Citation:
JIANG Li-Lin, LIU Wei-Long, SONG Yun-Fei, HE Xing, WANG Yang, WU Hong-Lin, YANG Yan-Qiang. Fluorescence and Raman Spectroscopic Characteristics of the Photo-Induced Electron Transfer of Coumarin 343 Dye-Sensitized TiO2 Nanoparticles[J]. Acta Physico-Chimica Sinica,
;2012, 28(12): 2953-2957.
doi:
10.3866/PKU.WHXB20121127
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The fluorescence and Raman spectroscopic characteristics of the photo-induced electron transfer of Coumarin 343 (C343) dye-sensitized TiO2 nanoparticles have been investigated. The results indicate that the red-shift of the absorption spectrum peaks and the fluorescence spectrum maxima can be attributed to the photo-induced electron transfer from the excited state of the absorbed C343 dye molecules and the charge transfer complex (C343/TiO2) to the conduction band manifold of the TiO2 nanoparticles. Back electron transfer of the system was investigated by time resolved fluorescence spectroscopy and takes place in around τ1=31 ps. Raman spectroscopy of the C343 dye-sensitized TiO2 nanoparticles reveals that the carbon bond stretching vibrations and ring breathing motions of the absorbed C343 dye molecules at the interface significantly contribute to the ultrafast interface photoinduced electron transfer.
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