Citation: GUO Xiao-Ming, MAO Dong-Sen, LU Guan-Zhong, WANG Song. Preparation of CuO-ZnO-ZrO₂ by Citric Acid Combustion Method and Its Catalytic Property for Methanol Synthesis from CO₂ Hydrogenation[J]. Acta Physico-Chimica Sinica, ;2012, 28(01): 170-176. doi: 10.3866/PKU.WHXB201228170 shu

Preparation of CuO-ZnO-ZrO₂ by Citric Acid Combustion Method and Its Catalytic Property for Methanol Synthesis from CO₂ Hydrogenation

1.
1. Research Institute of Industrial Catalysis, East China University of Science and Technology, Shanghai 200237, P. R. China;
2. Research Institute of Applied Catalysis, Shanghai Institute of Technology, Shanghai 200235, P. R. China

Received Date: 29 August 2011
Available Online: 3 November 2011
Fund Project: 上海市科委科研项目(08520513600) (08520513600) 上海市教委重点学科建设项目(J51503) (J51503)上海应用技术学院科技发展基金(KJ2010-05)资助 (KJ2010-05)

CuO-ZnO-ZrO₂ (CZZ) catalysts for methanol synthesis from CO₂ hydrogenation were prepared by a citric acid combustion method. The combustion reactions were analyzed in terms of propellant chemistry and the combustion behavior was recorded by thermo-gravimetric/differential thermal analysis (TG-DTA). The as-prepared CZZ powders were investigated with X-ray diffraction (XRD), N₂ adsorption, temperature-programmed reduction (TPR), and reactive N₂O adsorption techniques and the catalytic activities were evaluated for methanol synthesis from CO₂ hydrogenation. The results show that the influence of citric acid quantity on the physicochemical and catalytic properties of CZZ is subtle, and the reason is related to the characteristics of the combustion reaction. Furthermore, the relationship between the quantity of fuel (citric acid, urea, and glycine) and the properties of the catalysts was determined. The citric acid combustion method exhibits better controllability and it is a simple, fast, and valuable route for the preparation of the CZZ catalyst for methanol synthesis from CO₂ hydrogenation.
- Combustion synthesis,
- Citric acid,
- CuO-ZnO-ZrO₂,
- CO₂ hydrogenation,
- Methanol
1. [1]
  (1) Zhang, J. X.; Zhao, Y. Q.; Chen, J. X.;Wang, R. J.; Zhang, J. Y. Natural Gas Chem. Ind. 2004, 29, 43. [张建祥, 赵彦巧, 陈吉祥, 王日杰, 张继炎. 天然气化工, 2004, 29, 43.]
2. [2]
  (2) Olah, G. A. Catal. Lett. 2004, 93, 1.
3. [3]
  (3) Arena, F.; Barbera,K.; Italiano, G.; Bonura, G.; Spadaro, L.; Frusteri, F. J. Catal. 2007, 249, 185.
4. [4]
  (4) S?oczyński, J.; Grabowski, R.; Koz?owska, A.; Olszewski, P.; Lachowska, M.; Skrzypek, J.; Stoch, J. Appl. Catal. A-Gen. 2003, 249, 129.
5. [5]
  (5) Ma, Y.; Sun, Q.;Wu, D.; Fan,W. H.; Zhang, Y. L.; Deng, J. F. Appl. Catal. A-Gen. 1998, 171, 45.
6. [6]
  (6) Raudaskoski, R.; Niemelä, M. V.; Keiski, R. L. Top. Catal. 2007, 45, 57.
7. [7]
  (7) S?oczyński, J.; Grabowski, R.; Koz?owska, A.; Olszewski, P.; Stoch, J.; Skrzypek, J.; Lachowska, M. Appl. Catal. A-Gen. 2004, 278, 11.
8. [8]
  (8) Zhuang, H. D.; Bai, S. F.; Liu, X. M.; Yan, Z. F. J. Fuel Chem. Technol. 2010, 38, 462. [庄会栋, 白绍芬, 刘欣梅, 阎子峰. 燃料化学学报, 2010, 38, 462.]
9. [9]
  (9) Zhu, P. F.; Li, J.; Zuo, S. F.; Zhou, R. X. Appl. Surf. Sci. 2008, 255, 2903.
10. [10]
  (10) Zhu, Y. Q.; Ma, Y. F.; Lin, X. P.;Wang, Z. H. Chin. J. Catal. 1998, 19, 393. [朱毅青, 马延风, 林西平, 王占华. 催化学报, 1998, 19, 393.]
11. [11]
  (11) Cong, Y.; Tin, K. C.;Wang, N. B.; Xu, C. H.; Zhang, T.; Sun, X. Y.; Guan,W.; Liang, D. B. Chin. J. Catal. 2000, 21, 247. [从昱, 田金忠, 黄宁表, 徐长海, 张涛, 孙孝英, 关文, 梁东白. 催化学报, 2000, 21, 247.]
12. [12]
  (12) Agrell, J.; Boutonnet, M.; Melian-Cabrera, I.; Fierro, J. L. G. Appl. Catal. A-Gen. 2003, 253, 201.
13. [13]
  (13) Wang, L. C.; Liu, Y. M.; Chen, M.; Cao, Y.; He, H. Y.;Wu, G. S.; Dai,W. L.; Fan, K. N. J. Catal. 2007, 246, 193.
14. [14]
  (14) Su, X. T.; Yan, Q. Z.; Ge, C. C. Progress Chem. 2005, 17, 430. [宿新泰, 燕青芝, 葛昌纯. 化学进展, 2005, 17, 430.]
15. [15]
  (15) Patil, K. C.; Aruna, S. T.; Mimani, T. Curr. Opin. Solid State Mater. Sci. 2002, 6, 507.
16. [16]
  (16) Wang, Q. G.; Peng, R. R.; Xia, C. R.; Zhu,W.;Wang, H. T. Ceram. Int. 2008, 34, 1773.
17. [17]
  (17) Ribeiro, N. F. P.; Souza, M. M. V. M.; Schmal, M. J. Power Sources 2008, 179, 329.
18. [18]
  (18) Av uropoulos, G.; Ioannides, T. Appl. Catal. A-Gen. 2003, 244, 155.
19. [19]
  (19) Toniolo, J. C.; Lima, M. D.; Takimi, A. S.; Bergmann, C. P. Mater. Res. Bull. 2005, 40, 561.
20. [20]
  (20) Guo, X. M.; Mao, D. S.; Lu, G. Z.;Wang, S.;Wu, G. S. J. Catal. 2010, 271, 178.
21. [21]
  (21) Guo, X. M.; Mao, D. S.;Wang, S.;Wu, G. S.; Lu, G. Z. Catal. Commun. 2009, 10, 1661.
22. [22]
  (22) Chinchen, G. C.; Hay, C. M.; Vandervell, H. D.;Waugh, K. C. J. Catal. 1987, 103, 79.
23. [23]
  (23) Jain, S. R.; Adiga, K. C.; Pai Verneker, V. R. Combust. Flame 1981, 40, 71.
24. [24]
  (24) Dean, J. A. Lange ' s Handbook of Chemistry, 13th ed.; McGraw-Hill: New York, 1985; pp 9-14, 9-19, 9-25, 9-66, 9-67, 9-93.
25. [25]
  (25) Zhang, Y. P.; Fei, J. H.; Yu, Y. M.; Zheng, X. M. Energy Convs. Manage. 2006, 47, 3360.
26. [26]
  (26) Melián-Cabrera, I.; López Granados, M.; Fierro, J. L. G. J. Catal. 2002, 210, 273.
27. [27]
  (27) Lin, M. G.; Yang, C.;Wu, G. S.;Wei,W.; Li,W. H.; Shan, Y. K.; Sun, Y. H.; He, M. Y. Chin. J. Catal. 2004, 25, 591. [林明桂, 杨成, 吴贵升, 魏伟, 李文怀, 单永奎, 孙予罕, 何鸣元. 催化学报, 2004, 25, 591.]
28. [28]
  (28) Yang, Z. Q.; Mao, D. S.; Guo, Q. S.; Gu, L. Acta Phys. -Chim. Sin. 2010, 26, 3278. [杨志强, 毛东森, 郭强胜, 顾蕾. 物理化学学报, 2010, 26, 3278]
29. [29]
  (29) Purohit, R. D.; Sharma, B. P.; Pillai, K. T.; Tyagi, A. K. Mater. Res. Bull. 2001, 36, 2711.
30. [30]
  (30) Andrade de Jesus, F. A.; Silva, R. S.; Hernandes, A. C.; Macedo, Z. S. J. Eur. Ceram. Soc. 2009, 29, 125.
31. [31]
  (31) Chinchen, G. C.;Waugh, K. C.; Whan, D. A. Appl. Catal. 1986, 25, 101.
32. [32]
  (32) Sun, Q.; Zhang, Y. L.; Chen, H. Y.; Deng, J. F.;Wu, D.; Chen, S. Y. J. Catal. 1997, 167, 92.
33. [33]
  (33) Zhang, Z. L.; Zhang, Y. X.; Mu, Z. G.; Yu, P. F.; Ni, X. Z.; Wang, S. L.; Zheng, L. S. Appl. Catal. B-Enviro. 2007, 76, 335.
34. [34]
  (34) Deganello, F.; Marcì, G.; Deganello, G. J. Eur. Ceram. Soc. 2009, 29, 439.
35. [35]
  (35) Zhang, J. R.; Gao, L. Mater. Lett. 2004, 58, 2730.
36. [36]
  (36) Singh, K. A.; Pathak, L. C.; Roy, S. K. Ceram. Int. 2007, 33, 1463.
37. [37]
  (37) Chandramouli, V.; Anthonysamy, S.; Vasudeva Rao, P. R. J. Nucl. Mater. 1999, 265, 255.
38. [38]
  (38) Li, F.; Hu, K. A.; Li, J. L.; Zhang, D.; Chen, G. J. Nucl. Mater. 2002, 300, 82.
1. [1]
  Jinghua Wang , Yanxin Yu , Yanbiao Ren , Yesheng Wang . Integration of Science and Education: Investigation of Tributyl Citrate Synthesis under the Promotion of Hydrate Molten Salts for Research and Innovation Training. University Chemistry, 2024, 39(11): 232-240. doi: 10.3866/PKU.DXHX202402057
2. [2]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
3. [3]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
4. [4]
  Ling Liu , Haibin Wang , Genrong Qiang . Curriculum Ideological and Political Design for the Comprehensive Preparation Experiment of Ethyl Benzoate Synthesized from Benzyl Alcohol. University Chemistry, 2024, 39(2): 94-98. doi: 10.3866/PKU.DXHX202304080
5. [5]
  Wanmin Cheng , Juan Du , Peiwen Liu , Yiyun Jiang , Hong Jiang . Photoinitiated Grignard Reagent Synthesis and Experimental Improvement in Triphenylmethanol Preparation. University Chemistry, 2024, 39(5): 238-242. doi: 10.3866/PKU.DXHX202311066
6. [6]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
7. [7]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
8. [8]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
9. [9]
  Jian Jin , Jing Cheng , Xueping Yang . Integration Practice of Organic Chemistry Experiment and Safety Education: Taking the Synthesis of Triphenylmethanol as an Example. University Chemistry, 2024, 39(3): 345-350. doi: 10.3866/PKU.DXHX202309010
10. [10]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
11. [11]
  Lirui Shen , Kun Liu , Ying Yang , Dongwan Li , Wengui Chang . Synthesis and Application of Decanedioic Acid-N-Hydroxysuccinimide Ester: Exploration of Teaching Reform in Comprehensive Applied Chemistry Experiment. University Chemistry, 2024, 39(8): 212-220. doi: 10.3866/PKU.DXHX202312035
12. [12]
  Qingying Gao , Tao Luo , Jianyuan Su , Chaofan Yu , Jiazhu Li , Bingfei Yan , Wenzuo Li , Zhen Zhang , Yi Liu . Refinement and Expansion of the Classic Cinnamic Acid Synthesis Experiment. University Chemistry, 2024, 39(5): 243-250. doi: 10.3866/PKU.DXHX202311074
13. [13]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
14. [14]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
15. [15]
  Ping Song , Nan Zhang , Jie Wang , Rui Yan , Zhiqiang Wang , Yingxue Jin . Experimental Teaching Design on Synthesis and Antitumor Activity Study of Cu-Pyropheophorbide-a Methyl Ester. University Chemistry, 2024, 39(6): 278-286. doi: 10.3866/PKU.DXHX202310087
16. [16]
  Houzhen Xiao , Mingyu Wang , Yong Liu , Bangsheng Lao , Lingbin Lu , Minghuai Yu . Course Ideological and Political Design of Combustion Heat Measurement Experiment. University Chemistry, 2024, 39(2): 7-13. doi: 10.3866/PKU.DXHX202310011
17. [17]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
18. [18]
  Yuan Zheng , Quan Lan , Zhenggen Zha , Lingling Li , Jun Jiang , Pingping Zhu . Teaching Reform of Organic Synthesis Experiments by Introducing Reverse Thinking and Design Concepts: Taking the Synthesis of Cinnamic Acid Based on Retrosynthetic Analysis as an Example. University Chemistry, 2024, 39(6): 207-213. doi: 10.3866/PKU.DXHX202310065
19. [19]
  Yukun Chang , Haoqin Huang , Baolei Wang . Preparation of Trans-Cinnamic Acid via “One-Pot” Protocol of Aldol Condensation-Hydrolysis Reaction: Recommending an Improved Organic Synthesis Experiment. University Chemistry, 2024, 39(4): 322-328. doi: 10.3866/PKU.DXHX202309095
20. [20]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093

Get Citation

PDF

XML

Metrics

PDF Downloads(2720)
Abstract views(2844)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of CuO-ZnO-ZrO2 by Citric Acid Combustion Method and Its Catalytic Property for Methanol Synthesis from CO2 Hydrogenation

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of CuO-ZnO-ZrO₂ by Citric Acid Combustion Method and Its Catalytic Property for Methanol Synthesis from CO₂ Hydrogenation