Citation: ZHU Yan-Yan, LIU Yan-Fang, LÜ Yan-Hui, WANG Hua, LING Qiang, ZHU Yong-Fa. Reflux Preparation and Photocatalytic Performance of Bismuth Phosphate Nanorods[J]. Acta Physico-Chimica Sinica, ;2013, 29(03): 576-584. doi: 10.3866/PKU.WHXB201301043 shu

Reflux Preparation and Photocatalytic Performance of Bismuth Phosphate Nanorods

1.
1 Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China;
2 Institute of Aeronautical Meteorology and Chemical Defence, Equipment Academy of Air Force, Beijing 100085, P. R. China

Received Date: 24 October 2012
Available Online: 4 January 2013
Fund Project: 国家自然科学基金(20925725, 50972070) (20925725, 50972070)

BiPO₄ nanorods were synthesized by reflux, and the effect of reaction time, reactant ratio and concentration, and pH value on BiPO₄ crystal structure and morphology was investigated. Nanorods were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), specific surface area analysis (BET), and UV-Vis diffuse reflectance spectroscopy (UV-Vis DRS). The ability of BiPO₄ to photo-degrade methylene blue (MB) was investigated. The reaction time and reactant concentration influenced the product morphology. The reactant ratio and pH value had a large effect on the product crystal structure and morphology, and also on the photo-activity of BiPO₄. Highly UV active BiPO₄ nanorods of monoclinic monazite/hexa nal mixed crystal structure suitable for photocatalysis could be prepared by carefully controlling the above conditions.
- Refluxing method,
- Controllable synthesis,
- Bismuth phosphate,
- Mixed crystal structure,
- Photocatalysis
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