Citation: CHEN Xiao-Yun, LU Dong-Fang, HUANG Jin-Feng, LU Yan-Feng, ZHENG Jian-Qiang. Preparation and Properties of N-F Co-Doped TiO₂ Photocatalyst with Wide Range Light Response and Multipore Structure from Ionic Liquid-Water Mixture Solvent[J]. Acta Physico-Chimica Sinica, ;2012, 28(01): 161-169. doi: 10.3866/PKU.WHXB201228161 shu

Preparation and Properties of N-F Co-Doped TiO₂ Photocatalyst with Wide Range Light Response and Multipore Structure from Ionic Liquid-Water Mixture Solvent

1.
1. College of Material Engineering, Fujian Agriculture and Forestry University, Fuzhou 350002, P. R. China;
2. College of Landscape Architecture, Fujian Agriculture and Forestry University, Fuzhou 350002, P. R. China

Received Date: 16 August 2011
Available Online: 25 October 2011
Fund Project: 国家自然科学基金(31000269) (31000269) 福建省高等学校杰出青年科研人才培育计划(JA11072) (JA11072)福建省教育厅基金(JA10121)资助项目 (JA10121)

A yellow N-F co-doped TiO₂ photocatalyst (TiONF) exhibited high activity over a wide light spectrum range and a multipore structure was prepared by a hydrolysis-precipitation method using an ionic liquid ([Bmim]PF₆)-water mixture as the solvent and TiCl₄ as the precursor. Photocatalytic activity was investigated by the photocatalytic degradation of phenol under ultraviolet (UV), artificial visible (Vis), and solar light irradiation. X-ray photoelectron spectroscopy (XPS), UV-Vis diffuse reflectance spectroscopy (DRS), transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared (FTIR), spectroscopy, and N₂ adsorption-desorption were used for catalyst characterization. The results show that TiONF synthesis in an ionic liquid-water mixture solvent with suitable N-F doping gives high activity under UV, Vis, and solar light irradiation, and the activities are higher than those obtained by synthesis in pure water. The ionic liquid-water mixture solvent leads to N and F being incorporated into the TiO₂ lattice and N-F co-doping can increase the amount of surface OH^- on TiO₂. The new bandgap formed by N-F doping can induce a second adsorption edge (450-530 nm), which can be excited by Vis irradiation and induce Vis activity. N-F co-doping retards the phase transformation. In addition, an ionic liquid-water mixture as a solvent benefits the dispersion of TiO₂, increases the S_BET and reduces the particle size.
- TiO₂,
- N-F co-doping,
- Ionic liquid,
- Photocatalyst,
- Visible light
1. [1]
  (1) Yu, J. G.; Zhou, M. H.; Cheng, B.; Zhao, X. J. J. Mol. Catal. A-Chem. 2006, 246 (1-2), 176.
2. [2]
  (2) Wawrzyniak, B.; Morawski, A.W. Appl. Catal. B-Environ. 2005, 62 (1-2), 150.
3. [3]
  (3) Liu, S. X.; Chen, X. Y.; Chen, X. Chin. Chem. Lett. 2006, 17
4. [4]
  (4) Mori, K.; Maki, K.; Kawasaki, S.; Yuan, S.; Yamashita, H. Chem. Eng. Sci. 2008, 63, 5066.
5. [5]
  (4) Mori, K.; Maki, K.; Kawasaki, S.; Yuan, S.; Yamashita, H. Chem. Eng. Sci. 2008, 63, 5066.
6. [6]
  (5) Balek, V.; Li, D.; Subrt, J.; Vecerniková, E.; Hishitab, S.; Mitsuhashib, T.; Hanedab, H. J. Phys. Chem. Solid 2007, 68
7. [7]
  (5-6), 770.
8. [8]
  (7) Wu, Y. M.; Xing, M. Y.; Tian, B. Z.; Zhang, J. L.; Chen, F. Chem. Eng. J. 2010, 162, 710.
9. [9]
  (7) Wu, Y. M.; Xing, M. Y.; Tian, B. Z.; Zhang, J. L.; Chen, F. Chem. Eng. J. 2010, 162, 710.
10. [10]
  (8) Chen. P.; Gu, M. Y.; Jin, Y. P. Progress in Chemistry 2005, 17
11. [11]
  (1), 8. [程萍, 顾明元, 金燕苹. 化学进展, 2005, 17 (1), 8.]
12. [12]
  (9) Tang, Y. C.; Huang, X. H.; Yu, H. Q.; Hu, C. Progress in Chemistry 2007, 19 (2-3), 225. [唐玉朝, 黄显怀, 俞汉青, 胡春. 化学进展, 2007, 19 (2-3), 225.]
13. [13]
  (10) Lu,W. S.; Xiao, G. S.; Li, D. Z.; Fu, X. Z.;Wang, X. X. Chin. J. Inorg. Chem. 2005, 21 (10), 1495. [鲁文升, 肖光参, 李旦振, 付贤智, 王绪绪. 无机化学学报, 2005, 21 (10), 1495.]
14. [14]
  (11) Ihara, T.; Miyoshi, M.; Iriyama, Y.; Matsumoto, O.; Sugihara, S. Appl. Catal. B 2003, 42 (4), 403.
15. [15]
  (12) O, Regan, B.; Graetzel, M. Nature 1991, 353 (6346), 737.
16. [16]
  (13) Nakamura, I.; Negishi, N.; Kutsuns, S.; Ihara, T.; Sugihara, S.; Takeuchi, K. J. Mol. Catal. A-Chem. 2000, 161 (1-2), 205.
17. [17]
  (14) Ashia, R.; Ohwaki, T.; Ohwak, K.; Aoki, K.; Taga, Y. Science 2001, 293 (5528), 269.
18. [18]
  (15) Hattori, A.; Tada, H. J. Sol-Gel. Sci. Technol. 2001, 22 (1-2), 47.
19. [19]
  (17) Pelaez, M.; Cruz, A. A.; Stathatos, E.; Falaras, P.; Dionysiou, D. Catal. Today 2009, 144, 19.
20. [20]
  (17) Pelaez, M.; Cruz, A. A.; Stathatos, E.; Falaras, P.; Dionysiou, D. Catal. Today 2009, 144, 19.
21. [21]
  (18) Lee, S. H.; Yamasue, E.; Ishihara, K. N.; Okumura, H. Appl. Catal. B-Environ. 2010, 93 (3-4), 217.
22. [22]
  (19) Li, X. H.; Liu, S. X. Acta Phys. -Chim. Sin. 2008, 24 (11), 2019. [李晓辉, 刘守新. 物理化学学报, 2008, 24 (11), 2019.]
23. [23]
  (20) Huang, D. G.; Liao, S. J.; Dang, Z. Acta. Chim. Sin. 2006, 64
24. [24]
  (17), 1805. [黄冬根, 廖世军, 党志. 化学学报, 2006, 64
25. [25]
  (17), 1805.]
26. [26]
  (21) Li, D.; Haneda, H.; Hishita, S.; Ohashi, N.; Labhsetwar, N. K. J. Fluorine Chem. 2005, 126 (1), 69.
27. [27]
  (23) Yoo, K. S.; Choi, H.; Dionysiou, D. D. Catal. Commun. 2005, 6, 259.
28. [28]
  (23) Yoo, K. S.; Choi, H.; Dionysiou, D. D. Catal. Commun. 2005, 6, 259.
29. [29]
  (25) Alammar, T.; Birkner, A.; Shekhah, O.; Mudring, A. V. Mater. Chem. Phys. 2010, 120, 109.
30. [30]
  (26) Liu, H.; Liang, Y. G.; Hu, H. J.;Wang, M. Y. Solid State Sci. 2009, 11, 1655.
31. [31]
  (27) Yu, N.; ng, L.; Song, H. J.; Liu, Y.; Yin, D. H. J. Solid State Chem. 2007, 180, 799.
32. [32]
  (27) Yu, N.; ng, L.; Song, H. J.; Liu, Y.; Yin, D. H. J. Solid State Chem. 2007, 180, 799.
33. [33]
  (28) Choi, E. H.; Hong, S. I.; Moon, D. J. Catal. Lett. 2008, 123
34. [34]
  (30) Benesi, H. A. J . Phys . Chem. 1957, 61, 970.
35. [35]
  (29) Wang, Z. Z.; Zhu, G. M.; Chen, B. Q. Chem. Eng. 2007, 141 (6), l4. [王振中, 朱光明, 陈北强. 化学工程师, 2007, 141 (6), l4.]
36. [36]
  (32) Li, Y. X.; Jiang, Y.; Peng, S. Q.; Jiang, F. Y. J. Hazard. Mater. 2010, 182, 90.
37. [37]
  (33) Ling, Q. C.; Sun, J Z.; Zhou, Q Y. Appl. Surf. Sci. 2008, 254, 3236.
38. [38]
  (34) Fox, M. A.; Dulay, M. T. Chem. Rev. 1993, 93, 341.
39. [39]
  (33) Ling, Q. C.; Sun, J Z.; Zhou, Q Y. Appl. Surf. Sci. 2008, 254, 3236.
40. [40]
  (34) Fox, M. A.; Dulay, M. T. Chem. Rev. 1993, 93, 341.
41. [41]
  (35) Hoffmann, M. R.; Martin, S. T.; Choi,W. Y.; Bahnemann, D.W. Chem. Rev. 1995, 95, 693.
42. [42]
  (36) Su, Y. L.; Li, Y.; Du, Y. X.; Lei, L. C. Acta Phys. -Chim. Sin. 2011, 27 (4), 939. [苏雅玲, 李轶, 杜瑛珣, 雷乐成. 物理化学学报, 2011, 27 (4), 939.]
43. [43]
  (37) Chen, X. Y.; Liu, S. X. Acta Phys. -Chim. Sin. 2007, 23 (5), 701. [陈孝云, 刘守新. 物理化学学报, 2007, 23 (5), 701.]
44. [44]
  (40) He, X.; David, A. Angew. Chem. Int. Edit. 2002, 41, 214.
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Properties of N-F Co-Doped TiO2 Photocatalyst with Wide Range Light Response and Multipore Structure from Ionic Liquid-Water Mixture Solvent

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通讯作者: 陈斌, bchen63@163.com

Preparation and Properties of N-F Co-Doped TiO₂ Photocatalyst with Wide Range Light Response and Multipore Structure from Ionic Liquid-Water Mixture Solvent