Citation: JIANG Li-Lin, LIU Wei-Long, SONG Yun-Fei, HE Xing, WANG Yang, WU Hong-Lin, YANG Yan-Qiang. Fluorescence and Raman Spectroscopic Characteristics of the Photo-Induced Electron Transfer of Coumarin 343 Dye-Sensitized TiO₂ Nanoparticles[J]. Acta Physico-Chimica Sinica, ;2012, 28(12): 2953-2957. doi: 10.3866/PKU.WHXB20121127 shu

Fluorescence and Raman Spectroscopic Characteristics of the Photo-Induced Electron Transfer of Coumarin 343 Dye-Sensitized TiO₂ Nanoparticles

1.
1. Centre for the Condensed Matter Science and Technology, Department of Physics, Harbin Institute of Technology, Harbin 150001, Heilongjiang Province, P. R. China;
2. Department of Physics and Electronics Information Engineering, Hezhou University, Hezhou, 542800, Guangxi Province, P. 1 R. China

Received Date: 3 July 2012
Available Online: 31 August 2012
Fund Project: 国家自然科学基金(20973050, 21173063, 21003033) (20973050, 21173063, 21003033)广西自然科学青年基金(2012GXNSFBA053012) (2012GXNSFBA053012)广西教育厅科研基金(200103YB140, 200807LX015) (200103YB140, 200807LX015)中国工程物理研究院科学与技术发展基金(2010B0101001) (2010B0101001)冲击波与爆轰物理重点实验室基金(9140C67130208ZS75)资助项目 (9140C67130208ZS75)

The fluorescence and Raman spectroscopic characteristics of the photo-induced electron transfer of Coumarin 343 (C343) dye-sensitized TiO₂ nanoparticles have been investigated. The results indicate that the red-shift of the absorption spectrum peaks and the fluorescence spectrum maxima can be attributed to the photo-induced electron transfer from the excited state of the absorbed C343 dye molecules and the charge transfer complex (C343/TiO₂) to the conduction band manifold of the TiO₂ nanoparticles. Back electron transfer of the system was investigated by time resolved fluorescence spectroscopy and takes place in around τ₁=31 ps. Raman spectroscopy of the C343 dye-sensitized TiO₂ nanoparticles reveals that the carbon bond stretching vibrations and ring breathing motions of the absorbed C343 dye molecules at the interface significantly contribute to the ultrafast interface photoinduced electron transfer.
- C343 dye,
- TiO₂ nanoparticle,
- Photo-induced electron transfer,
- Time-resolved fluorescence spectroscopy,
- Stretching vibration
1. [1]
  
  (1) West,W.; Gilman, P. B., Jr. The Theory of the Photographic Process, 4th ed.; James, T. H. Ed.; New York: Macmillan, 1977;p 251.
2. [2]
  (2) Nazeerudin, M. K.; Kay, A.; Rodicio, I.; Humphrey-Baker, R.;Müller, E.; Liska, P.; Vlachopoulos, N.; Grätzel, M. J. Am. Chem. Soc. 1993, 115, 6382. doi: 10.1021/ja00067a063
3. [3]
  (3) Nitzan, A.; Ratner, M. A. Science 2003, 300, 1384. doi: 10.1126/science.1081572
4. [4]
  (4) Duncan,W. R.; Prezhdo, O. V. Annu. Rev. Phys. Chem. 2007,58, 143. doi: 10.1146/annurev.physchem.58.052306.144054
5. [5]
  (5) Heimer, T. A.; Heilweil, E. J. J. Phys. Chem. B 1997, 101,10990. doi: 10.1021/jp972560z
6. [6]
  (6) Stier,W.; Prezhdo, O. V. J. Phys. Chem. B 2002, 106, 8047. doi: 10.1021/jp014267b
7. [7]
  (7) O'Regan, B.; Grätzel, M. Nature 1991, 353, 737. doi: 10.1038/353737a0
8. [8]
  (8) Nazeeruddin, M. K.; Péchy, P.; Renouard, T.; Zakeeruddin, S.M.; Humphry-Baker, R.; Comte, P.; 10 Liska, P.; Cevey, L.;Costa, E.; Shklover, V.; Spiccia, L.; Deacon, G. B.; Bignozzi, C.A.; Grätzel, M. J. Am. Chem. Soc. 2001, 123, 1613. doi: 10.1021/ja003299u
9. [9]
  (9) Gao, F. F.;Wang, Y.; Shi, D.; Zhang, J.;Wang, M. K.; Jing, X.Y.; Humphry-Baker, R.;Wang, P.; Zakeeruddin, S. M.; Grätzel,M. J. Am. Chem. Soc. 2008, 130, 10720. doi: 10.1021/ja801942j
10. [10]
  (10) Cao, Y. M.; Bai, Y.; Yu, Q. J.; Cheng, Y. M.; Liu, S.; Shi, D.;Gao, F. F.;Wang, P. J. Phys. Chem. C 2009, 113, 6290. doi: 10.1021/jp9006872
11. [11]
  (11) Yella, A.; Lee, H.W.; Tsao, H. N.; Yi, C. Y.; Chandiran, A. K.;Nazeeruddin, M.; Diau, E.W.; Yeh, C. Y.; Zakeeruddin, S. M.;Grätzel, M. Science 2011, 334, 629. doi: 10.1126/science.1209688
12. [12]
  (12) Tachibana, Y.; Moser, J. E.; Grätzel, M.; Klug, D. R.; Durrant, J.R. J. Phys. Chem. 1996, 100, 20056. doi: 10.1021/jp962227f
13. [13]
  (13) Anderson, N. A.; Lian, T. Q. Annu. Rev. Phys. Chem. 2005, 5,491.
14. [14]
  (14) Cheng, H.; Dong, J. Z.; Chao, H.; Yao, J. H.; Cao, Y. A. Acta Phys. -Chim. Sin. 2012, 28, 850. [程辉, 董江舟, 巢晖,姚江宏, 曹亚安. 物理化学学报, 2012, 28, 850.] doi: 10.3866/PKU.WHXB2012020111
15. [15]
  (15) Xu,W.W.; Dai, S. Y.; Fang, X. Q.; Hu, L. H.; Kong, F, T.; Pan,X.;Wang, K. J. Acta Phys. Sin. 2005, 54, 5943. [徐炜炜, 戴松元, 方霞琴, 胡林华, 孔凡太, 潘旭, 王孔嘉. 物理学报, 2005,54, 5943.]
16. [16]
  (16) Liu,W. Q.; Kou, D. X.; Hu, L. H.; Huang, Y.; Jiang, N. Q.; Dai,S. Y. Acta Phys. Sin. 2010, 59, 5141. [刘伟庆, 寇东星, 胡林华, 黄阳, 姜年权, 戴松元. 物理学报, 2010, 59, 5141.]
17. [17]
  (17) Frontiera, R. R.; Dasgupta, J.; Mathies, R. A. J. Am. Chem. Soc.2009, 131, 15630. doi: 10.1021/ja907188b
18. [18]
  (18) Kaczor, A.; Turnau, K.; Baransk, M. Analyst 2011, 136, 1109.
19. [19]
  (19) Kukura, P.; McCamant, D.W.; Mathies, R. A. Annu. Rev. Phys. Chem. 2007, 58, 461. doi: 10.1146/annurev.physchem.58.032806.104456
20. [20]
  (20) Kukura, P.; McCamant, D.W.; Yoon, S.;Wandschneider, D. B.;Mathies, R. A. Science 2005, 310, 1006. doi: 10.1126/science.1118379
21. [21]
  (21) Huber, R.; Moser, J. E.; Grätzel, M.;Wachtveitl, J. J. Phys. Chem. B 2002, 106, 6494. doi: 10.1021/jp0155819
22. [22]
  (22) Marcus, R. A.; Sutin, N. Biochimica et Biophysica Acta 1985,811, 265.
23. [23]
  (23) Ramakrishna, G.; Das, A.; Ghosh, H. N. Langmuir 2004, 20,1430. doi: 10.1021/la035190g
24. [24]
  (24) Ramakrishna, G.; Singh, A. K.; Palit, D. K.; Ghosh, H. N.J. Phys. Chem. B 2004, 108, 1701. doi: 10.1021/jp036701a
25. [25]
  (25) Barzykin, A. V.; Tachiya, M. J. Phys. Chem. B 2002, 106, 4356.doi: 10.1021/jp012957+
26. [26]
  (26) Ghosh, H. N.; Asbury, J. B.; Lian, T. Q. J. Phys. Chem. B 1998,102, 6482. doi: 10.1021/jp981806c
27. [27]
  (27) Ramakrishna, G.; Ghosh, H. N. J. Phys. Chem. B 2001, 105,7000. doi: 10.1021/jp011291g
28. [28]
  (28) Ghosh, H. N. J. Phys. Chem. B 1999, 103, 10382. doi: 10.1021/jp9918611
29. [29]
  (29) Jiang, L. L.; Song, Y. F.; Liu,W. L.; Yu, G. Y.; He, X.;Wang, Y.;Wu, H. L.; Yang, Y. Q. Acta Phys. Sin. 2012, 61, 090505. [蒋礼林, 宋云飞, 刘伟龙, 于国洋, 何兴, 王阳, 吴红琳, 杨延强. 物理学报, 2012, 61, 090505.]
30. [30]
  (30) Huber, R.; Sporlein, S.; Moser, J. E.; Grätzel, M.;Wachtveitl,J. J. Phys. Chem. B 2000, 104, 8995.
31. [31]
  (31) Shoute, L. C. T.; Loppnowa, G. R. J. Chem. Phys. 2002, 117,842. doi: 10.1063/1.1483848
32. [32]
  (32) Frisch, M. J.; Trucks, G.W.; Schlegel, H. B.; et al. Gaussian 03,Revision E.01; Gaussian Inc.:Wallingford, CT, 2004.
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沈阳化工大学材料科学与工程学院沈阳 110142

Fluorescence and Raman Spectroscopic Characteristics of the Photo-Induced Electron Transfer of Coumarin 343 Dye-Sensitized TiO2 Nanoparticles

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通讯作者: 陈斌, bchen63@163.com

Fluorescence and Raman Spectroscopic Characteristics of the Photo-Induced Electron Transfer of Coumarin 343 Dye-Sensitized TiO₂ Nanoparticles