Citation: YANG Yong-Hong, LI Fen-Fen, YANG Cheng, ZHANG Wen-Yu, WU Jin-Hu. Grafting Morphologies of TEPA on SBA-15(P) and Its Effect on CO₂ Adsorption Performance[J]. Acta Physico-Chimica Sinica, ;2012, 28(01): 195-200. doi: 10.3866/PKU.WHXB201228195 shu

Grafting Morphologies of TEPA on SBA-15(P) and Its Effect on CO₂ Adsorption Performance

1.
1. Key Laboratory of Biofuels, Qindao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, Shandong Province, P. R. China;
2. Graduate University of Chinese Academy of Sciences, Beijing 100049, P. R. China;
3. Shandong Polytechnic University, Jinan 250353, P. R. China

Received Date: 8 August 2011
Available Online: 27 October 2011
Fund Project: 山东省自然科学基金(2009ZRB01250) (2009ZRB01250)青岛市科技发展计划(1263194353127)资助项目 (1263194353127)

Various amine-functionalized CO₂ adsorbents were prepared by incorporating tetraethylenepenthamine (TEPA) onto SBA-15(P) by controlling the impregnation method and its process. The materials were characterized using X-ray diffraction (XRD), N2-adsorption, elemental analysis, and Fourier transform infrared (FTIR) techniques. Their adsorptive capacities were determined by CO₂-temperature programmed desorption (TPD). The results indicate that the dynamic impregnation process using a TEPA ethanol solution was successful in loading TEPA into the channels of SBA-15(P). Moreover, bonding formation between the highly dispersed TEPA and SBA-15(P) was facilitated to CO₂ adsorption/desorption. Therefore, a binding mechanism is proposed. The －NH₂ group of TEPA forms hydrogen bonds with －OH and C－O－C groups on SBA-15(P), which results in the better dispersion of TEPA. However, the dynamic impregnation process for the TEPA ethanol solution can effectively avoid the formation of hydrogen bonds between the intra- and inter-molecules resulting in the high adsorptive capacity of the amino groups in TEPA.
- SBA-15(P),
- TEPA,
- CO₂,
- Dynamic impregnation,
- Bond formation,
- Adsorptive capacity
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Grafting Morphologies of TEPA on SBA-15(P) and Its Effect on CO2 Adsorption Performance

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通讯作者: 陈斌, bchen63@163.com

Grafting Morphologies of TEPA on SBA-15(P) and Its Effect on CO₂ Adsorption Performance