) Cheon, S. E.; Choi, S. S.; Han, J. S.; Choi, Y. S.; Jung, B. H.;Lim, H. S. J. Electrochem. Soc. 2004, 151, A2067. doi: 10.1149/1.1815153
25. [25]
  (25) Chen, J. J.; Zhang, Q.; Shi, Y. N.; Qin, L. L.; Cao, Y.; Zheng, M.S.; Dong, Q. F. Phys. Chem. Chem. Phys. 2012, 14 (16), 5376.doi: 10.1039/c2cp40141j
26. [26]
  (26) Wang, Y. X.; Huang, L.; Sun, L. C.; Xie, S. Y.; Xu, G. L.; Chen,S. R.; Xu, Y. F.; Li, J. T.; Chou, S. L.; Dou, S. X.; Sun, S. G. J.Mater. Chem. 2012, 22 (11), 4744. doi: 10.1039/c2jm15041g
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