Citation: LI Feng-Li, GUO Li, XIAN Hui, MENG Ming, LI Zhi-Jun, BAO Jun, LI Xin-Gang. NO_x Storage Performance of Alkaline Earth-Doped Perovskite-Type BaFeO₃ Catalysts[J]. Acta Physico-Chimica Sinica, ;2013, 29(03): 605-611. doi: 10.3866/PKU.WHXB201212241 shu

NO_x Storage Performance of Alkaline Earth-Doped Perovskite-Type BaFeO₃ Catalysts

LI Feng-Li ¹ ,
GUO Li ¹ ,
XIAN Hui ¹ ,
MENG Ming ¹ ,
LI Zhi-Jun ² ,
BAO Jun ³ ,
LI Xin-Gang ^1,

1.
1 Tianjin Key Laboratory of Applied Catalysis Science & Technology, School of Chemical Engineering & Technology, Tianjin University, Tianjin 300072, P. R. China;
2 State Key Laboratory of Engines, Tianjin University, Tianjin 300072, P. R. China;
3 National Synchrotron Radiation Laboratory, University of Science & Technology of China, Hefei 230029, P. R. China

Received Date: 25 October 2012
Available Online: 24 December 2012
Fund Project: 国家自然科学基金(U1162103, U1232118) (U1162103, U1232118) 国家高技术研究发展计划(863) (2008AA06Z323) (863) (2008AA06Z323) 天津市自然科学基金(11JCYBJC03700) (11JCYBJC03700) 教育部新世纪优秀人才支持计划(NCET-10-0615) (NCET-10-0615) 教育部留学归国人员科研启动基金(2011-1568) (2011-1568)天津大学内燃机燃烧学国家重点实验室开放基金(K2012-05)资助项目 (K2012-05)

A series of Ba_1-xM_xFeO₃ (M=Mg, Ca, Sr; x=0, 0.1, 0.2) perovskites were prepared by the sol-gel method as NO_x storage reduction (NSR) catalysts. The effect of doping with alkaline earth metals (Mg, Ca, and Sr) on the NO_x storage and oxidation performance of the BaFeO₃ perovskites was investigated. Doping with Mg enhanced the NO_x storage capacity (NSC) of the BaFeO₃ perovskites in the temperature range 250-400 ℃, the Ba_0.8Mg_0.2FeO₃ perovskite exhibited the best NO_x storage performance, which reached its maximum at 350 ℃, with NSC>1200 μmol·g^-1 and the NO→NO₂ conversion of 53.4%. Compared with BaFeO₃, the monodentate nitrate appeared clearly for the Ba_0.8Mg_0.2FeO₃ sample after storing NO_x at 250 ℃. The amount of the monodentate nitrate on Ba_0.8Mg_0.2FeO₃ varied with the NO_x storage temperature in a similar manner to that of its NSC. Fourier transform infrared (FTIR) spectra indicated that doping with Mg induced an A-site deficient perovskite structure in BaFeO₃, which readily generates oxygen vacancies that act as the active sites for NO_x adsorption. Moreover, the residual M on the catalyst might also improve the NSC of the sample by forming the monodentate nitrate.
- Perovskite,
- Alkaline-earth metal doping,
- NO_x storage,
- NO oxidation,
- Lean-burn
1. [1]
  
  (1) Takahashi, N.; Shinjoh, H.; Iijima, T.; Suzuki, T.; Yamazaki, K.;Yokota, K.; Suzuki, H.; Miyoshi, N.; Matsumoto, S.; Tanizawa,T.; Tateishi, S.; Kasahara, K. Catal. Today 1996, 27, 63. doi: 10.1016/0920-5861(95)00173-5
2. [2]
  (2) Liu, Z. M.;Woo, S. I. Catal. Rev. 2006, 48, 43.
3. [3]
  (3) Liu, G.; Gao, P. X. Catal. Sci. Technol. 2011, 1, 552.
4. [4]
  (4) Roy, S.; Baiker, A. Chem. Rev. 2009, 109, 4054.
5. [5]
  (5) Epling,W. S.; Campbell, L. E.; Yezerets, A.; Currier, N.W.;Parks, J. E., II. Catal. Rev. 2004, 46, 163.
6. [6]
  (6) Li, X. G.; Meng, M.; Lin, P. Y.; Fu, Y. L.; Hu, T. D.; Xie, Y. N.;Zhang, J. Top. Catal. 2003, 22, 111. doi: 10.1023/A:1021480115825
7. [7]
  (7) Li, X. G.; Vernoux, P. Appl. Catal. B 2005, 61, 267. doi: 10.1016/j.apcatb.2005.06.003
8. [8]
  (8) Li, X. G.; Meng, M.; Lin, P. Y.; Fu, Y. L.; Hu, T. D.; Xie, Y. N.;Zhang, J. Chem. Eng. Res. Des. 2002, 80, 194.
9. [9]
  (9) Nova, I.; Castoldi, L.; Lietti, L.; Tronconi, E.; Forzatti, P.;Prinetto, F.; Ghiotti, G. J. Catal. 2004, 222, 377. doi: 10.1016/j.jcat.2003.11.013
10. [10]
  (10) Nova, I.; Lietti, L.; Castoldi, L.; Tronconi, E.; Forzatti, P.J. Catal. 2006, 239, 244. doi: 10.1016/j.jcat.2006.01.013
11. [11]
  (11) Li,W. Z.; Sun, K. Q.; Hu, Z.; Xu, B. Q. Catal. Today 2010, 153,103. doi: 10.1016/j.cattod.2010.02.056
12. [12]
  (12) Hu, Z.; Sun, K. Q.; Li,W. Z.; Xu, B. Q. Catal. Today 2010, 158,432. doi: 10.1016/j.cattod.2010.06.008
13. [13]
  (13) Li, X. G.; Meng, M.; Lin, P. Y.; Chen, J. F.; Fu, Y. L.; Yu, S. M.;Xie, Y. N.; Hu, T. D. Chin. J. Catal. 2002, 23, 417. [李新刚,孟明, 林培炎, 陈家福, 伏义路, 俞寿明, 谢亚宁, 胡天斗. 催化学报, 2002, 23, 417.]
14. [14]
  (14) Li, X. G.; Dong, Y. H.; Xian, H.; Hernández,W. Y.; Meng, M.;Zou, H. H.; Ma, A. J.; Zhang, T. Y.; Jiang, Z.; Tsubaki, N.;Vernoux, P. Energy Environ. Sci. 2011, 4, 3351. doi: 10.1039/c1ee01726h
15. [15]
  (15) Ma, A. J.;Wang, S. Z.; Zou, H. H.; Meng, M.; Li, Z. J.; Bao, J.;Li, X. G. Acta Phys. -Chim. Sin. 2012, 28, 1474. [马爱静, 王绍增, 邹鸿鹄, 孟明, 李志军, 鲍骏, 李新刚. 物理化学学报, 2012, 28, 1474.] doi: 10.3866/PKU.WHXB201203311
16. [16]
  (16) Hodjati, S.; Vaezzadeh, K.; Petit, C.; Pitchon,V.; Kiennemann,A. Appl. Catal. B 2000, 26, 5. doi: 10.1016/S0926-3373(99)00143-5
17. [17]
  (17) Hodjati, S.; Petit, C.; Pitchon, V.; Kiennemann, A. Appl. Catal.B 2000, 27, 117. doi: 10.1016/S0926-3373(00)00139-9
18. [18]
  (18) Chen, J. F.; Meng, M.; Lin, P. Y.; Li, X. G.; Fu, Y. L.; Yu, S. M.Chin. J. Catal. 2003, 24, 419. [陈家福, 孟明, 林培炎, 李新刚, 伏义路, 俞寿明. 催化学报, 2003, 24, 419.]
19. [19]
  (19) Xian, H.; Li, F. L.; Li, X. G.; Zhang, X.W.; Meng, M.; Zhang,T. Y.; Tsubaki, N. Fuel Proc. Technol. 2011, 92, 1718. doi: 10.1016/j.fuproc.2011.04.021
20. [20]
  (20) Xian, H.; Zhang, X.W.; Li, X. G.; Li, L. Y.; Zou, H. H.; Meng,M.; Li, Q.; Tan, Y. S.; Tsubaki, N. J. Phys. Chem. C 2010, 114,11844.
21. [21]
  (21) Xian, H.; Zhang, X.W.; Li, X. G.; Zou, H. H.; Meng, M.; Zou,Z. Q.; Guo, L. H.; Tsubaki, N. Catal. Today 2010, 158, 215. doi: 10.1016/j.cattod.2010.03.026
22. [22]
  (22) Basile, F.; Fornasari, G.; Grimandi, A.; Livi, M.; Vaccari, A.Appl. Catal. B 2006, 69, 58. doi: 10.1016/j.apcatb.2006.05.017
23. [23]
  (23) Basile, F.; Fornasari, G.; Gambatesa, A.; Livi, M.; Vaccari, A.Catal. Today 2007, 119, 59. doi: 10.1016/j.cattod.2006.08.051
24. [24]
  (24) Dawody, J.; Skoglundh, M.; Olsson, L.; Fridell, E. Appl. Catal.B 2007, 70, 179. doi: 10.1016/j.apcatb.2005.11.021
25. [25]
  (25) Wimmers, O. J.; Arnoldy, P.; Moulijn, J. A. J. Phys. Chem.1986, 90, 1331. doi: 10.1021/j100398a025
26. [26]
  (26) Fanson, P. T.; Horton, M. R.; Delgass,W. N.; Lauterbach, J.Appl. Catal. B 2003, 46, 393. doi: 10.1016/S0926-3373(03)00275-3
1. [1]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
2. [2]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
3. [3]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
4. [4]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
5. [5]
  Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . 卤化物钙钛矿的单双向离子迁移. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-. doi: 10.3866/PKU.WHXB202311011
6. [6]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
7. [7]
  Zuozhong Liang , Lingling Wei , Yiwen Cao , Yunhan Wei , Haimei Shi , Haoquan Zheng , Shengli Gao . Exploring the Development of Undergraduate Scientific Research Ability in Basic Course Instruction: A Case Study of Alkali and Alkaline Earth Metal Complexes in Inorganic Chemistry. University Chemistry, 2024, 39(7): 247-263. doi: 10.3866/PKU.DXHX202310103
8. [8]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
9. [9]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
10. [10]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
11. [11]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
12. [12]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
13. [13]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
14. [14]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
15. [15]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
16. [16]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
17. [17]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
18. [18]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
19. [19]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
20. [20]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093

Get Citation

PDF

XML

Metrics

PDF Downloads(687)
Abstract views(1279)
HTML views(40)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

NOx Storage Performance of Alkaline Earth-Doped Perovskite-Type BaFeO3 Catalysts

Metrics

通讯作者: 陈斌, bchen63@163.com

NO_x Storage Performance of Alkaline Earth-Doped Perovskite-Type BaFeO₃ Catalysts