Citation: JIANG Li-Lin, LIU Wei-Long, SONG Yun-Fei, HE Xing, WANG Yang, WU Hong-Lin, YANG Yan-Qiang. Fluorescence and Raman Spectroscopic Characteristics of the Photo-Induced Electron Transfer of Coumarin 343 Dye-Sensitized TiO₂ Nanoparticles[J]. Acta Physico-Chimica Sinica, ;2012, 28(12): 2953-2957. doi: 10.3866/PKU.WHXB20121127 shu

Fluorescence and Raman Spectroscopic Characteristics of the Photo-Induced Electron Transfer of Coumarin 343 Dye-Sensitized TiO₂ Nanoparticles

1.
1. Centre for the Condensed Matter Science and Technology, Department of Physics, Harbin Institute of Technology, Harbin 150001, Heilongjiang Province, P. R. China;
2. Department of Physics and Electronics Information Engineering, Hezhou University, Hezhou, 542800, Guangxi Province, P. 1 R. China

Received Date: 3 July 2012
Available Online: 31 August 2012
Fund Project: 国家自然科学基金(20973050, 21173063, 21003033) (20973050, 21173063, 21003033)广西自然科学青年基金(2012GXNSFBA053012) (2012GXNSFBA053012)广西教育厅科研基金(200103YB140, 200807LX015) (200103YB140, 200807LX015)中国工程物理研究院科学与技术发展基金(2010B0101001) (2010B0101001)冲击波与爆轰物理重点实验室基金(9140C67130208ZS75)资助项目 (9140C67130208ZS75)

The fluorescence and Raman spectroscopic characteristics of the photo-induced electron transfer of Coumarin 343 (C343) dye-sensitized TiO₂ nanoparticles have been investigated. The results indicate that the red-shift of the absorption spectrum peaks and the fluorescence spectrum maxima can be attributed to the photo-induced electron transfer from the excited state of the absorbed C343 dye molecules and the charge transfer complex (C343/TiO₂) to the conduction band manifold of the TiO₂ nanoparticles. Back electron transfer of the system was investigated by time resolved fluorescence spectroscopy and takes place in around τ₁=31 ps. Raman spectroscopy of the C343 dye-sensitized TiO₂ nanoparticles reveals that the carbon bond stretching vibrations and ring breathing motions of the absorbed C343 dye molecules at the interface significantly contribute to the ultrafast interface photoinduced electron transfer.
- C343 dye,
- TiO₂ nanoparticle,
- Photo-induced electron transfer,
- Time-resolved fluorescence spectroscopy,
- Stretching vibration
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沈阳化工大学材料科学与工程学院沈阳 110142

Fluorescence and Raman Spectroscopic Characteristics of the Photo-Induced Electron Transfer of Coumarin 343 Dye-Sensitized TiO2 Nanoparticles

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通讯作者: 陈斌, bchen63@163.com

Fluorescence and Raman Spectroscopic Characteristics of the Photo-Induced Electron Transfer of Coumarin 343 Dye-Sensitized TiO₂ Nanoparticles