Citation: HAN Xia, CHENG Xin-Hao, HUANG Jian-Bin. Application of Anion-Cation Pair Surfactant Systems to Achieve Ultra-Low Oil-Water Interfacial Tension[J]. Acta Physico-Chimica Sinica, ;2012, 28(01): 146-153. doi: 10.3866/PKU.WHXB201228146 shu

Application of Anion-Cation Pair Surfactant Systems to Achieve Ultra-Low Oil-Water Interfacial Tension

1.
1. College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China;
2. Shengli Engineering & Consulting Co., Ltd., Dongying 257026, Shandong Province, P. R. China

Received Date: 26 August 2011
Available Online: 4 November 2011
Fund Project: 国家自然科学基金(20873001, 50821061, 21073006) (20873001, 50821061, 21073006)国家重点基础研究发展规划项目(973) (2007CB936201)资助 (973) (2007CB936201)

In this paper, ultra-low interfacial tension was obtained in realistic oil-water systems using ion pair surfactant systems. To improve the solubility of the ion pair surfactants, polyoxyethylene chain was introduced into the anionic surfactant molecular structure, and a three-component strategy where ion pair surfactants were combined with a non-ionic surfactant was used. Furthermore, the effects of the structures of the cationic and non-ionic surfactants, distribution ratio of the three components, and surfactant concentration on oil-water interfacial tension were studied. We successfully achieved the ultra-low interfacial tension in the Shengli oil fields using the mixed systems combining ion pairs and non-ionic agents. Several systems possessed an interfacial tension as low as 10^-4 mN·m^-1. Because of the strong electrostatic attraction between surfactant ions, our systems possess ultra-low interfacial tension after adsorption. The results show that after 48 h quartz adsorption, the systems can still reduce the interfacial tension to an ultra-low level.
- Anion-cation pair surfactants,
- Surfactants mixed system,
- Ultra-low interfacial tension,
- Enhanced oil recovery,
- Oil recovery
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